In Paul Forman and José M. Sánchez-Ron, eds. National Military Establishments and the Advancement of Science and Technology: Studies in Twentieth Century History (Kluwer Academic Publ.: Dordrecht, 1996), pp. 261–326. -/- .

Introduction -- Quantum information: basic relevant concepts and applications -- Theory -- Part I. Atomic processes -- Coulombic entanglement: one-step single photoionization of atoms -- Coulombic entanglement: one-step double photoinonization of atoms -- Coulombic entanglement: two-step double photoinonization of atoms -- Fine-structure entanglement: bipartite states of flying particlees with rest mass different from zero -- Bipartite states and flying electronic qubits -- Part II. Molecular processes -- One-step double photoionization of molecules -- Two-step double photoionization of molecules -- Part (...) III. Miscellaneous -- Conclusions and prospectives. (shrink)

Within quantum chemistry, the electron clouds that surround nuclei in atoms and molecules are sometimes treated as clouds of probability and sometimes as clouds of charge. These two roles, tracing back to Schrödinger and Born, are in tension with one another but are not incompatible. Schrödinger’s idea that the nucleus of an atom is surrounded by a spread-out electron charge density is supported by a variety of evidence from quantum chemistry, including two methods that are used to determine (...) atomic and molecular structure: the Hartree-Fock method and density functional theory. Taking this evidence as a clue to the foundations of quantum physics, Schrödinger’s electron charge density can be incorporated into many different interpretations of quantum mechanics. (shrink)

The historical development of the electronic configuration model is traced and the status of the model with respect to quantum mechanics is examined. The successes and problems raised by the model are explored, particularly in chemical ab initio calculations. The relevance of these issues to whether chemistry has been reduced to quantum mechanics is discussed, as are some general notions on reduction.

We discuss the problem of treating strongly correlated electrons by quantum chemical methods. It is shown how an incremental computational scheme for the ground-state energy can be related to a generalization of Faddeev's equations. We also discuss the application of the local increment method to lithium metal by the study of a Li8 cluster.

In 1965, John A. Pope presented a paper entitled 'Two-Dimensional Chart of Quantum Chemistry' to illustrate the inverse relationship between the sophistication of computational methods and the size of molecules under study. This chart, later called the 'hyperbola of quantum chemistry', succinctly summarized the growing tension between the proponents of two different approaches to computation–the ab initio method and semiempirical method–in the early years of electronic digital computers. Examining the development of quantum chemistry after World War II, (...) I focus on the role of computers in shaping disciplinary identity. The availability of high-speed computers in the early 1950s attracted much attention from quantum chemists, and their community took shape through a series of conferences and personal networking. However, this emerging community soon encountered the problem of communication between groups that differed in the degree of reliance they placed on computers. I show the complexity of interactions between computing technology and a scientific discipline, in terms of both forming and splitting the community of quantum chemistry. (shrink)

En este trabajo presentamos una revision de la definición cuántica del elcetrón en relación con el principio de incertidumbre de Werner Heisenberg.In this paper we present a revision of the electron’s quantum definition in relation to the so called uncerrainty principle by Wenrer Heisenberg.

Smarandache Hypothesis states that there is no speed limit of anything, including light and particles. While the idea is quite simple and based on known hypothesis of quantum mechanics, called Einstein-Podolski-Rosen paradox, in reality such a superluminal physics seems still hard to accept by majority of physicists. Here we review some experiments to support superluminal physics and also findings to explain Smarandache Quantum Paradoxes and Quantum Sorites Paradox. We also touch briefly on new experiment on magneton, supporting (...) SubQuantum Kinetic Model of Electron. (shrink)

Atomic states are rigorously characterized by the total orbital angular momentum and the total spin angular momentum, but chemists persist in the use of electron configurations based on one-electron quantum numbers and simplified rules for predicting ground state configurations. This practice is defended against two lines of criticism, and its use in teaching chemistry is encouraged with the claim that the inductive approach of Mendeleev and the deductive approach initiated by Schrödinger compose the consummate example of that interaction of (...) empirical and rational epistemologies that defines how chemists think. (shrink)

An Aristotelian philosophy of nature offers an alternative to reduction for the conception of the inter-theoretical relationships between molecular chemistry and quantum mechanics. A basic ingredient for such an approach is an ontology of fundamental causal powers, and this work aims to develop such an ontology by drawing on quantum-chemical entities, particularly, the electron density. This notion is central to the Quantum Theory of Atoms in Molecules, a theory of molecular structure developed by Richard F. W. Bader, (...) which describes molecules and atoms in terms precisely of the electron density. Then, by identifying a philosophical tension in Bader’s discourse about the nature of electron density, the work will analyze this central notion in terms of the categorical/dispositional distinction regarding properties. The central idea is that electron density can be conceived as categorical and dispositional at once, and this very characterization can avoid Bader’s philosophical tension. (shrink)

In this work we consider the energy states of muonic atoms which are predominantly influenced by vacuum polarization. This fact is used for testing the electron propagator of QED with the modification $S(p) = (\not p - me)^{ - 1} + f(\not p - M)^{ - 1}$ . The data of some well analyzed transitions in muonic He, Si, Ba, and Pb yield the limit M>29 MeV for f=1.Similarly the presence of a Higgs boson would cause a shift of the (...) energy levels which can be measured easier in muonic atoms since the coupling grows with the fermion mass. The analysis of several transitions in heavy muonic atoms shows, that the mass of the Higgs boson is larger than 12.8 MeV.Further reductions of the present-day uncertainties concerning the experimental data and especially of the nuclear structure effects could improve these limits. (shrink)

The energy spectra for two electrons in a parabolic quantum dot are calculated by the quantization rule approach. The numerical results are in excellent agreement with the results by the method of integrating directly the Schrödinger equation, and better than those by the WKB method and the WKB-DP method.

This article describes a descriptive-qualitative method for analyzing and reviewing several textbooks for high school as samples commonly used by teachers and students in their teaching–learning to reveal possible misconceptions. This study focused on the subjects of quantum numbers and electronic configuration. From the advanced literature review to analyze the samples the occurrence of various misconceptions was noted. All textbooks described correctly the four symbols of quantum numbers, but none correlates correctly the magnetic-angular quantum number to the (...) Cartesian labeled orbitals. All textbooks consider mistakenly the meaning of aufbau as the building-up energy of orbitals by following (n + ℓ, n) rules on describing the electronic configuration for all atoms. Only one textbook states that the electronic configuration of transition metal atoms (3d series) can be described in the following order of shell (n), thus giving rise to two types of electronic configurations, [Ar] 3d 4s (Type I) beside [Ar] 4s 3d (Type II), leading further misconception. All textbooks described favorably an unpaired electron of ms = + ½ due to the specific agreement, which is a potential misconception in applying Hund’s rule. In drawing the diagram boxes of orbitals, they are arranged in increasing or decreasing the numeric mℓ, due to the specific agreement, and again leading to a potential misconception on describing the quantum number of electrons issued. Three textbooks introduced the terms of the last and the xth electron associated with the quantum numbers, leading to serious further misconceptions. No books stated that the ordering energy of the (n + ℓ, n) rule is true only for the first twenty atoms. (shrink)

In this paper I put forward a new micro realistic, fundamentally probabilistic, propensiton version of quantum theory. According to this theory, the entities of the quantum domain - electrons, photons, atoms - are neither particles nor fields, but a new kind of fundamentally probabilistic entity, the propensiton - entities which interact with one another probabilistically. This version of quantum theory leaves the Schroedinger equation unchanged, but reinterprets it to specify how propensitons evolve when no probabilistic transitions occur. (...) Probabilisitic transitions occur when new "particles" are created as a result of inelastic interactions. All measurements are just special cases of this. This propensiton version of quantum theory, I argue, solves the wave/particle dilemma, is free of conceptual problems that plague orthodox quantum theory, recovers all the empirical success of orthodox quantum theory, and at the same time yields as yet untested predictions that differ from those of orthodox quantum theory. (shrink)

Quantum mechanics studies physical phenomena on a microscopic scale. These phenomena are far beyond the reach of our observation, and the connection between QM's mathematical formalism and the experimental results is very indirect. Furthermore, quantum indeterminism defies common sense. Microphysical experiments have shown that, according to the empirical context, electrons and quanta of light behave as waves and other times as particles, even though it is impossible to design an experiment that manifests both behaviors at the same time. (...) Unlike Newtonian physics, the properties of quantum systems are not all well-defined simultaneously. Moreover, quantum systems are not characterized by their properties, but by a wave function. Although one of the principles of the theory is the uncertainty principle, the trajectory of the wave function is controlled by the deterministic Schrödinger equations. But what is the wave function? Like other theories of the physical sciences, quantum theory assigns states to systems. The wave function is a particular mathematical representation of the quantum state of a physical system, which contains information about the possible states of the system and the respective probabilities of each state. (shrink)

Prologue: Stormclouds : London, April 1900 -- Quantum of action: The most strenuous work of my life : Berlin, December 1900 ; Annus Mirabilis : Bern, March 1905 ; A little bit of reality : Manchester, April 1913 ; la Comédie Française : Paris, September 1923 ; A strangely beautiful interior : Helgoland, June 1925 ; The self-rotating electron : Leiden, November 1925 ; A late erotic outburst : Swiss Alps, Christmas 1925 -- Quantum interpretation: Ghost field : (...) Oxford, August 1926 ; All this damned quantum jumping : Copenhagen, October 1926 ; The uncertainty principle : Copenhagen, February 1927 ; The 'Kopenhagener geist' : Copenhagen, June 1927 ; There is no quantum world : Lake Como, September 1927 -- Quantum debate: The debate commences : Brussels, October 1927 ; An absolute wonder : Cambridge, Christmas 1927 ; The photon box : Brussels, October 1930 ; A bolt from the blue : Princeton, May 1935 ; The paradox of Schrödinger's cat : Oxford, August 1935 -- Interlude: The first war of physics : Christmas 1938-August 1945 -- Quantum fields: Shelter Island : Long Island, June 1947 ; Pictorial semi-vision thing : New York, January 1949 ; A beautiful idea : Princeton, February 1954 ; Some strangeness in the proportion : Rochester, August 1960 ; Three quarks for Muster Mark! : New York, March 1963 ; The 'God particle' : Cambridge, Massachusetts, Autumn 1967 -- Quantum particles: Deep inelastic scattering : Stanford, August 1968 ; Of charm and weak neutral currents : Harvard, February 1970 ; The magic of colour : Princeton/Harvard, April 1973 ; The November revolution : Long Island/Stanford, November 1974 ; Intermediate vector bosons : Geneva, January/June 1983 ; The standard model : Geneva, September 2003 -- Quantum reality: Hidden variable : Princeton, Spring 1951 ; Bertlmann's socks : Boston, September 1964 ; The Aspect experiments : Paris, September 1982 ; The quantum eraser : Baltimore, January 1999 ; Lab cats : Stony Brook/Delft, July 2000 ; The persistent illusion : Vienna, December 2006 -- Quantum cosmology: The wavefunction of the universe : Princeton, July 1966 ; Hawking radiation : Oxford, February 1974 ; The first superstring revolution : Aspen, August 1984 ; Quanta of space and time : Santa Barbara, February 1986 ; Crisis? What crisis? : Durham, Summer 1994 -- A quantum of solace? : Geneva, March 2010. (shrink)

Quantum entanglement poses a challenge to the traditional metaphysical view that an extrinsic property of an object is determined by its intrinsic properties. So structural realists might be tempted to cite quantum entanglement as evidence for structural realism. I argue, however, that quantum entanglement undermines structural realism. If we classify two entangled electrons as a single system, we can say that their spin properties are intrinsic properties of the system, and that we can have knowledge about these (...) intrinsic properties. Specifically, we can know that the parts of the system are entangled and spatially separated from each other. In addition, the concept of supervenience neither illuminates quantum entanglement nor helps structural realism. (shrink)

Problems of self-interaction arise in both classical and quantum field theories. To understand how such problems are to be addressed in a quantum theory of the Dirac and electromagnetic fields (quantum electrodynamics), we can start by analyzing a classical theory of these fields. In such a classical field theory, the electron has a spread-out distribution of charge that avoids some of the problems of self-interaction facing point charge models. However, there remains the problem that the electron will (...) experience self-repulsion. This self-repulsion cannot be eliminated within classical field theory without also losing Coulomb interactions between distinct particles. But, electron self-repulsion can be eliminated from quantum electrodynamics in the Coulomb gauge by fully normal-ordering the Coulomb term in the Hamiltonian. After normal-ordering, the Coulomb term contains pieces describing attraction and repulsion between distinct particles and also pieces describing particle creation and annihilation, but no pieces describing self-repulsion. (shrink)

Proposals for quantum computation rely on superposed states implementing multiple computations simultaneously, in parallel, according to quantum linear superposition (e.g., Benioff, 1982; Feynman, 1986; Deutsch, 1985, Deutsch and Josza, 1992). In principle, quantum computation is capable of specific applications beyond the reach of classical computing (e.g., Shor, 1994). A number of technological systems aimed at realizing these proposals have been suggested and are being evaluated as possible substrates for quantum computers (e.g. trapped ions, electron spins, (...) class='Hi'>quantum dots, nuclear spins, etc., see Table 1; Bennett, 1995; and Barenco, 1995). The main obstacle to realization of quantum computation is the problem of interfacing to the system (input, output) while also protecting the quantum state from environmental decoherence. If this problem can be overcome, then present day classical computers may evolve to quantum computers. (shrink)

This paper analyses Richard Bader’s ‘operational’ view of quantum mechanics and the role it plays in the the explanation of chemistry. I argue that QTAIM can partially be reconstructed as an ‘austere’ form of quantum mechanics, which is in turn committed to an eliminative concept of reduction that stems from Kemeny and Oppenheim. As a reductive theory in this sense, the theory fails. I conclude that QTAIM has both a regulatory and constructive function in the theories of chemistry.

Quantum mechanics is humanity's finest scientific achievement. It explains why the sun shines and how your eyes can see. It's the theory behind the LEDs in your phone and the nuclear hearts of space probes. Every physicist agrees quantum physics is spectacularly successful. But ask them what quantum physics means, and the result will be a brawl. At stake is the nature of the Universe itself. What does it mean for something to be real? What is the (...) role of consciousness in the Universe? And do quantum rules apply to very small objects like electrons and protons, but not us? In What is Real?, Adam Becker brings to vivid life the brave researchers whose quest for the truth led them to challenge Bohr: David Bohm, who picked up Einstein's mantle and sought to make quantum mechanics deterministic, all while being hounded by the forces of McCarthyism; Hugh Everett, who argued that everything, big and small, must be governed by the same rules; and John Bell, who went to great lengths to eradicate the power of the god-like observer from the core of quantum physics. And they paid dearly, their reputations, careers, and sometimes lives ruined completely. But history has been kinder to them than their contemporaries were. As Becker shows, the brave intellectual giants have inspired a growing army of physicists and philosophers intent both on making a philosophically more satisfying theory of the universe and a more useful one as well. A gripping story of some of humanity's greatest ideas and the high cost with which many have pursued them, What is Real? is intellectual history at its passionate best. (shrink)

-/- Panpsychism is often thought to be an obviously mistaken doctrine, because it is considered to be completely inconceivable how the elementary particles of physics could possibly have proto-mental properties. This paper points out that quantum theory implies that elementary particles are far more subtle and strange than most contemporary physicalist philosophers assume. The discusses David Bohm’s famous “pilot wave” theory which implies that, say, an electron is a particle guided by a field carrying active information, the latter of (...) which can be seen as a primitive mind-like quality. (shrink)

E. Schrödinger's ideas on interpreting quantum mechanics have been recently re-examined by historians and revived by philosophers of quantum mechanics. Such recent re-evaluations have focused on Schrödinger's retention of space–time continuity and his relinquishment of the corpuscularian understanding of microphysical systems. Several of these historical re-examinations claim that Schrödinger refrained from pursuing his 1926 wave-mechanical interpretation of quantum mechanics under pressure from the Copenhagen and Göttingen physicists, who misinterpreted his ideas in their dogmatic pursuit of the complementarity (...) doctrine and the principle of uncertainty. My analysis points to very different reasons for Schrödinger's decision and, accordingly, to a rather different understanding of the dialogue between Schrödinger and N. Bohr, who refuted Schrödinger's arguments. Bohr's critique of Schrödinger's arguments predominantly focused on the results of experiments on the scattering of electrons performed by Bothe and Geiger, and by Compton and Simon. Although he shared Schrödinger's rejection of full-blown classical entities, Bohr argued that these results demonstrated the corpuscular nature of atomic interactions. I argue that it was Schrödinger's agreement with Bohr's critique, not the dogmatic pressure, which led him to give up pursuing his interpretation for 7 yr. Bohr's critique reflected his deep understanding of Schrödinger's ideas and motivated, at least in part, his own pursuit of his complementarity principle. However, in 1935 Schrödinger revived and reformulated the wave-mechanical interpretation. The revival reflected N. F. Mott's novel wave-mechanical treatment of particle-like properties. R. Shankland's experiment, which demonstrated an apparent conflict with the results of Bothe–Geiger and Compton–Simon, may have been additional motivation for the revival. Subsequent measurements have proven the original experimental results accurate, and I argue that Schrödinger may have perceived even the reformulated wave-mechanical approach as too tenuous in light of Bohr's critique. (shrink)

The present paper reveals (non-relativistic) quantum mechanics as an emergent property of otherwise classical ergodic systems embedded in a stochastic vacuum or zero-point radiation field (zpf). This result provides a theoretical basis for understanding recent numerical experiments in which a statistical analysis of an atomic electron interacting with the zpf furnishes the quantum distribution for the ground state of the H atom. The action of the zpf on matter is essential within the present approach, but it is the (...) ergodic demand what ultimately leads to the matrix formulation of quantum mechanics. The paper thus represents a step forward in the quest for an elucidation of the fundamentals of quantum mechanics. (shrink)

This dissertation reconstructs some aspects of the historical development of the concept of the electron from 1891, when the term "electron" was introduced, to 1925, when the notion of spin was put forward, in the light of the relevant historiographical and philosophical problems. The central historiographical tool employed is Karl Popper's notion of a problem situation. Furthermore, some of the historical episodes are reconstructed in terms of a "biographical" approach to theoretical entities that portrays them as active agents that participate (...) in the development of scientific knowledge. Their agency is due to the heuristic resources that they embody and to the resistance that they exhibit to manipulation. The historical analysis begins with a reconceptualization of the "discovery" of the electron and aims at situating the principal historical actors within the wider process which led to the acceptance of the electron as an element of the ontology of physics. I continue with a reconstruction of the discovery of the Zeeman effect in the light of recent work on the history and philosophy of experimental science. The next three chapters are devoted to a reading of the development of the old quantum theory of the atom , which aimed at understanding the behavior and distribution of electrons bound within the atom, from the perspective of the electron's biography. Furthermore, I discuss the chemists' representation of the electron and contrast it with its physical counterpart. The main philosophical problem examined concerns the implications of meaning change for scientific realism . I discuss in detail that issue and argue against the widespread view that meaning variance is incompatible with scientific realism. Thus, I provide a way out for the aspiring realist, without however committing myself to a realist position. Finally, I argue that the historical development of the concept of the electron from 1896 to 1925 is compatible with a realist construal of its ontological status. (shrink)

This book gives an overview for practitioners and students of quantum physics and information science. It provides ready access to essential information on quantum information processing and communication, such as definitions, protocols and algorithms. Quantum information science is rarely found in clear and concise form. This book brings together this information from its various sources. It allows researchers and students in a range of areas including physics, photonics, solid-state electronics, nuclear magnetic resonance and information technology, in (...) their applied and theoretical branches, to have this vital material directly at hand. (shrink)

Generalized Quantum Theory seeks to explain and predict quantum-like phenomena in areas usually outside the scope of quantum physics, such as biology and psychology. It draws on fundamental theories and uses the algebraic formalism of quantum theory that is used in the study of observable physical matter such as photons, electrons, etc. In contrast to quantum theory proper, GQT is a very generalized form that does not allow for the full application of formalism. For instance (...) neither a commutator, such as Planck’s constant, nor any additive operations are defined, which precludes the usage of a full Hilbert-space formalism. But it is a formalized phenomenological theory that is applicable whenever the core element of a quantum theory needs to be captured, namely in the presence of incompatible or non-commuting operations. As a consequence, it also predicts nonlocal, generalized entanglement correlations in systems other than proper quantum systems. In this paper we summarize the specific scientific evidence relating to the quantum-like mental, behavioral and physiological nonlocal correlations. Such non-local, generalized entanglement correlations are expected, both in space and time, between subsystems of a larger system, whenever observables pertaining to the global system are incompatible or complementary to observables pertaining to subsystems, as predicted by GQT. The result is a coherent explanation of a significant amount of controversial and seemingly weird occurrences that cannot be explained by classical physical laws. This review also offers a new perspective of the human mind’s potential. (shrink)

Papers from the 1994 meeting represent a broad review of contemporary experimental work on quantum phenomena, emphasizing state-of-the-art experimental science. Useful as an introductory manual for young researchers, the volume addresses topics that include: experiments with single and ultracold ato.

How much of philosophical, scientific, and political thought is caught up with the idea of continuity? What if it were otherwise? This paper experiments with the disruption of continuity. The reader is invited to participate in a performance of spacetime (re)configurings that are more akin to how electrons experience the world than any journey narrated though rhetorical forms that presume actors move along trajectories across a stage of spacetime (often called history). The electron is here invoked as our host, an (...) interesting body to inhabit (not in order to inspire contemplation of flat-footed analogies between ‘macro’ and ‘micro’ worlds, concepts that already presume a given spatial scale), but a way of thinking with and through dis/continuity – a dis/orienting experience of the dis/jointedness of time and space, entanglements of here and there, now and then, that is, a ghostly sense of dis/continuity, a quantum dis/continuity. There is no overarching sense of temporality, of continuity, in place. Each scene diffracts various temporalities within and across the field of spacetimemattering. Scenes never rest, but are reconfigured within, dispersed across, and threaded through one another. The hope is that what comes across in this dis/jointed movement is a felt sense of différance, of intra-activity, of agential separability – differentiatings that cut together/apart – that is the hauntological nature of quantum entanglements. (shrink)

Quantum mechanics teaches that before detection, knowledge of particle position is, at best, probabilistic, and classical trajectories are seen as a feature of the macroscopic world. These comments refer to detected particles, but we are still free to consider the motions generated by the wave equation. Within hydrogen, the Schrodinger equation allows calculation of kinetic energy at any location, and if this is identified as the energy of the wave, then radial momentum, allowing for spherical harmonics, becomes available. The (...) distance across the real zone of radial momentum is found to match semi-integer wavelengths of the adjusted matter wave, consistent with what is expected from a standing wave condition. The approach is extended to include orbital motions, where it is established that the underlying wave, which has direction and wavelength at each location, forms a series of connected trajectories, which are shown to be ellipses orientated at various angles to the equatorial plane. This suggests that wave trajectories, rather than particle trajectories, are still a feature of the hydrogen atom. The finding allows the reason for the coincidence between energy results derived by Sommerfeld’s classical trajectories and the Schrodinger wave equation to be appreciated. The result has implications when the relativistic situation is considered, as Sommerfeld’s correct deduction of the relativistic energy levels of hydrogen well before Dirac derived his wave equation has long been somewhat puzzling. (shrink)

In December 1924 Wolfgang Pauli proposed the idea of an inner degree of freedom of the electron, which he insisted should be thought of as genuinely quantum mechanical in nature. Shortly thereafter Ralph Kronig and, independently, Samuel Goudsmit and George Uhlenbeck took up a less radical stance by suggesting that this degree of freedom somehow corresponded to an inner rotational motion, though it was unclear from the very beginning how literal one was actually supposed to take this picture, since (...) it was immediately recognised that it would very likely lead to serious problems with Special Relativity if the model were to reproduce the electron's values for mass, charge, angular momentum, and magnetic moment. However, probably due to the then overwhelming impression that classical concepts were generally insufficient for the proper description of microscopic phenomena, a more detailed reasoning was never given. In this contribution I shall investigate in some detail what the restrictions on the physical quantities just mentioned are, if they are to be reproduced by rather simple classical models of the electron within the framework of Special Relativity. It turns out that surface stresses play a decisive role and that the question of whether a classical model for the electron does indeed contradict Special Relativity can only be answered on the basis of an exact solution, which has hitherto not been given. (shrink)

While for the majority of physicists the problem of the deciphering of the brain code, the intelligence code, is a matter for future generations, the author boldly and forcefully disagrees. Breaking with the dogma of classical logic he develops in the form of the conversion postulate a concrete working hypothesis for the actual thought mechanism. The reader is invited on a fascinating mathematical journey to the very edges of modern scientific knowledge. From lepton and quark to mind, from cognition to (...) a logic analogue of the Schrodinger equation, from Fibonacci numbers to logic quantum numbers, from imaginary logic to a quantum computer, from coding theory to atomic physics - the breadth and scope of this work is overwhelming. Combining quantum physics, fundamental logic and coding theory this unique work sets the stage for future physics and is bound to titillate and challenge the imagination of physicists, biophysicists and computer designers. Growing from the author's matrix operator formalization of logic, this work pursues a synthesis of physics and logic methods, leading to the development of the concept of infophysics. The experimental verification of the proposed quantum hypothesis of the brain is presently in preparation in cooperation with the Cavendish Laboratory, Cambridge, UK, and, if proved positive, would have major theoretical implications. Even more significant should be the practical applications in such fields as molecular electronics and computer science, biophysics and neuroscience, medicine and education. The new possiblities that could be opened up by quantum level computing could be truly revolutionary. The book aims at researchers and engineers in technical sciences as well as in biophysics and biosciences in general. It should have great appeal for physicists, mathematicians, logicians and for philosophers with a mathematical bent. (shrink)

It is argued that some elusive “entropic” characteristics of chemical bonds, e.g., bond multiplicities (orders), which connect the bonded atoms in molecules, can be probed using quantities and techniques of Information Theory (IT). This complementary perspective increases our insight and understanding of the molecular electronic structure. The specific IT tools for detecting effects of chemical bonds and predicting their entropic multiplicities in molecules are summarized. Alternative information densities, including measures of the local entropy deficiency or its displacement relative to the (...) system atomic promolecule, and the nonadditive Fisher information in the atomic orbital resolution(called contragradience) are used to diagnose the bonding patterns in illustrative diatomic and polyatomic molecules. The elements of the orbital communication theory of the chemical bond are briefly summarized and illustrated for the simplest case of the two-orbital model. The information-cascade perspective also suggests a novel, indirect mechanism of the orbital interactions in molecular systems, through “bridges” (orbital intermediates), in addition to the familiar direct chemical bonds realized through “space”, as a result of the orbital constructive interference in the subspace of the occupied molecular orbitals. Some implications of these two sources of chemical bonds in propellanes, π-electron systems and polymers are examined. The current–density concept associated with the wave-function phase is introduced and the relevant phase-continuity equation is discussed. For the first time, the quantum generalizations of the classical measures of the information content, functionals of the probability distribution alone, are introduced to distinguish systems with the same electron density, but differing in their current(phase) composition. The corresponding information/entropy sources are identified in the associated continuity equations. (shrink)

Freely falling point-like objects converge toward the center of the Earth. Hence the gravitational field of the Earth is inhomogeneous, and possesses a tidal component. The free fall of an extended quantum mechanical object such as a hydrogen atom prepared in a high principal-quantum-number state, i.e. a circular Rydberg atom, is predicted to fall more slowly than a classical point-like object, when both objects are dropped from the same height above the Earth’s surface. This indicates that, apart from (...) transitions between quantum states, the atom exhibits a kind of quantum mechanical incompressibility during free fall in inhomogeneous, tidal gravitational fields like those of the Earth.A superconducting ring-like system with a persistent current circulating around it behaves like the circular Rydberg atom during free fall. Like the electronic wavefunction of the freely falling atom, the Cooper-pair wavefunction is quantum mechanically incompressible. The ions in the lattice of the superconductor, however, are not incompressible, since they do not possess a globally coherent quantum phase. The resulting difference during free fall in the response of the nonlocalizable Cooper pairs of electrons and the localizable ions to inhomogeneous gravitational fields is predicted to lead to a charge separation effect, which in turn leads to a large Coulomb force that opposes the convergence caused by the tidal gravitational force on the superconducting system.A “Cavendish-like” experiment is proposed for observing the charge separation effect induced by inhomogeneous gravitational fields in a superconducting circuit. The charge separation effect is determined to be limited by a pair-breaking process that occurs when low frequency gravitational perturbations are present. (shrink)

1. Introduction Dirac's theory of the electron was the first widely accepted relativistic quantum theory, and it later provided the basis for constructing the modern electromagnetic theory of quantum electrodynamics. Whereas Dirac's theory in its simplest form describes relativistic freely-propagating massive non-chiral particles of spin-½, QED describes how such particles interact with one another electromagnetically, via a dynamical quantum field.