When Does a Boltzmannian Equilibrium Exist?

In Cristián Soto (ed.), Current Debates in Philosophy of Science: In Honor of Roberto Torretti. Springer Verlag. pp. 247-273 (2023)
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Abstract

We present a definition of equilibrium for Boltzmannian statistical mechanics based on the long-run fraction of time a system spends in a state. We then formulate and prove an existence theorem which provides general criteria for the existence of an equilibrium state. We illustrate how the theorem works with toy example. After a look at the ergodic programme, we discuss equilibria in a number of different gas systems: the ideal gas, the dilute gas, the Kac gas, the stadium gas, the mushroom gas and the multi-mushroom gas.

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Author Profiles

Charlotte Sophie Werndl
London School of Economics
Roman Frigg
London School of Economics

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