The book explores several open questions in the philosophy of statistical mechanics. Each chapter is written by a leading expert in the field. Here is a list of some questions that are addressed in the book: 1) Boltzmann showed how the phenomenological gas laws of thermodynamics can be derived from statistical mechanics. Since classical mechanics is a deterministic theory there are no probabilities in it. Since statistical mechanics is based on classical mechanics, (...) all the probabilities statistical mechanics talks about cannot be fundamental. However, if probabilities are epistemic, how can they play a role, as they seem to do, in laws, explanation, and prediction? 2) Many physicists use the notion of typicality instead of the one of probability when discussing statistical mechanics. What is the connection between the two notions? 3) How can one extend Boltzmann’s analysis to the quantum domain, where some theories are indeterministic? 4) Boltzmann’s explanation fundamentally involves cosmology: for the explanation to go through the Big Bang needs to have had extremely low entropy. Does the fact that the Big Bang was a low entropy state imply that it was, in some sense, “highly improbable” and requires an explanation? 5) What exactly is the connection between statistical and classical mechanics? Is the one of theory reduction or there is no such thing? 6) Statistical mechanics has two main formulation: one due to Botzmann and the other due to Gibbs. What is the connection between the two formulations . (shrink)

I argue against the claim, advanced by David Albert and Barry Loewer, that all non-fundamental laws can be derived from those required to underwrite the second law of thermodynamics.

The fundamental problem on which Ilya Prigogine and the Brussels–Austin Group have focused can be stated briefly as follows. Our observations indicate that there is an arrow of time in our experience of the world (e.g., decay of unstable radioactive atoms like uranium, or the mixing of cream in coffee). Most of the fundamental equations of physics are time reversible, however, presenting an apparent conflict between our theoretical descriptions and experimental observations. Many have thought that the observed arrow of time (...) was either an artifact of our observations or due to very special initial conditions. An alternative approach, followed by the Brussels–Austin Group, is to consider the observed direction of time to be a basic physical phenomenon due to the dynamics of physical systems. This essay focuses mainly on recent developments in the Brussels–Austin Group after the mid-1980s. The fundamental concerns are the same as in their earlier approaches (subdynamics, similarity transformations), but the contemporary approach utilizes rigged Hilbert space (whereas the older approaches used Hilbert space). While the emphasis on nonequilibrium statistical mechanics remains the same, their more recent approach addresses the physical features of large Poincare systems, nonlinear dynamics and the mathematical tools necessary to analyze them. (shrink)

In two recent papers Barry Loewer (2001, 2004) has suggested to interpret probabilities in statistical mechanics as Humean chances in David Lewis’ (1994) sense. I first give a precise formulation of this proposal, then raise two fundamental objections, and finally conclude that these can be overcome only at the price of interpreting these probabilities epistemically.

I. Prigogine has proposed, and the writings of N. S. Krylov to some extent suggest, a novel and unorthodox solution to foundational problems in statistical mechanics. In particular, the view claims to offer new insight into two interconnected problems: understanding the role of probability in physics, and that of reconciling the irreversibility of physical processes with the temporal symmetry of dynamical theories. The approach in question advocates a conception of the state of a system which incorporates features of (...) the quantum mechanical state concept in a context, classical statistical mechanics, where quantum considerations are generally considered to be irrelevant. I examine the plausibility of this new approach by offering an analysis of the various notions of state employed in modern physics. ;In the first chapter, I analyze the conceptual connections between dynamical laws and the nature of a system's state. I argue that laws and states are correlative. In constructing dynamical theories one does not start with a fixed or pre-determined state concept. Neither is one given the laws of the theory from which the conception of state is derived. Rather, we get the law/state structure as a "package." In light of this general analysis, I next examine the notion of state employed in the quantum theory. Here I consider a variety of conceptions of quantum states and assess their ability to answer the "paradoxes" of quantum theory. I pay particular attention to the role of probability and related restrictions on the realization of certain states. The new approach to statistical mechanics proposes to exploit similar restrictions on states in order to resolve the irreversibility problem. But is this unorthodox approach viable? In the final four chapters, I offer a detailed critique of this approach, examining the plausibility of the radical reworking of the state concept. I argue that while some important progress can be made, certain old puzzles remain, and new and difficult ones arise--ones which raise serious doubts about the ultimate success of this particular approach. I conclude, however, by arguing that such radical proposals are not unmotivated; and that novel and unorthodox proposals concerning the foundations of statistical mechanics must be taken seriously. (shrink)

In this paper I will argue that the two main approaches to statistical mechanics, that of Boltzmann and Gibbs, constitute two substantially different theoretical apparatuses. Particularly, I defend that this theoretical split must be philosophically understood as a separation of epistemic functions within this physical domain: while Boltzmannians are able to generate powerful explanations of thermal phenomena from molecular dynamics, Gibbsians can statistically predict observable values in a highly effective way. Therefore, statistical mechanics is a counterexample (...) to Hempel's (1958) symmetry thesis, where the predictive capacity of a theory is directly correlated with its explanatory potential and vice versa. (shrink)

There are two theoretical approaches in statistical mechanics, one associated with Boltzmann and the other with Gibbs. The theoretical apparatus of the two approaches offer distinct descriptions of the same physical system with no obvious way to translate the concepts of one formalism into those of the other. This raises the question of the status of one approach vis-à-vis the other. We answer this question by arguing that the Boltzmannian approach is a fundamental theory while Gibbsian statistical (...) mechanics is an effective theory, and we describe circumstances under which Gibbsian calculations coincide with the Boltzmannian results. We then point out that regarding GSM as an effective theory has important repercussions for a number of projects, in particular attempts to turn GSM into a nonequilibrium theory. (shrink)

One finds, in Maxwell's writings on thermodynamics and statistical physics, a conception of the nature of these subjects that differs in interesting ways from the way that they are usually conceived. In particular, though—in agreement with the currently accepted view—Maxwell maintains that the second law of thermodynamics, as originally conceived, cannot be strictly true, the replacement he proposes is different from the version accepted by most physicists today. The modification of the second law accepted by most physicists is a (...) probabilistic one: although statistical fluctuations will result in occasional spontaneous differences in temperature or pressure, there is no way to predictably and reliably harness these to produce large violations of the original version of the second law. Maxwell advocates a version of the second law that is strictly weaker; the validity of even this probabilistic version is of limited scope, limited to situations in which we are dealing with large numbers of molecules en masse and have no ability to manipulate individual molecules. Connected with this is his concept of the thermodynamic concepts of heat, work, and entropy; on the Maxwellian view, these are concepts that must be relativized to the means we have available for gathering information about and manipulating physical systems. The Maxwellian view is one that deserves serious consideration in discussions of the foundation of statistical mechanics. It has relevance for the project of recovering thermodynamics from statistical mechanics because, in such a project, it matters which version of the second law we are trying to recover. (shrink)

Statistical mechanics is a strange theory. Its aims are debated, its methods are contested, its main claims have never been fully proven, and their very truth is challenged, yet at the same time, it enjoys huge empirical success and gives us the feeling that we understand important phenomena. What is this weird theory, exactly? Statistical mechanics is the name of the ongoing attempt to apply mechanics, together with some auxiliary hypotheses, to explain and predict certain (...) phenomena, above all those described by thermodynamics. This paper shows what parts of this objective can be achieved with mechanics by itself. It thus clarifies what roles remain for the auxiliary assumptions that are needed to achieve the rest of the desiderata. Those auxiliary hypotheses are described in another paper in this journal, Foundations of statistical mechanics: The auxiliary hypotheses. (shrink)

In this paper I propose an interpretation of classical statistical mechanics that centers on taking seriously the idea that probability measures represent complete states of statistical mechanical systems. I show how this leads naturally to the idea that the stochasticity of statistical mechanics is associated directly with the observables of the theory rather than with the microstates (as traditional accounts would have it). The usual assumption that microstates are representationally significant in the theory is therefore (...) dispensable, a consequence which suggests interesting possibilities for developing non-equilibrium statistical mechanics and investigating inter-theoretic answers to the foundational questions of statistical mechanics. (shrink)

In "Counterfactual Dependence and Time's Arrow", David Lewis defends an analysis of counterfactuals intended to yield the asymmetry of counterfactual dependence: that later affairs depend counterfactually on earlier ones, and not the other way around. I argue that careful attention to the dynamical properties of thermodynamically irreversible processes shows that in many ordinary cases, Lewis's analysis fails to yield this asymmetry. Furthermore, the analysis fails in an instructive way: it teaches us something about the connection between the asymmetry of overdetermination (...) and the asymmetry of entropy. (shrink)

Based on Newton’s laws reformulated in the Hamiltonian dynamics combined with statistical mechanics, we formulate a statistical mechanical theory supporting the hypothesis of a closed universe oscillating in phase-space. We find that the behavior of this universe as a whole can be represented by a free entropic oscillator whose lifespan is nonhomogeneous, thus implying that time is shorter or longer according to the state of this universe given through its entropy. We conclude that time reduces to the (...) entropy production of this universe and that a nonzero entropy production means that local fluctuations could exist giving rise to the appearance of masses and to the curvature of the space. (shrink)

Statistical mechanics is the name of the ongoing attempt to explain and predict certain phenomena, above all those described by thermodynamics on the basis of the fundamental theories of physics, in particular mechanics, together with certain auxiliary assumptions. In another paper in this journal, Foundations of statistical mechanics: Mechanics by itself, I have shown that some of the thermodynamic regularities, including the probabilistic ones, can be described in terms of mechanics by itself. But (...) in order to prove those regularities, in particular the time asymmetric ones, it is necessary to add to mechanics assumptions of three kinds, all of which are under debate in contemporary literature. One kind of assumptions concerns measure and probability, and here, a major debate is around the notion of “typicality.” A second assumption concerns initial conditions, and here, the debate is about the nature and status of the so-called past hypothesis. The third kind of assumptions concerns the dynamics, and here, the possibility and significance of “Maxwell's Demon” is the main topic of discussions. This article describes these assumptions and examines the justification for introducing them, emphasizing the contemporary debates around them. (shrink)

In recent previous work, the authors proposed a new approach extending the framework of statistical mechanics to reparametrization-invariant systems with no additional gauges. In this paper, the approach is generalized to systems defined by more than one Hamiltonian constraint. We show how well-known features as the Ehrenfest–Tolman effect and the Jüttner distribution for the relativistic gas can be consistently recovered from a covariant approach in the multi-fingered framework. Eventually, the crucial role played by the interaction in the definition (...) of a global notion of equilibrium is discussed. (shrink)

This chapter will review selected aspects of the terrain of discussions about probabilities in statistical mechanics (with no pretensions to exhaustiveness, though the major issues will be touched upon), and will argue for a number of claims. None of the claims to be defended is entirely original, but all deserve emphasis. The first, and least controversial, is that probabilistic notions are needed to make sense of statistical mechanics. The reason for this is the same reason that (...) convinced Maxwell, Gibbs, and Boltzmann that probabilities would be needed, namely, that the second law of thermodynamics, which in its original formulation says that certain processes are impossible, must, on the kinetic theory, be replaced by a weaker formulation according to which what the original version deems impossible is merely improbable. Second is that we ought not take the standard measures invoked in equilibrium statistical mechanics as giving, in any sense, the correct probabilities about microstates of the system. We can settle for a much weaker claim: that the probabilities for outcomes of experiments yielded by the standard distributions are effectively the same as those yielded by any distribution that we should take as a representing probabilities over microstates. Lastly, (and most controversially): in asking about the status of probabilities in statistical mechanics, the familiar dichotomy between epistemic probabilities (credences, or degrees of belief) and ontic (physical) probabilities is insufficient; the concept of probability that is best suited to the needs of statistical mechanics is one that combines epistemic and physical considerations. (shrink)

Statistical mechanics is often taken to be the paradigm of a successful inter-theoretic reduction, which explains the high-level phenomena (primarily those described by thermodynamics) by using the fundamental theories of physics together with some auxiliary hypotheses. In my view, the scope of statistical mechanics is wider since it is the type-identity physicalist account of all the special sciences. But in this chapter, I focus on the more traditional and less controversial domain of this theory, namely, that (...) of explaining the thermodynamic phenomena.What are the fundamental theories that are taken to explain the thermodynamic phenomena? The lively research into the foundations of classical statistical mechanics suggests that using classical mechanics to explain the thermodynamic phenomena is fruitful. Strictly speaking, in contemporary physics, classical mechanics is considered to be false. Since classical mechanics preserves certain explanatory and predictive aspects of the true fundamental theories, it can be successfully applied in certain cases. In other circumstances, classical mechanics has to be replaced by quantum mechanics. In this chapter I ask the following two questions: I) How does quantum statistical mechanics differ from classical statistical mechanics? How are the well-known differences between the two fundamental theories reflected in the statistical mechanical account of high-level phenomena? II) How does quantum statistical mechanics differ from quantum mechanics simpliciter? To make our main points I need to only consider non-relativistic quantum mechanics. Most of the ideas described and addressed in this chapter hold irrespective of the choice of a (so-called) interpretation of quantum mechanics, and so I will mention interpretations only when the differences between them are important to the matter discussed. (shrink)

To complete our ontological interpretation of quantum theory we have to conclude a treatment of quantum statistical mechanics. The basic concepts in the ontological approach are the particle and the wave function. The density matrix cannot play a fundamental role here. Therefore quantum statistical mechanics will require a further statistical distribution over wave functions in addition to the distribution of particles that have a specified wave function. Ultimately the wave function of the universe will he (...) required, but we show that if the universe in not in thermodynamic equilibrium then it can he treated in terms of weakly interacting large scale constituents that are very nearly independent of each other. In this way we obtain the same results as those of the usual approach within the framework of the ontological interpretation. (shrink)

Discussions of the foundations of Classical Equilibrium Statistical Mechanics (SM) typically focus on the problem of justifying the use of a certain probability measure (the microcanonical measure) to compute average values of certain functions. One would like to be able to explain why the equilibrium behavior of a wide variety of distinct systems (different sorts of molecules interacting with different potentials) can be described by the same averaging procedure. A standard approach is to appeal to ergodic theory to (...) justify this choice of measure. A different approach, eschewing ergodicity, was initiated by A. I. Khinchin. Both explanatory programs have been subjected to severe criticisms. This paper argues that the Khinchin type program deserves further attention in light of relatively recent results in understanding the physics of universal behavior. (shrink)

This article argues that most of the approaches to the foundations of statistical mechanics have severed their link with the original foundational project, the project of demonstrating how real mechanical systems can behave thermodynamically.

In the previous papers, it was demonstrated that applying the principle of maximum information entropy by maximizing the conditional information entropy, subject to the constraint given by the Liouville equation averaged over the phase space, leads to a definition of the rate of entropy change for closed Hamiltonian systems without any additional assumptions. Here, we generalize this basic model and, with the introduction of the additional constraints which are equivalent to the hydrodynamic continuity equations, show that the results obtained are (...) consistent with the known results from the nonequilibrium statistical mechanics and thermodynamics of irreversible processes. In this way, as a part of the approach developed in this paper, the rate of entropy change and entropy production density for the classical Hamiltonian fluid are obtained. The results obtained suggest the general applicability of the foundational principles of predictive statistical mechanics and their importance for the theory of irreversibility. (shrink)

I give a brief account of the way in which thermodynamics and statistical mechanics actually work as contemporary scientific theories, and in particular of what statistical mechanics contributes to thermodynamics over and above any supposed underpinning of the latter's general principles. In doing so, I attempt to illustrate that statistical mechanics should not be thought of wholly or even primarily as itself a foundational project for thermodynamics, and that conceiving of it this way potentially (...) distorts the foundational study of statistical mechanics itself. (shrink)

This second part of a two-part essay discusses recent developments in the Brussels-Austin Group after the mid 1980s. The fundamental concerns are the same as in their similarity transformation approach (see Part I), but the contemporary approach utilizes rigged Hilbert space (whereas the older approach used Hilbert space). While the emphasis on nonequilibrium statistical mechanics remains the same, the use of similarity transformations shifts to the background. In its place arose an interest in the physical features of large (...) Poincaré systems, nonlinear dynamics and the mathematical tools necessary to analyze them. (shrink)

This is an extensive review of recent work on the foundations of statistical mechanics.

In a quantum universe with a strong arrow of time, it is standard to postulate that the initial wave function started in a particular macrostate---the special low-entropy macrostate selected by the Past Hypothesis. Moreover, there is an additional postulate about statistical mechanical probabilities according to which the initial wave function is a ''typical'' choice in the macrostate. Together, they support a probabilistic version of the Second Law of Thermodynamics: typical initial wave functions will increase in entropy. Hence, there are (...) two sources of randomness in such a universe: the quantum-mechanical probabilities of the Born rule and the statistical mechanical probabilities of the Statistical Postulate. I propose a new way to understand time's arrow in a quantum universe. It is based on what I call the Thermodynamic Theories of Quantum Mechanics. According to this perspective, there is a natural choice for the initial quantum state of the universe, which is given by not a wave function but by a density matrix. The density matrix plays a microscopic role: it appears in the fundamental dynamical equations of those theories. The density matrix also plays a macroscopic / thermodynamic role: it is exactly the projection operator onto the Past Hypothesis subspace. Thus, given an initial subspace, we obtain a unique choice of the initial density matrix. I call this property "the conditional uniqueness" of the initial quantum state. The conditional uniqueness provides a new and general strategy to eliminate statistical mechanical probabilities in the fundamental physical theories, by which we can reduce the two sources of randomness to only the quantum mechanical one. I also explore the idea of an absolutely unique initial quantum state, in a way that might realize Penrose's idea of a strongly deterministic universe. (shrink)

A statistical mechanical treatment is given of thermal contact between two systems. Reciprocal temperature emerges from this as the relative change in the number of microscopic states a macroscopic system at equilibrium ranges over, at constant volume and chemical composition, with change in internal energy. The significance of this is discussed in detail with reference to a monatomic gas and an Einstein solid.

The aging of the two brothers in the “twins paradox” is analyzed through the space-time evolution of the densities that correspond to their internal complex structure. Taking into account their relative motion, it is shown that the traveling brother evolves over a shorter interval of time than his twin, which makes him younger than his brother.

The aim of the present paper is to show that the formalism of equilibrium quantum statistical mechanics can fully be incorporated into Ludwig's embedding scheme for classical theories in many-body quantum mechanics. A construction procedure based on a recently developed reconstruction procedure for the so-called macro-observable is presented which leads to the explicit determination of the set of classical ensembles compatible with the embedding scheme.

Requiring only a background in elementary calculus and elementary mechanics, this book starts with the basics, introduces the most important developments in classical statistical mechanics over the last thirty years, and guides readers to ...

The paper reviews statistical models for money, wealth, and income distributions developed in the econophysics literature since the late 1990s. By analogy with the Boltzmann-Gibbs distribution of energy in physics, it is shown that the probability distribution of money is exponential for certain classes of models with interacting economic agents. Alternative scenarios are also reviewed. Data analysis of the empirical distributions of wealth and income reveals a two-class distribution. The majority of the population belongs to the lower class, characterized (...) by the exponential (“thermal”) distribution, whereas a small fraction of the population in the upper class is characterized by the power-law (“superthermal”) distribution. The lower part is very stable, stationary in time, whereas the upper part is highly dynamical and out of equilibrium. (shrink)

The formulation of manifestly covariant relativistic statistical mechanics as the description of an ensemble of events in spacetime parametrized by an invariant proper-time τ is reviewed. The linear and cubic mass spectra, which result from this formulation (the latter with the inclusion of anti-events) as the actual spectra of an individual hadronic multiplet and hot hadronic matter, respectively, are discussed. These spectra allow one to predict the masses of particles nucleated to quasi-levels in such an ensemble. As an (...) example, the masses of the ground-state mesons and baryons are considered; the results are in excellent agreement with the measured hadron masses. Additivity of inverse Regge slopes is established and shown to be consistent with available experimental data on the D meson and Λc baryon production. (shrink)

Information theory and statistical mechanics II.

Statistical mechanics involves probabilities. At the same time, most approaches to the foundations of statistical mechanics--programs whose goal is to understand the macroscopic laws of thermal physics from the point of view of microphysics--are classical; they begin with the assumption that the underlying dynamical laws that govern the microscopic furniture of the world are deterministic. This raises some potential puzzles about the proper interpretation of these probabilities.

The self-avoiding walk is a classical model in statistical mechanics, probability theory and mathematical physics. It is also a simple model of polymer entropy which is useful in modelling phase behaviour in polymers. This monograph provides an authoritative examination of interacting self-avoiding walks, presenting aspects of the thermodynamic limit, phase behaviour, scaling and critical exponents for lattice polygons, lattice animals and surfaces. It also includes a comprehensive account of constructive methods in models of adsorbing, collapsing, and pulled walks, (...) animals and networks, and for models of walks in confined geometries. Additional topics include scaling, knotting in lattice polygons, generating function methods for directed models of walks and polygons, and an introduction to the Edwards model.This essential second edition includes recent breakthroughs in the field, as well as maintaining the older but still relevant topics. New chapters include an expanded presentation of directed models, an exploration of methods and results for the hexagonal lattice, and a chapter devoted to the Monte Carlo methods. (shrink)

Statistical Mechanics (SM) involves probabilities. At the same time, most approaches to the foundations of SM—programs whose goal is to understand the macroscopic laws of thermal physics from the point of view of microphysics—are classical; they begin with the assumption that the underlying dynamical laws that govern the microscopic furniture of the world are (or can without loss of generality be treated as) deterministic. This raises some potential puzzles about the proper interpretation of these probabilities. It also raises, (...) more generally, the question of what kinds, if any, of objective probabilities can exist in a deterministic world. (shrink)

In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann’s analysis, the essence of which I shall review here, is basically correct. The most famous criticisms of Boltzmann’s later work on the subject have little merit. Most twentieth century innovations – such as the identification of the state of a physical system with a probability distribution on its phase space, (...) of its thermodynamic entropy with the Gibbs entropy of , and the invocation of the notions of ergodicity and mixing for the justification of the foundations of statistical mechanics – are thoroughly misguided. (shrink)

In Boltzmannian statistical mechanics macro-states supervene on micro-states. This leads to a partitioning of the state space of a system into regions of macroscopically indistinguishable micro-states. The largest of these regions is singled out as the equilibrium region of the system. What justifies this association? We review currently available answers to this question and find them wanting both for conceptual and for technical reasons. We propose a new conception of equilibrium and prove a mathematical theorem which establishes in (...) full generality -- i.e. without making any assumptions about the system's dynamics or the nature of the interactions between its components -- that the equilibrium macro-region is the largest macro-region. We then turn to the question of the approach to equilibrium, of which there exists no satisfactory general answer so far. In our account, this question is replaced by the question when an equilibrium state exists. We prove another -- again fully general -- theorem providing necessary and sufficient conditions for the existence of an equilibrium state. This theorem changes the way in which the question of the approach to equilibrium should be discussed: rather than launching a search for a crucial factor, the focus should be on finding triplets of macro-variables, dynamical conditions, and effective state spaces that satisfy the conditions of the theorem. (shrink)

Statistical mechanics is one of the crucial fundamental theories of physics, and in his new book Lawrence Sklar, one of the pre-eminent philosophers of physics, offers a comprehensive, non-technical introduction to that theory and to attempts to understand its foundational elements. Among the topics treated in detail are: probability and statistical explanation, the basic issues in both equilibrium and non-equilibrium statistical mechanics, the role of cosmology, the reduction of thermodynamics to statistical mechanics, and (...) the alleged foundation of the very notion of time asymmetry in the entropic asymmetry of systems in time. The book emphasises the interaction of scientific and philosophical modes of reasoning, and in this way will interest all philosophers of science as well as those in physics and chemistry concerned with philosophical questions. The book could also be read by an informed general reader interested in the foundations of modern science. (shrink)

In a previous work (M. Campisi. Stud. Hist. Phil. M. P. 36 (2005) 275-290) we have addressed the mechanical foundations of equilibrium thermodynamics on the basis of the Generalized Helmholtz Theorem. It was found that the volume entropy provides a good mechanical analogue of thermodynamic entropy because it satisfies the heat theorem and it is an adiabatic invariant. This property explains the ``equal'' sign in Clausius principle ($S_f \geq S_i$) in a purely mechanical way and suggests that the volume entropy (...) might explain the ``larger than'' sign (i.e. the Law of Entropy Increase) if non adiabatic transformations were considered. Based on the principles of microscopic (quantum or classical) mechanics here we prove that, provided the initial equilibrium satisfy the natural condition of decreasing ordering of probabilities, the expectation value of the volume entropy cannot decrease for arbitrary transformations performed by some external sources of work on a insulated system. This can be regarded as a rigorous quantum mechanical proof of the Second Law. We discuss how this result relates to the Minimal Work Principle and improves over previous attempts. The natural evolution of entropy is towards larger values because the natural state of matter is at positive temperature. Actually the Law of Entropy Decrease holds in artificially prepared negative temperature systems. (shrink)

The paper reviews statistical models for money, wealth, and income distributions developed in the econophysics literature since the late 1990s. By analogy with the Boltzmann-Gibbs distribution of energy in physics, it is shown that the probability distribution of money is exponential for certain classes of models with interacting economic agents. Alternative scenarios are also reviewed. Data analysis of the empirical distributions of wealth and income reveals a two-class distribution. The majority of the population belongs to the lower class, characterized (...) by the exponential (“thermal”) distribution, whereas a small fraction of the population in the upper class is characterized by the power-law (“superthermal”) distribution. The lower part is very stable, stationary in time, whereas the upper part is highly dynamical and out of equilibrium. (shrink)

Information theory and statistical mechanics.

The fundamental problem on which Ilya Prigogine and the Brussels-Austin Group have focused can be stated briefly as follows. Our observations indicate that there is an arrow of time in our experience of the world (e.g., decay of unstable radioactive atoms like Uranium, or the mixing of cream in coffee). Most of the fundamental equations of physics are time reversible, however, presenting an apparent conflict between our theoretical descriptions and experimental observations. Many have thought that the observed arrow of time (...) was either an artifact of our observations or due to very special initial conditions. An alternative approach, followed by the Brussels-Austin Group, is to consider the observed direction of time to be a basic physical phenomenon and to develop a mathematical formalism that can describe this direction as being due to the dynamics of physical systems. In part I of this essay, I review and assess an attempt to carry out an approach that received much of their attention from the early 1970s to the mid 1980s. In part II, I will discuss their more recent approach using rigged Hilbert spaces. (shrink)