The problem of optical isomerism and the interpretation of quantum mechanics

Foundations of Chemistry 21 (1):97-107 (2019)
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Abstract

When young Kant meditated upon the distinction between his right and left hands, he could not foresee that the problem of incongruent counterparts would revive in the twentieth century under a new form. In the early days of quantum chemistry, Friedrich Hund developed the so-called Hund paradox that arises from the supposed inability of quantum mechanics to account for the difference between enantiomers. In this paper, the paradox is expressed as a case of quantum measurement, stressing that decoherence does not offer a way out of the problem. The main purpose is to argue for the need to adopt a clear interpretation of quantum mechanics in order to solve the paradox. In particular, I claim that the Modal-Hamiltonian Interpretation, which conceives measurement as a breaking-symmetry process, supplies the tools required to explain the dextro-rotation or levo-rotation properties of optical isomers.

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References found in this work

Interpreting the Quantum World.Jeffrey Bub - 1998 - British Journal for the Philosophy of Science 49 (4):637-641.
Ontological reduction and molecular structure.Robin Findlay Hendry - 2010 - Studies in History and Philosophy of Science Part B: Studies in History and Philosophy of Modern Physics 41 (2):183-191.
A modal-Hamiltonian interpretation of quantum mechanics.Olimpia Lombardi & Mario Castagnino - 2008 - Studies in History and Philosophy of Science Part B: Studies in History and Philosophy of Modern Physics 39 (2):380-443.
A modal-Hamiltonian interpretation of quantum mechanics.Olimpia Lombardi & Mario Castagnino - 2008 - Studies in History and Philosophy of Science Part B: Studies in History and Philosophy of Modern Physics 39 (2):380-443.
Two conceptions of the chemical bond.Robin Findlay Hendry - 2008 - Philosophy of Science 75 (5):909-920.

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