Boltzmann, Gibbs, and the concept of equilibrium

Philosophy of Science 75 (5):682-696 (2008)
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Abstract

The Boltzmann and Gibbs approaches to statistical mechanics have very different definitions of equilibrium and entropy. The problems associated with this are discussed and it is suggested that they can be resolved, to produce a version of statistical mechanics incorporating both approaches, by redefining equilibrium not as a binary property but as a continuous property measured by the Boltzmann entropy and by introducing the idea of thermodynamic-like behaviour for the Boltzmann entropy. The Kac ring model is used as an example to test the proposals.

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David Anthony Lavis
King's College London

Citations of this work

Rethinking boltzmannian equilibrium.Charlotte Werndl & Roman Frigg - 2015 - Philosophy of Science 82 (5):1224-1235.
Entropy - A Guide for the Perplexed.Roman Frigg & Charlotte Werndl - 2011 - In Claus Beisbart & Stephan Hartmann (eds.), Probabilities in Physics. Oxford, GB: Oxford University Press. pp. 115-142.

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References found in this work

Boltzmann and Gibbs: An attempted reconciliation.D. A. Lavis - 2005 - Studies in History and Philosophy of Science Part B: Studies in History and Philosophy of Modern Physics 36 (2):245-273.
Nonequilibrium statistical mechanics Brussels–Austin style.Robert C. Bishop - 2004 - Studies in History and Philosophy of Science Part B: Studies in History and Philosophy of Modern Physics 35 (1):1-30.

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