I argue that there are two distinct approaches to understanding reduction: the ontology-first approach and the theory-first approach. They concern the relation between ontological reduction and inter-theoretic reduction. Further, I argue for the significance of this distinction by demonstrating that either one or the other approach has been taken as an implicit assumption in, and has in fact shaped, our understanding of what statistical mechanics is. More specifically, I argue that the Boltzmannian framework of (...) statistical mechanics assumes and relies on the ontology-first approach, whereas the Gibbsian framework should assume the theory-first approach. -/- . (shrink)

An important contemporary version of Boltzmannian statistical mechanics explains the approach to equilibrium in terms of typicality. The problem with this approach is that it comes in different versions, which are, however, not recognized as such and not clearly distinguished. This article identifies three different versions of typicality‐based explanations of thermodynamic‐like behavior and evaluates their respective successes. The conclusion is that the first two are unsuccessful because they fail to take the system's dynamics into account. (...) The third, however, is promising. I give a precise formulation of the proposal and present an argument in support of its central contention. †To contact the author, please write to: Department of Philosophy, Logic, and Scientific Method, London School of Economics, Houghton Street, London WC2A 2AE, England; e‐mail: [email protected]. (shrink)

In discussions of the foundations of statistical mechanics, it is widely held that the Gibbsian and Boltzmannian approaches are incompatible but empirically equivalent; the Gibbsian approach may be calculationally preferable but only the Boltzmannian approach is conceptually satisfactory. I argue against both assumptions. Gibbsian statistical mechanics is applicable to a wide variety of problems and systems, such as the calculation of transport coefficients and the statistical mechanics and (...) thermodynamics of mesoscopic systems, in which the Boltzmannian approach is inapplicable. And the supposed conceptual problems with the Gibbsian approach are either misconceived, or apply only to certain versions of the Gibbsian approach, or apply with equal force to both approaches. I conclude that Boltzmannian statistical mechanics is best seen as a special case of, and not an alternatve to, Gibbsian statistical mechanics. (shrink)

In this paper I will argue that the two main approaches to statistical mechanics, that of Boltzmann and Gibbs, constitute two substantially different theoretical apparatuses. Particularly, I defend that this theoretical split must be philosophically understood as a separation of epistemic functions within this physical domain: while Boltzmannians are able to generate powerful explanations of thermal phenomena from molecular dynamics, Gibbsians can statistically predict observable values in a highly effective way. Therefore, statistical mechanics is a counterexample (...) to Hempel's (1958) symmetry thesis, where the predictive capacity of a theory is directly correlated with its explanatory potential and vice versa. (shrink)

There are two theoretical approaches in statistical mechanics, one associated with Boltzmann and the other with Gibbs. The theoretical apparatus of the two approaches offer distinct descriptions of the same physical system with no obvious way to translate the concepts of one formalism into those of the other. This raises the question of the status of one approach vis-à-vis the other. We answer this question by arguing that the Boltzmannian approach is a fundamental theory while (...) Gibbsian statistical mechanics is an effective theory, and we describe circumstances under which Gibbsian calculations coincide with the Boltzmannian results. We then point out that regarding GSM as an effective theory has important repercussions for a number of projects, in particular attempts to turn GSM into a nonequilibrium theory. (shrink)

In Boltzmannian statistical mechanics macro-states supervene on micro-states. This leads to a partitioning of the state space of a system into regions of macroscopically indistinguishable micro-states. The largest of these regions is singled out as the equilibrium region of the system. What justifies this association? We review currently available answers to this question and find them wanting both for conceptual and for technical reasons. We propose a new conception of equilibrium and prove a mathematical theorem which establishes (...) in full generality -- i.e. without making any assumptions about the system's dynamics or the nature of the interactions between its components -- that the equilibrium macro-region is the largest macro-region. We then turn to the question of the approach to equilibrium, of which there exists no satisfactory general answer so far. In our account, this question is replaced by the question when an equilibrium state exists. We prove another -- again fully general -- theorem providing necessary and sufficient conditions for the existence of an equilibrium state. This theorem changes the way in which the question of the approach to equilibrium should be discussed: rather than launching a search for a crucial factor, the focus should be on finding triplets of macro-variables, dynamical conditions, and effective state spaces that satisfy the conditions of the theorem. (shrink)

This pair of articles provides a critical commentary on contemporary approaches to statistical mechanical probabilities. These articles focus on the two ways of understanding these probabilities that have received the most attention in the recent literature: the epistemic indifference approach, and the Lewis-style regularity approach. These articles describe these approaches, highlight the main points of contention, and make some attempts to advance the discussion. The first of these articles provides a brief sketch of statistical mechanics, (...) and discusses the indifference approach to statistical mechanical probabilities. (shrink)

This pair of articles provides a critical commentary on contemporary approaches to statistical mechanical probabilities. These articles focus on the two ways of understanding these probabilities that have received the most attention in the recent literature: the epistemic indifference approach, and the Lewis-style regularity approach. These articles describe these approaches, highlight the main points of contention, and make some attempts to advance the discussion. The second of these articles discusses the regularity approach to statistical mechanical (...) probabilities, and describes some areas where further research is needed. (shrink)

There are two main theoretical frameworks in statistical mechanics, one associated with Boltzmann and the other with Gibbs. Despite their well-known differences, there is a prevailing view that equilibrium values calculated in both frameworks coincide. We show that this is wrong. There are important cases in which the Boltzmannian and Gibbsian equilibrium concepts yield different outcomes. Furthermore, the conditions under which equilibriums exists are different for Gibbsian and Boltzmannian statistical mechanics. There are, (...) however, special circumstances under which it is true that the equilibrium values coincide. We prove a new theorem providing sufficient conditions for this to be the case. (shrink)

Consider a gas that is adiabatically isolated from its environment and confined to the left half of a container. Then remove the wall separating the two parts. The gas will immediately start spreading and soon be evenly distributed over the entire available space. The gas has approached equilibrium. Thermodynamics (TD) characterizes this process in terms of an increase of thermodynamic entropy, which attains its maximum value at equilibrium. The second law of thermodynamics captures the irreversibility of this process by positing (...) that in an isolated system such as the gas entropy cannot decrease. The aim of statistical mechanics (SM) is to explain the behavior of the gas and, in particular, its conformity with the second law in terms of the dynamical laws governing the individual molecules of which the gas is made up. In what follows these laws are assumed to be the ones of Hamiltonian classical mechanics. We should not, however, ask for an explanation of the second law literally construed. This law is a universal law and as such cannot be explained by a statistical theory. But this is not a problem because we.. (shrink)

In this paper I first argue that the objection which is most commonly levelled against the coarse-graining approach-viz. that it introduces an element of subjectivity into what ought to be a purely objective formalism-is ultimately unfounded. I then proceed to argue that two different objections to the coarse-graining approach indicate that it is an inadequate approach to statistical mechanics. The first objection is based on the fact that the appeal to appearances by the coarse-graining (...) class='Hi'>approach fails to justify the coarse-graining strategy of ignoring the physical differences between so-called quasi-equilibrium distributions and equilibrium distributions. The second objection is centred on the notion of a coarse-grained entropy. I will argue that the required increase in the coarse-grained entropy is obtained by disregarding the dynamical constraints on the system. This undermines the very task statistical mechanics has set out to accomplish, viz. to provide a microdynamical underpinning of thermodynamics. (shrink)

In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann’s analysis, the essence of which I shall review here, is basically correct. The most famous criticisms of Boltzmann’s later work on the subject have little merit. Most twentieth century innovations – such as the identification of the state of a physical system with a probability distribution on its phase space, (...) of its thermodynamic entropy with the Gibbs entropy of , and the invocation of the notions of ergodicity and mixing for the justification of the foundations of statistical mechanics – are thoroughly misguided. (shrink)

In a recent paper, Werndl and Frigg discuss the relationship between the Boltzmannian and Gibbsian framework of statistical mechanics, addressing in particular the question when equilibrium values calculated in both frameworks coincide. In this comment, I point out serious flaws in their work and try to put their results into proper context. I also clarify the concept of Boltzmann equilibrium, the status of the "Khinchin condition" and their connection to the law of large numbers.

I will contrast the two main approaches to the foundations of statistical mechanics: the individualist approach and the ensemblist approach. I will indicate the virtues of each, and argue that the conflict between them is perhaps not as great as often imagined.

In this talk I present the main results from Anta (2021), namely, that the theoretical division between Boltzmannian and Gibbsian statistical mechanics should be understood as a separation in the epistemic capabilities of this physical discipline. In particular, while from the Boltzmannian framework one can generate powerful explanations of thermal processes by appealing to their microdynamics, from the Gibbsian framework one can predict observable values in a computationally effective way. Finally, I argue that this (...) statistical mechanical schism contradicts the Hempelian (1958) thesis that the predictive power of a scientific theory is directly proportional to its explanatory potential, and vice versa. (shrink)

Certain sections ofJosiah Willard Gibbs's thermodynamics papers might be applicable to biological equilibrium and growth, normal or abnormal.Gibbs added terms⌆ Μ i dm i to the differential of the internal energy dε=tdη−pdΝ, where μi=δεδmi is the potential of substancem i , to provide for chemical as well as thermal and mechanical equilibrium. In this article a further generalization is suggested, to include biological equilibrium by adding to de terms of the form GdN, the variableN being the number of cells, where (...) G=δεδN is a “growth potential” that measures exactly the resistance toward spontaneous growth. The functionG, likeΜ i is intensive in nature except for a conversion factor dMdN ,M=⌆m i , affording possible insight into why incipient abnormal growth is often independent of the number of cells. Useful applications might follow from identities between δGδη,δGδv , or δGδmi and δtδN,−δpδN or δμiδN respectively. The following new function is studied, ζ¯=ζ−GN , a natural generalization of theGibbs free energy function ζ, the possibility of measuring it electrically, and comparison of its role with that of ζ for the possible experimental determination ofG. Gibbs's necessary and sufficient conditions for heterogeneous equilibrium ofn components inm phases are generalized and also modified to include broader restraining conditions like ∑mi=1δNj⩾o ,j=1,f,n, the > being characteristic of only living cellular phases. Careful appraisal of the term “biological stability” is followed by new criteria for stability, instability, and limits of stability, in terms of derivatives ofG, with possible medical applications. Three different sections of Gibbs's works tend to indicate that, for a biological phase, lower pressure usually increases its stability. The equation p′′−p′=σ , where σ=surface tension,p′, p′ = pressures,r, r′=radii of curvature, is applied to possible control of tissue growth at interfaces. Methods of altering the equilibrum between three phasesA, B, C by varying the interfacial tensionsσ AB ,σ BC ,σ AC , using relations like AB <σ AC + BC for stability of theA, B interface, suggest different means for shifting biological equilibrium between normal and abnormal cells through the introduction of new third phases at the interface. Various devices are mentioned for possible control of growth through proper channeling of surface or other equivalent forms of energy. (shrink)

It is argued that certain recent advances in the construction of a theory of the collapses of Quantum Mechanical wave functions suggest the possibility of new and improved foundations for statistical mechanics, foundations in which epistemic considerations play no role.

In two recent papers Barry Loewer (2001, 2004) has suggested to interpret probabilities in statistical mechanics as Humean chances in David Lewis’ (1994) sense. I first give a precise formulation of this proposal, then raise two fundamental objections, and finally conclude that these can be overcome only at the price of interpreting these probabilities epistemically.

Thermodynamic macro variables, such as the temperature or volume macro variable, can take on a continuum of allowable values, called thermodynamic macro values. Although referring to the same macro phenomena, the macro variables of Boltzmannian Statistical Mechanics (BSM) differ from thermodynamic macro variables in an important respect: within the framework of BSM the evolution of macro values of systems with finite available phase space is invariably modelled as discontinuous, due to the method of partitioning phase space into (...) macro regions with sharp, fixed boundaries. Conceptually, this is at odds with the continuous evolution of macro values as described by thermodynamics, as well as with the continuous evolution of the micro state assumed in BSM. This discrepancy I call the discontinuity problem. I show how it arises from BSM’s framework and demonstrate its consequences, in particular for the foundational project of reducing thermodynamics to BSM: thermodynamic macro values are shown to not supervene on the corresponding BSM macro values. With supervenience being a conditio sine qua non for the kind of reduction envisaged by the foundational project, the latter is in jeopardy. (shrink)

Why do systems prepared in a non-equilibrium state approach, and eventually reach, equilibrium? An important contemporary version of the Boltzmannian approach to statistical mechanics answers this question by an appeal to the notion of typicality. The problem with this approach is that it comes in different versions, which are, however, not recognised as such, much less clearly distinguished, and we often find different arguments pursued side by side. The aim of this paper is to (...) disentangle different versions of typicality-based explanations of thermodynamic behaviour and evaluate their respective success. My conclusion will be that the boldest version fails for technical reasons, while more prudent versions leave unanswered essential questions. (shrink)

Charlotte Werndl and Roman Frigg discuss the relationship between the Boltzmannian and Gibbsian framework of statistical mechanics, addressing, in particular, the question when equilibrium values calculated in both frameworks agree. This note points out conceptual confusions that could arise from their discussion, concerning, in particular, the authors’ use of “Boltzmann equilibrium.” It also clarifies the status of the Khinchin condition for the equivalence of Boltzmannian and Gibbsian equilibrium predictions and shows that it follows, under (...) the assumptions proposed by Werndl and Frigg, from standard arguments in probability theory. (shrink)

Why do systems prepared in a non-equilibrium state approach, and eventually reach, equilibrium? An important contemporary version of the Boltzmannian approach to statistical mechanics answers this question by an appeal to the notion of typicality. The problem with this approach is that it comes in different versions, which are, however, not recognised as such, much less clearly distinguished, and we often find different arguments pursued side by side. The aim of this paper is to (...) disentangle different versions of typicality-based explanations of thermodynamic behaviour and evaluate their respective success. My conclusion will be that the boldest version fails for technical reasons, while more prudent versions leave unanswered essential questions. (shrink)

I. Prigogine has proposed, and the writings of N. S. Krylov to some extent suggest, a novel and unorthodox solution to foundational problems in statistical mechanics. In particular, the view claims to offer new insight into two interconnected problems: understanding the role of probability in physics, and that of reconciling the irreversibility of physical processes with the temporal symmetry of dynamical theories. The approach in question advocates a conception of the state of a system which incorporates features (...) of the quantum mechanical state concept in a context, classical statistical mechanics, where quantum considerations are generally considered to be irrelevant. I examine the plausibility of this new approach by offering an analysis of the various notions of state employed in modern physics. ;In the first chapter, I analyze the conceptual connections between dynamical laws and the nature of a system's state. I argue that laws and states are correlative. In constructing dynamical theories one does not start with a fixed or pre-determined state concept. Neither is one given the laws of the theory from which the conception of state is derived. Rather, we get the law/state structure as a "package." In light of this general analysis, I next examine the notion of state employed in the quantum theory. Here I consider a variety of conceptions of quantum states and assess their ability to answer the "paradoxes" of quantum theory. I pay particular attention to the role of probability and related restrictions on the realization of certain states. The new approach to statistical mechanics proposes to exploit similar restrictions on states in order to resolve the irreversibility problem. But is this unorthodox approach viable? In the final four chapters, I offer a detailed critique of this approach, examining the plausibility of the radical reworking of the state concept. I argue that while some important progress can be made, certain old puzzles remain, and new and difficult ones arise--ones which raise serious doubts about the ultimate success of this particular approach. I conclude, however, by arguing that such radical proposals are not unmotivated; and that novel and unorthodox proposals concerning the foundations of statistical mechanics must be taken seriously. (shrink)

I discuss a broad critique of the classical approach to the foundations of statistical mechanics (SM) offered by N. S. Krylov. He claims that the classical approach is in principle incapable of providing the foundations for interpreting the "laws" of statistical physics. Most intriguing are his arguments against adopting a de facto attitude towards the problem of irreversibility. I argue that the best way to understand his critique is as setting the stage for a positive (...) theory which treats SM as a theory in its own right, involving a completely different conception of a system's state. As the orthodox approach treats SM as an extension of the classical or quantum theories (one which deals with large systems), Krylov is advocating a major break with the traditional view of statistical physics. (shrink)

A popular view in contemporary Boltzmannian statistical mechanics is to interpret the measures as typicality measures. In measure-theoretic dynamical systems theory measures can similarly be interpreted as typicality measures. However, a justification why these measures are a good choice of typicality measures is missing, and the paper attempts to fill this gap. The paper first argues that Pitowsky's (2012) justification of typicality measures does not fit the bill. Then a first proposal of how to justify typicality measures (...) is presented. The main premises are that typicality measures are invariant and are related to the initial probability distribution of interest (which are translation-continuous or translation-close). The conclusions are two theorems which show that the standard measures of statistical mechanics and dynamical systems are typicality measures. There may be other typicality measures, but they agree about judgements of typicality. Finally, it is proven that if systems are ergodic or epsilon-ergodic, there are uniqueness results about typicality measures. (shrink)

Boltzmannian statistical mechanics (BSM) partitions a system’s space of micro-states into cells and refers to these cells as ‘macro-states’. One of these cells is singled out as the equilibrium macro-state while the others are non-equilibrium macro-states. It remains unclear, however, how these states are characterised at the macro-level as long as only real-valued macro-variables are available. We argue that physical quantities like pressure and temperature should be treated as field-variables and show how field variables fit into the (...) framework of our own version of BSM, the long-run residence time account of BSM. The introduction of field variables into the theory makes it possible to give a full macroscopic characterisation of the approach to equilibrium. (shrink)

Kevin Davey claims that the justification of the second law of thermodynamics as it is conveyed by the “standard story” of statistical mechanics, roughly speaking, that lowentropy microstates tend to evolve to high-entropy microstates, is “unhelpful at best and wrong at worst.” In reply, I demonstrate that Davey’s argument for rejecting the standard story commits him to a form of skepticism that is more radical than the position he claims to be stating and that Davey places unreasonable demands (...) on the notion of justification in the physical sciences. (shrink)

In this paper we address two problems in Boltzmann's approach to statistical mechanics. The first is the justification of the probabilistic predictions of the theory. And the second is the inadequacy of the theory's retrodictions.

To complete our ontological interpretation of quantum theory we have to conclude a treatment of quantum statistical mechanics. The basic concepts in the ontological approach are the particle and the wave function. The density matrix cannot play a fundamental role here. Therefore quantum statistical mechanics will require a further statistical distribution over wave functions in addition to the distribution of particles that have a specified wave function. Ultimately the wave function of the universe will (...) he required, but we show that if the universe in not in thermodynamic equilibrium then it can he treated in terms of weakly interacting large scale constituents that are very nearly independent of each other. In this way we obtain the same results as those of the usual approach within the framework of the ontological interpretation. (shrink)

Discussions of the foundations of Classical Equilibrium Statistical Mechanics (SM) typically focus on the problem of justifying the use of a certain probability measure (the microcanonical measure) to compute average values of certain functions. One would like to be able to explain why the equilibrium behavior of a wide variety of distinct systems (different sorts of molecules interacting with different potentials) can be described by the same averaging procedure. A standard approach is to appeal to ergodic theory (...) to justify this choice of measure. A different approach, eschewing ergodicity, was initiated by A. I. Khinchin. Both explanatory programs have been subjected to severe criticisms. This paper argues that the Khinchin type program deserves further attention in light of relatively recent results in understanding the physics of universal behavior. (shrink)

The fundamental problem on which Ilya Prigogine and the Brussels–Austin Group have focused can be stated briefly as follows. Our observations indicate that there is an arrow of time in our experience of the world (e.g., decay of unstable radioactive atoms like uranium, or the mixing of cream in coffee). Most of the fundamental equations of physics are time reversible, however, presenting an apparent conflict between our theoretical descriptions and experimental observations. Many have thought that the observed arrow of time (...) was either an artifact of our observations or due to very special initial conditions. An alternative approach, followed by the Brussels–Austin Group, is to consider the observed direction of time to be a basic physical phenomenon due to the dynamics of physical systems. This essay focuses mainly on recent developments in the Brussels–Austin Group after the mid-1980s. The fundamental concerns are the same as in their earlier approaches (subdynamics, similarity transformations), but the contemporary approach utilizes rigged Hilbert space (whereas the older approaches used Hilbert space). While the emphasis on nonequilibrium statistical mechanics remains the same, their more recent approach addresses the physical features of large Poincare systems, nonlinear dynamics and the mathematical tools necessary to analyze them. (shrink)

In the previous papers, it was demonstrated that applying the principle of maximum information entropy by maximizing the conditional information entropy, subject to the constraint given by the Liouville equation averaged over the phase space, leads to a definition of the rate of entropy change for closed Hamiltonian systems without any additional assumptions. Here, we generalize this basic model and, with the introduction of the additional constraints which are equivalent to the hydrodynamic continuity equations, show that the results obtained are (...) consistent with the known results from the nonequilibrium statistical mechanics and thermodynamics of irreversible processes. In this way, as a part of the approach developed in this paper, the rate of entropy change and entropy production density for the classical Hamiltonian fluid are obtained. The results obtained suggest the general applicability of the foundational principles of predictive statistical mechanics and their importance for the theory of irreversibility. (shrink)

This second part of a two-part essay discusses recent developments in the Brussels-Austin Group after the mid 1980s. The fundamental concerns are the same as in their similarity transformation approach (see Part I), but the contemporary approach utilizes rigged Hilbert space (whereas the older approach used Hilbert space). While the emphasis on nonequilibrium statistical mechanics remains the same, the use of similarity transformations shifts to the background. In its place arose an interest in the physical (...) features of large Poincaré systems, nonlinear dynamics and the mathematical tools necessary to analyze them. (shrink)

This paper is a discussion of David Albert's approach to the foundations of classical statistical menchanics. I point out a respect in which his account makes a stronger claim about the statistical mechanical probabilities than is usually made, and I suggest what might be motivation for this. I outline a less radical approach, which I attribute to Boltzmann, and I give some reasons for thinking that this approach is all we need, and also the most (...) we are likely to get. The issue between the two accounts turns out to be one about the explanatory role probabilities play in statistical mechanics. (shrink)

Detlef Dürr was inspirational to many who write about issues in the philosophical foundations of physics and probability. For many years I have been interested in his work on statistical mechanics and Bohmian mechanics and especially by the role of typicality in these theories. In my contribution I will say a few words comparing typicality and probability approaches to statistical mechanics and ask whether the approaches are friends or foes.

In (Weaver 2021), I showed that Boltzmann’s H-theorem does not face a significant threat from the reversibility paradox. I argue that my defense of the H-theorem against that paradox can be used yet again for the purposes of resolving the recurrence paradox without having to endorse heavy-duty statistical assumptions outside of the hypothesis of molecular chaos. As in (Weaver 2021), lessons from the history and foundations of physics reveal precisely how such resolution is achieved.

There have been attempts to derive anti-haeccetistic conclusions from the fact that quantum mechanics (QM) appeals to non-standard statistics. Since in fact QM acknowledges two kinds of such statistics, Bose-Einstein and Fermi-Dirac, I argue that we could in the same vein derive the sharper anti-haeccetistic conclusion that bosons are bundles of tropes and fermions are bundles of universals. Moreover, since standard statistics is still appropriate at the macrolevel, we could also venture to say that no anti-haecceitistic conclusion is warranted (...) for ordinary objects, which could then tentatively be identified with substrates. In contrast to this, however, there has been so far no acknowledgement of the possibility of inclusivism, according to which ontological accounts of particulars as widely different as those can possibly coexist in one world picture. The success of the different statistics in physics at least calls for a revision in this respect. (shrink)

I will argue, pace a great many of my contemporaries, that there's something right about Boltzmann's attempt to ground the second law of thermodynamics in a suitably amended deterministic time-reversal invariant classical dynamics, and that in order to appreciate what's right about (what was at least at one time) Boltzmann's explanatory project, one has to fully apprehend the nature of microphysical causal structure, time-reversal invariance, and the relationship between Boltzmann entropy and the work of Rudolf Clausius.

Statistical mechanics involves probabilities. At the same time, most approaches to the foundations of statistical mechanics--programs whose goal is to understand the macroscopic laws of thermal physics from the point of view of microphysics--are classical; they begin with the assumption that the underlying dynamical laws that govern the microscopic furniture of the world are deterministic. This raises some potential puzzles about the proper interpretation of these probabilities.

Statistical Mechanics (SM) involves probabilities. At the same time, most approaches to the foundations of SM—programs whose goal is to understand the macroscopic laws of thermal physics from the point of view of microphysics—are classical; they begin with the assumption that the underlying dynamical laws that govern the microscopic furniture of the world are (or can without loss of generality be treated as) deterministic. This raises some potential puzzles about the proper interpretation of these probabilities. It also raises, (...) more generally, the question of what kinds, if any, of objective probabilities can exist in a deterministic world. (shrink)

The fundamental problem on which Ilya Prigogine and the Brussels- Austin Group have focused can be stated briefly as follows. Our observations indicate that there is an arrow of time in our experience of the world (e.g., decay of unstable radioactive atoms like Uranium, or the mixing of cream in coffee). Most of the fundamental equations of physics are time reversible, however, presenting an apparent conflict between our theoretical descriptions and experimental observations. Many have thought that the observed arrow of (...) time was either an artifact of our observations or due to very special initial conditions. An alternative approach, followed by the Brussels-Austin Group, is to consider the observed direction of time to be a basic physical phenomenon due to the dynamics of physical systems. This essay focuses mainly on recent developments in the Brussels-Austin Group after the mid 1980s. The fundamental concerns are the same as in their earlier approaches (subdynamics, similarity transformations), but the contemporary approach utilizes rigged Hilbert space (whereas the older approaches used Hilbert space). While the emphasis on nonequilibrium statistical mechanics remains the same, their more recent approach addresses the physical features of large Poincar´. (shrink)

The fundamental problem on which Ilya Prigogine and the Brussels-Austin Group have focused can be stated briefly as follows. Our observations indicate that there is an arrow of time in our experience of the world (e.g., decay of unstable radioactive atoms like Uranium, or the mixing of cream in coffee). Most of the fundamental equations of physics are time reversible, however, presenting an apparent conflict between our theoretical descriptions and experimental observations. Many have thought that the observed arrow of time (...) was either an artifact of our observations or due to very special initial conditions. An alternative approach, followed by the Brussels-Austin Group, is to consider the observed direction of time to be a basic physical phenomenon and to develop a mathematical formalism that can describe this direction as being due to the dynamics of physical systems. In part I of this essay, I review and assess an attempt to carry out an approach that received much of their attention from the early 1970s to the mid 1980s. In part II, I will discuss their more recent approach using rigged Hilbert spaces. (shrink)

The received wisdom in statistical mechanics is that isolated systems, when left to themselves, approach equilibrium. But under what circumstances does an equilibrium state exist and an approach to equilibrium take place? In this paper we address these questions from the vantage point of the long-run fraction of time definition of Boltzmannian equilibrium that we developed in two recent papers. After a short summary of Boltzmannian statistical mechanics and our definition of equilibrium, (...) we state an existence theorem which provides general criteria for the existence of an equilibrium state. We first illustrate how the theorem works with a toy example, which allows us to illustrate the various elements of the theorem in a simple setting. After a look at the ergodic programme, we discuss equilibria in a number of different gas systems: the ideal gas, the dilute gas, the Kac gas, the stadium gas, the mushroom gas and the multi-mushroom gas. In the conclusion we briefly summarise the main points and highlight open questions. (shrink)

The present essay provides a new metaphysical interpretation of Relational Quantum Mechanics (RQM) in terms of mereological bundle theory. The essential idea is to claim that a physical system in RQM can be defined as a mereological fusion of properties whose values may vary for different observers. Abandoning the Aristotelian tradition centered on the notion of substance, I claim that RQM embraces an ontology of properties that finds its roots in the heritage of David Hume. To this regard, defining (...) what kind of concrete physical objects populate the world according to RQM, I argue that this theoretical framework can be made compatible with (i) a property-oriented ontology, in which the notion of object can be easily defined, and (ii) moderate structural realism, a philosophical position where relations and relata are both fundamental. Finally, I conclude that under this reading relational quantum mechanics should be included among the full-fledged realist interpretations of quantum theory. (shrink)

In recent previous work, the authors proposed a new approach extending the framework of statistical mechanics to reparametrization-invariant systems with no additional gauges. In this paper, the approach is generalized to systems defined by more than one Hamiltonian constraint. We show how well-known features as the Ehrenfest–Tolman effect and the Jüttner distribution for the relativistic gas can be consistently recovered from a covariant approach in the multi-fingered framework. Eventually, the crucial role played by the interaction (...) in the definition of a global notion of equilibrium is discussed. (shrink)

A fundamental link between system theory and statistical mechanics has been found to be established by the Kolmogorov entropy K. By this quantity the temporal evolution of dynamical systems can be classified into regular, chaotic, and stochastic processes. Since K represents a measure for the internal information creation rate of dynamical systems, it provides an approach to irreversibility. The formal relationship to statistical mechanics is derived by means of an operator formalism originally introduced by Prigogine. (...) For a Liouville operator L and an information operator $\tilde M$ acting on a distribution in phase space, it is shown that i[L, $\tilde M$ ]≡KI (I=identity operator). As a first consequence of this equivalence, a relation is obtained between the chaotic correlation time of a system and Prigogine's concept of a “finite duration of presence.” Finally, the existence of chaos in quantum systems is discussed with respect to the existence of a quantum mechanical time operator. (shrink)

Huw Price (1996, 2002, 2003) argues that causal-dynamical theories that aim to explain thermodynamic asymmetry in time are misguided. He points out that in seeking a dynamical factor responsible for the general tendency of entropy to increase, these approaches fail to appreciate the true nature of the problem in the foundations of statistical mechanics (SM). I argue that it is Price who is guilty of misapprehension of the issue at stake. When properly understood, causal-dynamical approaches in the foundations (...) of SM offer a solution for a different problem; a problem that unfortunately receives no attention in Price’s celebrated work. (shrink)

This article distinguishes two different senses of information-theoretic approaches to statistical mechanics that are often conflated in the literature: those relating to the thermodynamic cost of computational processes and those that offer an interpretation of statistical mechanics where the probabilities are treated as epistemic. This distinction is then investigated through Earman and Norton’s ([1999]) ‘sound’ and ‘profound’ dilemma for information-theoretic exorcisms of Maxwell’s demon. It is argued that Earman and Norton fail to countenance a ‘sound’ information-theoretic (...) interpretation and this paper describes how the latter inferential interpretations can escape the criticisms of Earman and Norton ([1999]) and Norton ([2005]) by adopting this ‘sound’ horn. This article considers a standard model of Maxwell’s demon to illustrate how one might adopt an information-theoretic approach to statistical mechanics without a reliance on Landauer’s principle, where the incompressibility of the probability distribution due to Liouville’s theorem is taken as the central feature of such an interpretation. (shrink)