This book exhibits deep philosophical quandaries and intricacies of the historical development of science lying behind a simple and fundamental item of common sense in modern science, namely the composition of water as H2O. Three main phases of development are critically re-examined, covering the historical period from the 1760s to the 1860s: the Chemical Revolution, early electrochemistry, and early atomic chemistry. In each case, the author concludes that the empirical evidence available at the time was not decisive in settling (...) the central debates and therefore the consensus that was reached was unjustified or at least premature. This leads to a significant re-examination of the realism question in the philosophy of science and a unique new advocacy for pluralism in science. Each chapter contains three layers, allowing readers to follow various parts of the book at their chosen level of depth and detail. The second major study in "complementary science", this book offers a rare combination of philosophy, history and science in a bid to improve scientific knowledge through history and philosophy of science. (shrink)

What can we conclude from a mere handful of case studies? The field of HPS has witnessed too many hasty philosophical generalizations based on a small number of conveniently chosen case studies. One might even speculate that dissatisfaction with such methodological shoddiness contributed decisively to a widespread disillusionment with the whole HPS enterprise. Without specifying clear mechanisms for history-philosophy interaction, we are condemned to either making unwarranted generalizations from history, or writing entirely "local" histories with no bearing on an overall (...) understanding of the scientific process. I propose a move away from the habit of viewing historical cases as an inductive evidence-base for general philosophical theses. The relation between historical and philosophical studies should not be seen as one between the particular and the general, but as a relation between the concrete and the abstract. An abstract framework is necessary for telling any concrete story at all. In this paper I explore how doing concrete history can help our abstract philosophizing. In the absence of ready-made philosophical concepts appropriate for understanding a given historical episode, the historian is compelled to craft new abstract philosophical concepts. Therefore, history-writing can be a very effective method of philosophical discovery. I will illustrate these claims through a discussion of two investigations in HPS from my own recent and current work: (1) temperature measurement and epistemic iteration; (2)constitution and laboratory practices in the Chemical Revolution. (This will also raise, and solve, a problem of reflexivity: how can we use case studies to show how to go beyond case studies?). (shrink)

Historians often feel that standard philosophical doctrines about the nature and development of science are not adequate for representing the real history of science. However, when philosophers of science fail to make sense of certain historical events, it is also possible that there is something wrong with the standard historical descriptions of those events, precluding any sensible explanation. If so, philosophical failure can be useful as a guide for improving historiography, and this constitutes a significant mode of productive interaction between (...) the history and the philosophy of science. I illustrate this methodological claim through the case of the Chemical Revolution. I argue that no standard philosophical theory of scientific method can explain why European chemists made a sudden and nearly unanimous switch of allegiance from the phlogiston theory to Lavoisier's theory. A careful re-examination of the history reveals that the shift was neither so quick nor so unanimous as imagined even by many historians. In closing I offer brief reflections on how best to explain the general drift toward Lavoisier's theory that did take place. (shrink)

A chemical substance is instantiated in the material world by a number of quantities of such substance, placed in different locations. A change of location implies a change in the net of relationships entertained by the QCS with the region wherein it is found. This fact entails changes of the ontological status of the CS, as this is not fully determined by the inherent features of the CS and includes a relevant relational contribution. In order to demonstrate (...) this thesis, we have chosen to analyse the status of quantities of a same CS that are synchronically located in different spacetime regions: a synthetic lab, a lab where the QCS is turned into a material, an industrial plant, the market where the QCS gets a price and a dump waste where the QCS is discarded, respectively: Chemical substance Open image in new window material Open image in new window product Open image in new window goods Open image in new window wasteThe use of first-order predicate logic, mereology and locative logic allows carrying out a regimentation process that highlights the ontological commitments implied by the formal expressions through which each element of the aforementioned series can be described. The presence of relational properties discloses the systemic nature of the CS instantiated within a spacetime region. The implications of such an aspect are discussed. (shrink)

The ArgumentThe relation between alchemy and early chemistry is still open to debate. How did what is now often dismissed as a pseudo-science contribute to the emerging science of chemistry, a subject that by the late eighteenth century, was often held up as a model for other sciences? Alchemy may have bequeathed to chemistry some processes and apparatus; more fundamental, however, was a transformation in mentality. It was in the seventeenth century that much of this transformation took place.A study that (...) was deeply anthropomorphic, making constant use of allegories and symbolism, and with a language rejoicing in mystery and concealment, gradually became depersonalized, much more objective, and more open. Poetic descriptions, a moral dimension, and a hierarchical view of matter all disappeared. Practical considerations required a concern for greater purity of materials, necessary for the successful replication of experiments. A study of the series of seventeenth-century French textbooks of chemistry from Beguin to Lemery reveals a growing desire for practical results and plain speaking. Robert Boyle was particularly influential in urging the necessity of plain language. The creation of a suitable language to denote and differentiate among different chemical species was a crucial step in the development of early chemistry, thus preparing the way for the systematic names introduced in the following century and the full organization of the science on rational lines. (shrink)

It is well known that environmental burdens are more pronounced in socioeconomically disadvantaged communities, a phenomenon known as environmental injustice. Yet, there have been few studies that have addressed whether the degree of environmental injustice has changed over time. We analyze toxic releases in the United States over the first 26 years of the toxics release inventory and examine whether the decreases in toxic releases differ according to characteristics of the communities in which the emitters reside. We find that decreases (...) over these years are universal but far more substantial in high-income areas. Our results speak to both the nascent literature on information disclosure and that on environmental justice. (shrink)

For years, legal scholars and environmental activists have maintained that traditional tort proof requirements create insurmountable obstacles to recovery for most plaintiffs in chemical exposure cases, be they pharmaceutical suits or environmental toxic tort cases. Generally, tort law requires a plaintiff to show that the defendant owed a duty, that the defendant breached that duty, and that the breach of that duty caused the injury that is the subject of the suit. In some cases those requirements can be relaxed, (...) as for example, when an injury is of a type that does not occur except as a result of negligence. (shrink)

What is it that turns a new observation into a true scientific discovery? And who may claim the credit? Theoreticians of science, the foremost thinkers of their times among them, have tried to answer these fundamental questions about the nature of scientific progress and discovery. With clear insight and the chemical as well as philosophical wisdom gained from over fifty years as a practising chemist, Jerome Berson puts their theories to the test. The development of chemistry into a "modern" (...) science during the last two centuries provides him with ample cases to illustrate the way scientific progress really happens. Kekul?'s struggle to arrive at a structure for benzene, the paradigm change that was necessary to accept the reality of molecular rearrangements, and other episodes are retold here from the philosopher's as well as from the practitioner's perspective, shedding light on the way scientists think and act. Berson's account of the rather unphilosophical way in which scientific discoveries are made includes the realization that even a false hypothesis, such as Woodward's ideas about the biosynthesis of strychnine, may help rather than hinder scientific progress. Scientists of all ages, as well as many non-scientists, will find this a highly readable and unusual book. (shrink)

The chemical characterization of the substance responsible for the phenomenon of “transformation” of pneumococci was presented in the now famous 1944 paper by Avery, MacLeod, and McCarty. Reception of this work was mixed. Although interpreting their results as evidence that deoxyribonucleic acid (DNA) is the molecule responsible for genetic changes was, at the time, controversial, this paper has been retrospectively celebrated as providing such evidence. The mixed and changing assessment of the evidence presented in the paper was due to (...) the work’s interpretive flexibility – the evidence was interpreted in various ways, and such interpretations were justified given the neophytic state of molecular biology and methodological limitations of Avery’s transformation studies. I argue that the changing context in which the evidence presented by Avery’s group was interpreted partly explains the vicissitudes of the assessments of the evidence. Two less compelling explanations of the reception are a myth-making account and an appeal to the wartime historical context of its publication. (shrink)

The strategic use of disease and poison in warfare has been subject to a longstanding and cross-cultural taboo that condemns the hostile exploitation of poisons and disease as the act of a pariah. In short, biological and chemical weapons are simply not fair game. The normative opprobrium is, however, not fixed, but context dependent and, as a social phenomenon, remains subject to erosion by social (or more specifically, antisocial) actors. The cross cultural understanding that fighting with poisons and disease (...) is reprehensible, that they are taboo, is codified through a web of interconnected measures, principal amongst these are the 1925 Geneva Protocol; the Biological Weapons Convention; and the Chemical Weapons Convention. Whilst these treaties have weathered the storm of international events reasonably well, their continued health is premised on their being ‘tended to’ in the face of contextual changes, particularly facing changes in science and technology, as well as the changed nature and character of conflict. This article looks at the potential for normative erosion of the norm against chemical and biological weapons in the face of these contextual changes and the creeping legitimization of chemical and biological weapons. (shrink)

Astonishing changes have occurred to agricultural production systems since WWII. As such, many people tend to date the origins of industrial chemical agricultural to the early 1940s. The origins of industrial chemical agriculture, however, both on and off the field, have a much longer history. Indeed, industrial agriculture’s much discussed chemical dependency—in particular its need for toxic chemicals—and the development of the industries that feed this fix, have a long and diverse past that extend well back into (...) the nineteenth century. In this paper, through the narrative of a late nineteenth century creation story, I go in search of a crucial linchpin in that longer history. I argue that industrial pest control has been imbued with the practices, discourse, materials, and ethics of modern chemical warfare since its inception. Faced with pest-induced collapse, Los Angeles citrus growers and scientists of the USDA and UC Agricultural Extension chemically fixed the citrus pest problem by developing and utilizing the cyanide gas chamber. Cyanide fumigation quickly became the toxic cornerstone of the citrus industry, enabling its intensification and expansion as the pest infection became systemic. By the turn the century, furnished with an economic poison made cheap and weapons-grade due to changes in the world gold mining industry, growers transformed cyanide fumigation into a necessary agricultural input. In chemically overriding an agro-ecological contradiction of capitalist agriculture, growers, scientists, and government officials amalgamated industrially organized agriculture to accelerating and endless chemical warfare. These suddenly necessary agricultural practices signaled a state change in world-ecology and agroindustrial organization, thus, the discovery of effective industrial control for citrus pests was not only a pivotal moment in the history of Southern California but it was also an event that has had world-historical implications. (shrink)

The first Indian institution for scientific research was founded in 1876. The period 1876–1918 was a time of gestation for Indian chemistry, in which pure research gradually replaced the need-based, result-oriented research formerly promoted by the British regime. This formative period in Indian chemistry came to an end after the First World War and was succeeded by a rapid expansion of chemical research. The educational and political background against which these changes took place, and the influence of European chemistry (...) on developments in India, are discussed. Indian achievements in pure research are summarized, special consideration being given to the work of P. C. Ray, educationalist, entrepreneur, and research chemist. (shrink)

SummaryThis essay explains why and how nineteenth-century chemists sought to stabilize the melting and boiling points of organic substances as reliable characteristics of identity and purity and how, by the end of the century, they established these values as ‘Constants of Nature’. Melting and boiling points as characteristic values emerge from this study as products of laboratory standardization, developed by chemists in their struggle to classify, understand and control organic nature. A major argument here concerns the role played by the (...) introduction of organic synthesis in driving these changes. Synthetic organic chemistry vastly increased the number of known organic substances, precipitating the chemical identity crisis of my title. Successful natural product synthesis, moreover, depended on chemists’ ability to demonstrate the absolute identity of synthetic product and natural target – something late nineteenth-century chemists eventually achieved by making reliable, replicable melting and boiling point measurements. In the period before the establishment of national standards laboratories, chemists and scientific glassblowers worked together to standardize melting and boiling points as physical constants, such collaborations highlighting the essential importance of chemical glassware and glassblowing skill in the development of nineteenth-century organic chemistry. (shrink)

In the early twentieth century, scientific innovations permanently changed international warfare. As chemicals traveled out of laboratories into factories and military locations, war became waged at home as well as overseas. Large numbers of women were employed in munitions factories during the First World War, but their public memories have been overshadowed by men who died on battlefields abroad; they have also been ignored in traditional histories of chemistry that focus on laboratory-based research. Mostly young and poorly educated, but crucial (...) for Britain’s military success, these female workers were subjected to procedures of social regulation and consigned to carrying out dangerous chemical procedures causing chronic illness or death; in particular, when TNT died their skin yellow, they were colloquially known as 'canaries.'. (shrink)

The concept of living has changed in time along the history of biology and its specificity has been associated or to a particular matter, active such as the chemical one, or was considered as a product of the spatial organization of a passive matter. Today, these two paths can be merged in the chemical perspective that takes account of the general reflections on the complexity and on the systemic, in the “systemic complexity” approach.

Summary The purpose of this work is to translate some of Robert Boyle's chemical experiments into the terms of modern chemistry. Most of the reactions involve sensible qualities, since there are on it considerable helpful tracking descriptions like heating, hissing, colour changing, etc. For a long time in the history of science, this procedure was seen as an exercise in anachronism which should be avoided at all costs. Recently many scholars have demonstrated that chemical translation can assist with (...) historical work instead of causing confusion, and it may be very useful as a tool for the history of chemistry and for reproducing past chemical experiments. (shrink)

The paper discusses how well Kuhn’s general theory of scientific revolutions fits the particular case of the chemical revolution. To do so, I first present condensed sketches of both Kuhn’s theory and the chemical revolution. I then discuss the beginning of the chemical revolution and compare it to Kuhn’s specific claims about the roles of anomalies, crisis and extraordinary science in scientific development. I proceed by comparing some features of the chemical revolution as a whole to (...) Kuhn’s general account. The result will be that Kuhn’s general description of scientific revolutions fits the chemical revolution extraordinarily well. However, this result should not be taken as an empirical confirmation of Kuhn’s theory, but rather as an indication that the chemical revolution is a constitutive part of it. (shrink)

This article states that drugs could be used to produce, if not more intelligent individuals, at least individuals with better cognitive functioning. Cognitive functioning is something that we might strive to produce through education, including of course the more general health education of the community. Enhancements are good if and only if they make people better at doing some of the things they want to do including experiencing the world through all of the senses, assimilating and processing what is experienced, (...) remembering and understanding things better, becoming more competent, and experiencing more. Beneficial neural changes have been reported for such familiar technologies as reading, education, physical exercise, and diet. Smart drugs create irresistible competitive pressures such that once they are used everyone is forced to follow in order to keep up, and this is coercive and corrosive. (shrink)

In a number of papers and in his recent book, Is Water H₂O? Evidence, Realism, Pluralism (2012), Hasok Chang has argued that the correct interpretation of the Chemical Revolution provides a strong case for the view that progress in science is served by maintaining several incommensurable “systems of practice” in the same discipline, and concerning the same region of nature. This paper is a critical discussion of Chang's reading of the Chemical Revolution. It seeks to establish, first, that (...) Chang's assessment of Lavoisier's and Priestley's work and character follows the phlogistonists' “actors' sociology”; second, that Chang simplifies late-eighteenth-century chemical debates by reducing them to an alleged conflict between two systems of practice; third, that Chang's evidence for a slow transition from phlogistonist theory to oxygen theory is not strong; and fourth, that he is wrong to assume that chemists at the time did not have overwhelming good reasons to favour Lavoisier's over the phlogistonists' views. (shrink)

Unlike other branches of science, the scientific products of synthetic chemistry are not only ideas but also new substances that change our material world, for the benefit or harm of living beings. This paper provides for the first time a systematical analysis of moral issues arising from chemical synthesis, based on concepts of responsibility and general morality. Topics include the questioning of moral neutrality of chemical synthesis as an end in itself, chemical weapons research, moral objections (...) against improving material conditions of life by chemical means, and freedom of research. The paper aims at providing both a sound basis for moral judgements of chemistry in a public discourse and a framework for chemists to reflect on the moral relevance of their activity. (shrink)

Of this article's seven experiments, the first five demonstrate that virtually no Americans know the basic global warming mechanism. Fortunately, Experiments 2–5 found that 2–45 min of physical–chemical climate instruction durably increased such understandings. This mechanistic learning, or merely receiving seven highly germane statistical facts, also increased climate-change acceptance—across the liberal-conservative spectrum. However, Experiment 7's misleading statistics decreased such acceptance. These readily available attitudinal and conceptual changes through scientific information disconfirm what we term “stasis theory”—which some researchers and (...) many laypeople varyingly maintain. Stasis theory subsumes the claim that informing people about climate science may be largely futile or even counterproductive—a view that appears historically naïve, suffers from range restrictions, and/or misinterprets some polarization and correlational data. Our studies evidenced no polarizations. Finally, we introduce HowGlobalWarmingWorks.org—a website designed to directly enhance public “climate-change cognition.”. (shrink)

In this essay I critically examine the role of entropy of mixing in articulating a macroscopic criterion for the sameness and difference of chemical substances. Consider three cases of mixing in which entropy change occurs: isotopic variants, spin isomers, and populations of atoms in different orthogonal quantum states. Using these cases I argue that entropy of mixing tracks differences between physical states, differences that may or may not correspond to a difference of substance. It does not provide a (...) criterion for the sameness and difference of substance that is appropriate to chemistry. (shrink)

A novel non-classical mereological concept built up by blending the Metaphysics of Xavier Zubiri and the Quantum Theory of Atoms in Molecules of R. F. W. Bader is proposed. It is argued that this philosophical concept is necessary to properly account for what happens in a chemical reaction. From the topology of the gradient of the laplacian of the electronic charge density, \\) within the QTAIM framework, different “atomic graphs” are found for each atom depending on the molecular context, (...) reflecting how the whole molecule affects each atom. In this way, the whole molecular system imposes certain geometry onto each atom, and every atom exhibits different ontological modality. On the Metaphysical side, for X. Zubiri real things are system of different notes. The physical essence is the subsystem of essential notes with a coherence unity. Every note is grounded on the essence. The unity of the system is present somehow in every note-of beforehand, and every essential note-of turns towards the other. The essence determines the position of each note within the system, and hence is the grounding for modality of the notes. By conflating both “theories” and taking the atoms as essential notes, we propose the concept of “Molecule in atoms-of” or “atoms-of in Molecules”. Within the course of a chemical reaction the atoms-of modified their “of” as required by the new molecular unity being formed, and eventually change their modality. The validity to the Zubiri’s statements, is attained by evaluating necessity and possibility in a set-up of finite accessible “possible worlds”. (shrink)

The recent rapid development of information technology, such as sensing technology, communications technology, and database, allows us to use simulation experiments for analyzing serious accidents caused by hazardous chemicals. Due to the toxicity and diffusion of hazardous chemicals, these accidents often lead to not only severe consequences and economic losses, but also traffic jams at the same time. Emergency evacuation after hazardous chemical accidents is an effective means to reduce the loss of life and property and to smoothly resume (...) the transport network as soon as possible. This paper considers the dynamic changes of the hazardous chemicals’ concentration after their leakage and simulates the diffusion process. Based on the characteristics of emergency evacuation of hazardous chemical accidents, we build a mixed-integer programming model and design a heuristic algorithm using network optimization and diffusion simulation. We then verify the validity and feasibility of the algorithm using Jinan, China, as a computational example. In the end, we compare the results from different scenarios to explore the key factors affecting the effectiveness of the evacuation process. (shrink)

Despite the currently perceived urgent need among contemporary philosophers of chemistry for adjudicating between two rival metaphysical conceptual frameworks—is chemistry primarily a science of substances or processes?—this essay argues that neither provides us with what we need in our attempts to explain and comprehend chemical operations and phenomena. First, I show the concept of a chemical property can survive the abandoning of the metaphysical framework of substance. While this abandonment means that we will need to give up essential (...) properties, contingent properties can give us all the stability we need to account for chemical continuity as well as change. I then go on to show that this attention to clusters of contingent properties does not force us into the arms of an alternative process metaphysical framework either. Finally, I sketch a view I call particularism with respect to chemical properties on analogy with moral particularism. I conclude by sketching some of the implications for the field of philosophy of chemistry of my proposal that we abandon our interest in the metaphysical question of what chemistry is primarily about in favor of a broadly scientific particularism with respect to kinds and properties. (shrink)

Climate change, pollution, and deforestation have a negative impact on global mental health. There is an environmental justice dimension to this challenge as wealthy people and high-income countries are major contributors to climate change and pollution, while poor people and low-income countries are heavily affected by the consequences. Using state-of-the art data mining, we analyzed and visualized the global research landscape on mental health, climate change, pollution and deforestation over a 15-year period. Metadata of papers were exported (...) from PubMed®, and both relevance and relatedness of terms in different time frames were computed using VOSviewer. Co-occurrence graphs were used to visualize results. The development of exemplary terms over time was plotted separately. The number of research papers on mental health and environmental challenges is growing in a linear fashion. Major topics are climate change, chemical pollution, including psychiatric medication in wastewater, and neurobiological effects. Research on specific psychiatric syndromes and diseases, particularly on their ethical and social aspects is less prominent. There is a growing body of research literature on links between mental health, climate change, pollution, and deforestation. This research provides a graphic overview to mental healthcare professionals and political stakeholders. Social and ethical aspects of the climate change-mental health link have been neglected, and more research is needed. (shrink)

In his account of scientific revolutions, Thomas Kuhn suggests that after a revolutionary change of theory, it is as if scientists are working in a different world. In this paper, we aim to show that the notion of world change is insightful. We contrast the reporting of the discovery of neon in 1898 with the discovery of hafnium in 1923. The one discovery was made when elements were identified by their atomic weight; the other discovery was made after (...) scientists came to classify elements by their atomic number. By considering two instances of the reporting of the discovery of a new chemical element 25 years apart, we argue that it becomes clear how chemists can be said to have been responding to different worlds as a result of the change in the concept of a chemical element. They saw, did, and reported different things as they conducted their research on the new chemical elements. (shrink)

Travelling waves crossing the nervous networks at mesoscopic/macroscopic scales have been correlated with different brain functions, from long-term memory to visual stimuli. Here we investigate a feasible relationship between wave generation/propagation in recurrent nervous networks and a physical/chemical model, namely the Belousov–Zhabotinsky reaction. Since BZ’s nonlinear, chaotic chemical process generates concentric/intersecting waves that closely resemble the diffusive nonlinear/chaotic oscillatory patterns crossing the nervous tissue, we aimed to investigate whether wave propagation of brain oscillations could be described in terms (...) of BZ features. We compared experimentally detected oscillations during the spontaneous activity of the brain with BZ-like concentric waves simulated by a recently introduced artificial network. The observed overlap and agreement between simulated and measured oscillatory patterns suggests that changes in cortical areas’ neural activity might be described in terms of a recognizable diffusion pattern. We describe biological plausibility, benefits and limits of our approach and discuss the relationship among BZ-like networks, Pandemonium-like architectures and the spontaneous activity of the brain. ER -. (shrink)

In this article I think through Black feminism and queer theory to critically analyze toxicology. I focus on toxicology's conception of endocrine-disrupting chemicals, a class of toxicants that can cause epigenetic changes leading to inheritable health issues. I suggest that Black feminist interventions are particularly necessary for the study of toxicants because multiply marginalized populations are disproportionately more exposed to EDCs. The structural preconditions that generate this uneven, racialized, and sexualized toxic body-burden threaten to turn cultural constructions of race and (...) sex into biological realities. My discursive analysis of key scientific texts on toxicology, EDCs, and epigenetics underscores how Eurocentric biases and eugenic logics permeate and co-constitute biochemical matter. I further argue that these texts’ un/articulated norms regarding the human, sexual behavior, and evolutionary fitness undermine the usefulness of toxicological assessments for environmental justice. I close by urging scientist scholar-activists to reconceive the study of toxicants. A Black feminist approach to toxicity, I suggest, would not only situate chemical exposures in their sociopolitical contexts, but also radically revision what it means to be human. (shrink)

Nowadays, some of the things that are ḥarāmto be consumed, such as lard, its derivatives and alcohol are used as additives or additional nutrients in products, namely food and cosmetics that people use widely in daily life. The provision of these products, which are accepted as najis(impure), stands in front of us as one of the actual fiqh problems. In order to produce an accurate solution in this regard, the reaction condition and the level of dissolution in the product must (...) be determined. In this article, the level of mutanajjis (contamination) of the products that najisthings transforms through istihlāk(physical change) and the provision (hukm) of benefits from such things are examined. The research covers the discussions in the classical period regarding the provision of things, which included najāsah(impurity) and underwent physical change as well as the evaluations of contemporary Islamic jurists. The aim of this study is to contribute to the researches, which will be carried out to determine the provision of products containing ḥarāmelements. As the production is carried out on an industrial scale, such studies are important today in terms of the establishment of “ḥalāl” sensitivity and meeting the needs of people who have this sensitivity to learn the provision of such products.SummaryNowadays, in various sectors, especially food, feed, cosmetics, health and clothing industries, for the purposes of reducing the cost of the product, extending the shelf life, making the product more attractive in terms of color, consistency and aroma, many substances are added to the main material. The fact that some of the substances added are ḥarām(forbidden) such as blood, lard, pest, and ethyl alcohol require the subject to be considered in terms of fiqh. It is important to clarify two issues in order to reach a healthy result in the studies aiming to determine the provision (ḥukm) of the products that are mixed with najis(impure) substance. One of them is the determination of the level of istihlāk(physical change) in the mutanajjis(contamination) things. The second is the determination of the basic principles to be used in determining the provision of the things which najāsahhas undergone the physical change in. In this study conducted within the scope of this purpose and method, the hadīthsrelated to two different issues that are directly related to the subject have been evaluated as the basic textual basis. These are narrations about the cleanliness and pollution status of the contaminated water, and about the availability of fats and oils, which the dead mouse is seen in. It is stated in the narrations about the condition of the water that najāsah involved in, the water will not be najisunless its smell, taste or color changes because of the falling najāsahin it. According to this hadith, which shows the change of description as a measure, the fuqahāʾ(jurists) came to a consensus on the fact that water, which one of its characteristics changed because of najāsahwould be considered mutanajjis. When thishadithis evaluated together with the narrations that indicate the small amount of water is contaminated because of najāsah, in fact, it is seen that while the water is considered to be clean-najis, the situation of the water being affected from najāsahis taken as the basis and aimed to protect human health against the dirty water. At the time when there were not any one of today's microbiological analysis laboratories, the way to understand the pollution status of water was to see if the smell, color and taste of the water changed while taking the amount of the water into account. Since the rate of foreign matter in the water, the level of pollution and the health status of the water can be determined correctly in the laboratory today, operating the modern techniques as well as the measure of qualification change will be appropriate for the purpose of the hadīthsmentioned.In the narrations about the state of the fat, which the dead mouse is found in, it is seen that different operations are requested depending on the fat being solid or liquid. If the fat is liquid, different instructions have been made such as its being poured or used in lighting. Mālikīs, Shāfiʿīs, and Ḥanbalīfaqīhs (jurists) of the first period have ruled that liquids such as vinegar, milk and honey are mutanajjis, whether they are in little quantity or not, and whether their descriptions are changed or not, claiming that the amount of oil and the degree of impact on the dirt is not declared in the hadīths. The Ḥanafīs adopted the provision in the narrations mentioned pointing to a small amount of liquid oil and considered the measure of description change for a large amount of liquid valid. Ẓāhirīs, Ibn Taymiyyah and some of the faqīhsargued that the liquids which one cannot feel the color, taste or smell of the najāsahin are clean, regardless of the amount.These three approaches are open to criticism because the first is limited only to the literal meaning in the narrations and neglects the aims, and the second ignored the non-water fluids’ ability to hide the descriptions of the substance added to them, and the third evaluates the mustahlak substance (that has undergone a physical change) as if it had been istiḥālah(chemically changed). When the narrations related to the subject are examined, it is understood that while the usage of the liquid fat which the dead mouse was seen in as the food was prohibited, in fact, it was based on the foresight that all of the fat is affected by the mouse. It appears to have been ruled out that only the part polluted is the part affected by thenajāsahfor the fact that after the removal of the mouse and the environment from the solid oil exposed to the same contamination, the rest is allowed to be eaten. According to this, it is possible to say that the measure of mutanajjisin the things that affected by najāsahis in the degree of spreading of najāsah.Nowadays it is possible to determine the presence of najisthings in the main material, which is used as additive or addition, by the level of effect of these substances in the product, as well as by the assays. If the najissubstances used for purposes such as brightness, taste, consistency and extending shelf life, perform the expected functions, it means that they protect their presence in the product effectively. In fact, it should be acknowledged that these substances continue to exist effectively in the product, if they perform the targeted function without any chemical change, even the ratio in the product is low or the color, taste and odor are eliminated during the mixture.The faqīhswhile differed in opinion about the mutanajjisof things that the najāsahhad undergone physical changes in, they, in concert, considered the substances, which were not cleaned or could not be cleansed from which that they accept as mutanajjisby their own measurements, khabīs(disgusting), and have accepted the people’s eating of them as ḥarām. Likewise, they did not allow such things to be used in any way touching the body, clothing and containers. They have evaluated the narrations, which requires the spilth the fat that the dead mouse was seen in, as the main basis in this issue. On the other hand, about the use of the mutanajjisthings outside the human consumption area and in such a way that the clothes and body would not be contaminated; the majority of thefaqīhs preferred the mubāḥ provision. They have put forth the narrations as the basis that recommends the usage of the liquid oil in which the mouse was fallen in lighting. These approaches of the fuqahāʾabout the effect of the istihlākon the provision of making use of the things that affected by najāsahare of worth as the basic principles on the subject. It is possible to say that it is not permissible to consume food products containing lard or pork gelatin, and the chicken that has been torn apart while being left in hot water in order to pluck its feathers, and the egg which becomes mutanajjisfor it is boiled up with thenajāsahon, and the using of cosmetic products containing lard when today’s industrial products are evaluated in accordance with these principles. If taken the general opinion that defends that the ethyl alcohol is najis as the basis, the carbonated soft drinks, which are added to alcohol, can also be evaluated in this context. (shrink)

Summary James Watt (1736–1819) is best known as an engineer who dramatically improved the efficiency of the steam engine. What we take to be his chemical interests are conventionally seen as peripheral to his main line of work. He is usually treated as a chemist in three main contexts: his ‘practical’ chemical work relating to chlorine bleaching, varnishes, pottery, and so on; his work with Thomas Beddoes on the medicinal uses of various ‘airs’; his, much disputed, claim as (...) a chemical discoverer in the case of the composition of water. In this paper, I argue that Watt himself, and his contemporaries, saw the centrepiece of his steam engine work—the separate condenser—as a chemical invention. I also suggest more broadly that Watt understood the steam engine as a chemical device. For Watt and his Scottish friends, the study of steam and heat was a chemical enquiry. The subsequent changes in the place of heat in chemical enquiry in the early nineteenth century led to a reclassification of Watt's chemical investigations as ‘physics’. This, in turn, produced the sharp separation of his chemical and engineering activities characteristic of modern historiography. Watt's steam engine, which is usually placed in the lineage of machines understood as heat engines, and explained by the laws of thermodynamics, is better seen in context as a chemical device. Watt's ‘indicator diagram’ is reassessed in the light of this. (shrink)

Artificial intelligence can be a game changer to address the global challenge of humanity-threatening climate change by fostering sustainable development. Since chemical research and development lay the foundation for innovative products and solutions, this study presents a novel chemical research and development process backed with artificial intelligence and guiding ethical principles to account for both process- and outcome-related sustainability. Particularly in ethically salient contexts, ethical principles have to accompany research and development powered by artificial intelligence to promote (...) social and environmental good and sustainability while preventing any harm for all stakeholders affected. (shrink)

After Lavoisier's execution, the leading French chemists were Antoine-François Fourcroy , Louis-Bernard Guyton de Morveau and Claude-Louis Berthollet . At the beginning of the nineteenth century, Berthollet introduced a new conception of chemical change that challenged the theory of elective affinities which had dominated chemistry for nearly a hundred years. Berthollet's new affinities raised controversy among chemists and had to coexist with the firmly established theory of elective affinities. Apart from the public debate in research articles, Berthollet's affinities (...) also had to compete with the influence of Fourcroy and his school in the textbook market. This paper seeks to assess the extent to which French textbooks published at the beginning of the nineteenth century were committed to Berthollet's innovation, and how they contributed to its marginalization. (shrink)

This essay has three interrelated goals: first, to sketch the basic contours of Georg Helm's energetic theory; second, to describe his attempt in his Grundzüge der mathematischen Chemie. Energetik der chemischen Erscheinungen (1894) to apply that theory to the (then) burgeoning new field of physical chemistry. This is of some interest historically, since Helm's work is the most sophisticated attempt to develop the whole of physical chemistry mathematically from an energetic point of view. Nevertheless, it is seriously flawed technically. Moreover, (...) that development is inconsistent with Helm's considered way of thinking about energy and energetic change. So a third goal of the essay is to explain his mature conception of the goal of energetics. I begin with a brief introduction to Helm and energetics, and end with some general conclusions about the success of Helm's mathematische Chemie. (shrink)