Perhaps the hottest topic in the philosophy of chemistry is that of the relationship between chemistry and physics. The problem finds one of its main manifestations in the debate about the nature of molecular structure, given by the spatial arrangement of the nuclei in a molecule. The traditional strategy to address the problem is to consider chemical cases that challenge the definition of molecular structure in quantum–mechanical terms. Instead of taking that top-down strategy, in this paper we face the problem (...) of the reduction of molecular structure to quantum mechanics from a bottom-up perspective: our aim is to show how the theoretical peculiarities of quantum mechanics stand against the possibility of molecular structure, defined in terms of the spatial relations of the nuclei conceived as individual localized objects. We will argue that, according to the theory, quantum “particles” are not individuals that can be identified as different from others and that can be reidentified through time; therefore, they do not have the ontological stability necessary to maintain the relations that can lead to a spatially definite system with an identifiable shape. On the other hand, although quantum chemists use the resources supplied by quantum mechanics with successful results, this does no mean reduction: their “approximations” add certain assumptions that are not justified in the context of quantum mechanics or are even inconsistent with the very formal structure of the theory. (shrink)

In the present paper we address the problem of optical isomerism embodied in the socalled “Hund’s paradox”, which points to the difficulty to account for chirality by means of quantum mechanics. In particular, we explain the answer to the problem proposed by the theory of decoherence. The purpose of this article is to challenge this answer on the basis of a conceptual analysis of the phenomenon of decoherence, that reveals the limitations of the theory of decoherence to solve the difficulties (...) posed by optical isomerism and, in general, by quantum measurement. (shrink)

In the present paper we address the problem of optical isomerism embodied in the socalled “Hund’s paradox”, which points to the difficulty to account for chirality by means of quantum mechanics. In particular, we explain the answer to the problem proposed by the theory of decoherence. The purpose of this article is to challenge this answer on the basis of a conceptual analysis of the phenomenon of decoherence, that reveals the limitations of the theory of decoherence to solve the difficulties (...) posed by optical isomerism and, in general, by quantum measurement. (shrink)

The modal-Hamiltonian interpretation belongs to the modal family of interpretations of quantum mechanics. By endowing the Hamiltonian with the role of selecting the subset of the definite-valued observables of the system, it accounts for ideal and non-ideal measurements, and also supplies a criterion to distinguish between reliable and non-reliable measurements in the non-ideal case. It can be reformulated in an explicitly invariant form, in terms of the Casimir operators of the Galilean group, and the compatibility of the MHI with the (...) theory of decoherence has been proved. Nevertheless, perhaps its main advantage in the eyes of a scientist is given by its several applications to well-known physical situations, leading to results compatible with experimental evidence. The purpose of this paper is to add a new application to the list: the case of optical isomerism, which is a central issue for the philosophy of physics and of chemistry since it points to the core of the problem of the relationship between physics and chemistry. Here it will be shown that the MHI supplies a direct and physically natural solution to the problem, a solution that does not require putting classical assumptions in “by hand.”. (shrink)

Christopher Timpson proposes a deflationary view about information, according to which the term ‘information’ is an abstract noun and, as a consequence, information is not part of the material contents of the world. The main purpose of the present article consists in supplying a critical analysis of this proposal, which will lead us to conclude that information is an item even more abstract than what Timpson claims. From this view, we embrace a pluralist stance that recognizes the legitimacy of different (...) interpretations of the concept of information. (shrink)

In a recent article entitled “The problem of molecular structure just is the measurement problem”, Alexander Franklin and Vanessa Seifert argue that insofar as the quantum measurement problem is solved, the problems of molecular structure are resolved as well. The purpose of the present article is to show that such a claim is too optimistic. Although the solution of the quantum measurement problem is relevant to how the problem of molecular structure is faced, such a solution is not sufficient to (...) account for the structure of molecules as understood in the field of chemistry. (shrink)

Focusing on Shannon information, this article shows that, even on the basis of the same formalism, there may be different interpretations of the concept of information, and that disagreements may be deep enough to lead to very different conclusions about the informational characterization of certain physical situations. On this basis, a pluralist view is argued for, according to which the concept of information is primarily a formal concept that can adopt different interpretations that are not mutually exclusive, but each useful (...) in a different specific context. (shrink)

The interpretation of the concept of reduced state is a subtle issue that has relevant consequences when the task is the interpretation of quantum mechanics itself. The aim of this paper is to argue that reduced states are not the quantum states of subsystems in the same sense as quantum states are states of the whole composite system. After clearly stating the problem, our argument is developed in three stages. First, we consider the phenomenon of environment-induced decoherence as an example (...) of the case in which the subsystems interact with each other; we show that decoherence does not solve the measurement problem precisely because the reduced state of the measuring apparatus is not its quantum state. Second, the non-interacting case is illustrated in the context of no-collapse interpretations, in which we show that certain well-known experimental results cannot be accounted for due to the fact that the reduced states of the measured system and the measuring apparatus are conceived as their quantum states. Finally, we prove that reduced states are a kind of coarse-grained states, and for this reason they cancel the correlations of the subsystem with other subsystems with which it interacts or is entangled. (shrink)

Given the impressive success of environment-induced decoherence, nowadays no interpretation of quantum mechanics can ignore its results. The modal-Hamiltonian interpretation has proved to be effective for solving several interpretative problems, but since its actualization rule applies to closed systems, it seems to stand at odds with EID. The purpose of this article is to show that this is not the case: the states einselected by the interaction with the environment according to EID are the eigenvectors of an actual-valued observable belonging (...) to the preferred context selected by the MHI. (shrink)

Although during the last decades the philosophy of chemistry has greatly extended its thematic scope, the main difficulties appear in the attempt to link the chemical description of atoms and molecules and the description supplied by quantum mechanics. The aim of this paper is to analyze how the difficulties that threaten the continuous conceptual link between molecular chemistry and quantum mechanics can be overcome or, at least, moderated from the perspective of BM. With this purpose, in “The quantum-mechanical challenges” section (...) the foundational incompatibility between chemical and SQM descriptions will be briefly recalled. “Bohmian mechanics” section will be devoted to explain the main features of BM. In “Empirical equivalence and underdetermination” section, the consequences of the empirical equivalence between SQM and BM will be discussed. Finally, in the Conclusion, we will stress the scope of the obtained conclusions and the philosophical difficulties that still remain even after adopting BM for foundational purposes. (shrink)

Some authors, inspired by the theoretical requirements for the formulation of a quantum theory of gravity, proposed a relational reconstruction of the quantum parameter-time—the time of the unitary evolution, which would make quantum mechanics compatible with relativity. The aim of the present work is to follow the lead of those relational programs by proposing a relational reconstruction of the event-time—which orders the detection of the definite values of the system’s observables. Such a reconstruction will be based on the modal-Hamiltonian interpretation (...) of quantum mechanics, which provides a clear criterion to select which observables acquire a definite value and to specify in what situation they do so. (shrink)

Although during the last decades the philosophy of chemistry has greatly extended its thematic scope, the main difficulties appear in the attempt to link the chemical description of atoms and molecules and the description supplied by quantum mechanics. The aim of this paper is to analyze how the difficulties that threaten the continuous conceptual link between molecular chemistry and quantum mechanics can be overcome or, at least, moderated from the perspective of BM. With this purpose, in “The quantum-mechanical challenges” section (...) the foundational incompatibility between chemical and SQM descriptions will be briefly recalled. “Bohmian mechanics” section will be devoted to explain the main features of BM. In “Empirical equivalence and underdetermination” section, the consequences of the empirical equivalence between SQM and BM will be discussed. Finally, in the Conclusion, we will stress the scope of the obtained conclusions and the philosophical difficulties that still remain even after adopting BM for foundational purposes. (shrink)

In the last years, the surprising bosonic behavior that a many-fermion system may acquire has raised interest because of theoretical and practical reasons. This trans-statistical behavior is usually considered to be the result of approximation modeling methods generally employed by physicists when faced with complexity. In this paper, we take a tensor product structure and an ontology of properties approach and provide two versions of a toy model in order to argue that trans-statistical behavior allows for a realistic interpretation.

According to the environment-induced approach to decoherence, the split of the Universe into the degrees of freedom which are of direct interest to the observer and the remaining degrees of freedom is absolutely essential for decoherence. However, the EID approach offers no general criterion for deciding where to place the “cut” between system and environment: the environment may be “external” or “internal”. The main purpose of this paper is to argue that decoherence is a relative phenomenon, better understood from a (...) closed-system perspective according to which the split of a closed quantum system into an open subsystem and its environment is just a way of selecting a particular space of relevant observables of the whole closed system. In order to support this claim, we shall consider the results obtained in a natural generalization of the simple spin-bath model usually studied in the literature. Our main thesis will lead us to two corollaries. First, the problem of identifying the system that decoheres is actually a pseudo-problem, which vanishes as soon as one acknowledges the relative nature of decoherence. Second, the usually supposed link between decoherence and energy dissipation is misguided. As previously pointed out, energy dissipation and decoherence are different phenomena, and we shall argue for this difference on the basis of the relative nature of decoherence. (shrink)

Two recent papers appeared in FOOP disagree regarding the role played by decoherence in quantum physics. On the one hand, Elise Crull considers that decoherence, by itself, solves many conceptual problems in quantum physics, with no need of interpretative considerations. On the other hand, Antonio Vassallo and Michael Esfeld reply by correctly claiming that, although decoherence is a powerful tool to deal with conceptual problems, it does not dispense us from interpreting the formalism. In this brief note we want to (...) contribute to the debate with further considerations from another viewpoint. In this work we show that the discussions "decoherence versus interpretation" revolve around whether the theory of decoherence requires interpretive considerations to solve the measurement problem. In general, those discussions take the theory of decoherence for granted, as if it would not involve any difficulty. Therefore, they commonly focus on the "interpretation" wing: even in the case that the open system decoheres in a given basis, the whole closed system is still in a superposition and, thus, without an adequate interpretation, it cannot be said that the observables defined by that basis behave classically. Here we have focused on the "decoherence" wing: given the conceptual challenges that the theory must face and the alternative approaches to the orthodox view, the understanding of the very phenomenon of decoherence still requires a great deal of interpretive work. (shrink)

The problem of the reduction of chemistry to physics has been traditionally addressed in terms of classical structural chemistry and standard quantum mechanics. In this work, we will study the problem from the perspective of the Quantum Theory of Atoms in Molecules, proposed by Richard Bader in the nineties. The purpose of this article is to unveil the role of QTAIM in the inter-theoretical relations between chemistry and physics. We argue that, although the QTAIM solves two relevant obstacles to reduction (...) by providing a rigorous definition of chemical bond and of atoms in a molecule, it appeals to concepts that are unacceptable in the quantum–mechanical context. Therefore, the QTAIM fails to provide the desired reduction. On the other hand, we will show that the QTAIM is more similar to Bohmian mechanics and that the basic elements of both theories are closely related. (shrink)

Although Bohr’s Correspondence Principle (CP) played a central role in the first days of quantum mechanics, its original version seems to have no present-day relevance. The purpose of this article is to show that the CP, with no need of being interpreted in terms of the quantum-to-classical limit, still plays a relevant role in the understanding of the relationships between the classical and the quantum domains. In particular, it will be argued that a generic version of the CP is very (...) helpful in elucidating the physical meaning of the phenomenon of quantum decoherence. (shrink)

In April 2016, Daniela Frauchiger and Renato Renner published an article online in which they introduce a Gedankenexperiment that led them to conclude that single-world interpretations of quantum theory cannot be self-consistent. In a new version of the paper, published in September 2018, the authors moderate their original claim by concluding that quantum theory cannot be extrapolated to complex systems, at least not in a straightforward manner. The purpose of this short article is to clarify the core of the F-R (...) argument, in order to show how the contradiction is obtained. On the basis of this clarification, we argue that the result of the F-R argument has been overestimated and should be reconsidered from a more cautious perspective. (shrink)

In this work we present a dynamical approach to quantum logics. By changing the standard formalism of quantum mechanics to allow non-Hermitian operators as generators of time evolution, we address the question of how can logics evolve in time. In this way, we describe formally how a non-Boolean algebra may become a Boolean one under certain conditions. We present some simple models which illustrate this transition and develop a new quantum logical formalism based in complex spectral resolutions, a notion that (...) we introduce in order to cope with the temporal aspect of the logical structure of quantum theory. (shrink)

Recent discussions about the microstructure of materials generally focus on the ontological aspects of the molecular structure. However, there are many types of substances that cannot be studied by means of the concept of molecule, for example, salts. For the quantum treatment of these substances, a new particle, called phonon, is introduced. Phonons are generally conceived as a pseudo-particle, that is, a mathematical device necessary to perform calculations but which does not have a “real” existence. In this context, the aim (...) of this paper will be to analyze the ontological status of phonons. For such purposes we will critically analyze the arguments that would account for the presumed nonexistence of phonons. Finally, having already demonstrated that there are not enough reasons to consider phonons as non-existing entities, we will explore some possibilities that allow us to elucidate their ontological status. (shrink)

The so-called classical limit of quantum mechanics is generally studied in terms of the decoherence of the state operator that characterizes a system. This is not the only possible approach to decoherence. In previous works we have presented the possibility of studying the classical limit in terms of the decoherence of relevant observables of the system. On the basis of this approach, in this paper we introduce the classical limit from a logical perspective, by studying the way in which the (...) logical structure of quantum properties corresponding to relevant observables acquires Boolean characteristics. (shrink)

A los cristales se los describe como a una red de átomos que puede vibrar alrededor de su posición de equilibrio. Sin embargo, el hecho de que la energía de estas ondas esté cuantificada sugiere una analogía con el campo electromagnético. En analogía con el fotón se define al fonón. Generalmente se concibe al fonón como a una cuasi-partícula, es decir, como a un instrumento matemático útil en los cálculos pero sin una existencia propia. En este trabajo estudiamos el estatuto (...) ontológico del fonón y argumentaremos en favor de la idea de considerarlo como una partícula real. (shrink)

Recent discussions about the microstructure of materials generally focus on the ontological aspects of the molecular structure. However, there are many types of substances that cannot be studied by means of the concept of molecule, for example, salts. For the quantum treatment of these substances, a new particle, called phonon, is introduced. Phonons are generally conceived as a pseudo-particle, that is, a mathematical device necessary to perform calculations but which does not have a "real" existence. In this context, the aim (...) of this paper will be to analyze the ontological status of phonons. For such purposes we will critically analyze the arguments that would account for the presumed nonexistence of phonons. Finally, having already demonstrated that there are not enough reasons to consider phonons as non-existing entities, we will explore some possibilities that allow us to elucidate their ontological status. (shrink)

The difficult issues related to the interpretation of quantum mechanics and, in particular, the “measurement problem” are revisited using as motivation the process of generation of structure from quantum fluctuations in inflationary cosmology. The unessential mathematical complexity of the particular problem is bypassed, facilitating the discussion of the conceptual issues, by considering, within the paradigm set up by the cosmological problem, another problem where symmetry serves as a focal point: a simplified version of Mott’s problem.

The problem of the 3N dimensions of the wave function is of particular interest in the philosophy of physics. In this work, we will recall the main positions about the nature and dimensionality of the wave function and we will introduce a new perspective, coming from quantum chemistry. For this, we will bring to light the formal operations that underlie the independent electron approximation. On this basis, we will point out how quantum chemistry can offer new arguments that contribute to (...) the debate about the ontology of wave function. (shrink)

The more common scheme to explain the classical limit of quantum mechanics includes decoherence, which removes from the state the interference terms classically inadmissible since embodying non-Booleanity. In this work we consider the classical limit from a logical viewpoint, as a quantum-to-Boolean transition. The aim is to open the door to a new study based on dynamical logics, that is, logics that change over time. In particular, we appeal to the notion of hybrid logics to describe semiclassical systems. Moreover, we (...) consider systems with many characteristic decoherence times, whose sublattices of properties become distributive at different times. (shrink)

In his recent Editorial Article, Jeffrey Seeman calls for the promotion of collaborative work among different disciplines, focusing on the case of the interaction between chemistry, the history of chemistry and the philosophy of chemistry. From a general viewpoint, it is difficult to disagree with this claim; moreover, the interest of scientists in the history and the philosophy of science is always welcome. However, the devil is in the details: there are several points that, we think, must be discussed more (...) carefully with the aim of arriving at far-reaching conclusions. (shrink)

En este trabajo se discuten los problemas que se presentan en el modelo de medición basado en decoherencia. Debido a que el origen de las críticas a este modelo se encuentra en el uso de los estados reducidos de sistemas abiertos, se propone un cambio de enfoque. Por un lado, la adopción de la perspectiva de los sistemas cerrados permite dar cuenta de procesos irreversibles en sistemas que no interactúan con un ambiente. Por otro lado, el enfoque de los valores (...) medios hace posible el estudio de la evolución de los sistemas cuánticos sin apelar a sus estados. La combinación de ambos enfoques da como resultado una formulación de la decoherencia cuántica, cuya aplicación al problema de la medición supera las críticas del enfoque original. (shrink)

According to classical molecular chemistry, molecules have a structure, that is, they are sets of atoms with a definite arrangements in space and held together by chemical bonds. The concept of molecular structure is central to modern chemical thought given its impressive predictive power. It is also a very useful concept in chemistry education, due to its role in the rationalization and visualization of microscopic phenomena. However, such a concept seems to find no place in the ontology described by quantum (...) mechanics, since it appeals to classical notions such as the position of the atomic nuclei or the individuality of electrons. Although this problem has attracted the attention of several authors, the discussion is far from settled. Some authors adopt an explicitly reductionist position and advocate to reconstruct the concept of molecular structure within the framework of the quantum theory. Others, although acknowledging the conceptual discontinuity between quantum mechanics and molecular chemistry, keep the hope of future reduction alive. From an explicitly non-reductionist position, on the contrary, others authors conceive molecular structure as an emergent phenomenon. The purpose of this article is to propose a different line of argumentation to address this problem. By contrast to reduction and emergence, the admission of a multiplicity of ontologies, not necessarily linked by hierarchical connections, cancels the need of finding a relation of dependence between the molecular level and the quantum level. This ontologically pluralist position can be applied to the issue of molecular structure, in order to argue that it is possible to admit the existence of structure in the ontology of molecular chemistry, in spite of the fact that it does not exist in the quantum world. (shrink)

In this paper it will be argued that any realist interpretation of quantum mechanics intending to preserve the objectivity of the set of the definite-valued observables should require such a set to be invariant under the symmetry group of the theory. In particular, it will be shown that the natural way to reach this goal is to appeal to the Casimir operators of the Galilean group. Additionally, this idea will be generalized in two ways: by selecting the definite-valued observables of (...) a system in quantum field theory as those represented by the Casimir operators of the Poincaré group, and by extending the strategy to gauge symmetries. (shrink)

En los últimos años, el comportamiento bosónico que un sistema de fermiones puede exhibir ha despertado el interés de los físicos. En este trabajo, se adopta un enfoque basado en estructuras producto tensorial y se asume una ontología de propiedades para argumentar en favor de la relatividad de la noción de identidad estadística y en favor de una interpretación realista del comportamiento trans-estadístico.

Although during the last decades the philosophy of chemistry has greatly extended its thematic scope, the main difficulties appear in the attempt to link the chemical description of atoms and molecules and the description supplied by quantum mechanics. The aim of this paper is to analyze how the difficulties that threaten the continuous conceptual link between molecular chemistry and quantum mechanics can be overcome or, at least, moderated from the perspective of BM. With this purpose, in “The quantum-mechanical challenges” section (...) the foundational incompatibility between chemical and SQM descriptions will be briefly recalled. “Bohmian mechanics” section will be devoted to explain the main features of BM. In “Empirical equivalence and underdetermination” section, the consequences of the empirical equivalence between SQM and BM will be discussed. Finally, in the Conclusion, we will stress the scope of the obtained conclusions and the philosophical difficulties that still remain even after adopting BM for foundational purposes. (shrink)

We discuss generalized pobabilistic models for which states not necessarily obey Kolmogorov's axioms of probability. We study the relationship between properties and probabilistic measures in this setting, and explore some possible interpretations of these measures.

The aim of the present paper is to supply an elucidation of the concept of information in the communicational context. For this purpose, two traditional interpretations of the concept of information, the epistemic and the physical interpretations, will be distinguished, and their specific problems will be considered. In particular, whereas the epistemic interpretation misses an essential feature of communication, the physical interpretation faces difficulties in the quantum domain. The final goal will be to argue that the difficulties of the physical (...) interpretation can be overcome by means of a manipulability conception of causation. (shrink)

Combining physics and philosophy, this is a uniquely interdisciplinary examination of quantum information science. Suitable as both a discussion of the conceptual and philosophical problems of this field and a comprehensive stand-alone introduction, this book will benefit both experienced and new researchers in quantum information and the philosophy of physics.

La interpretación modal-hamiltoniana fue introducida para resolver ciertos problemas de interpretación vinculados a su ontología y a la medición cuántica. Su regla de actualización establece que todo sistema cerrado tiene su energía bien definida, y debido a la indeterminación entre la energía y el tiempo esto plantea un interrogante respecto a la situación temporal de estos sistemas. En este trabajo se analiza el problema del tiempo en sistemas cerrados y se propone la reconstrucción de un tiempo relacional compatible con la (...) perspectiva holista. (shrink)