The consequences of a generalized Dirac equation are discussed for the energy levels of the hydrogen atom. Apart from the usual generalizations of the Dirac equation by adding new interaction terms, we generalize the anticommutation rule of the Dirac matrices, which leads to spin-dependent propagation properties. Such a theory can be looked at as a model theory for testing Lorentz invariance or as an outcome of pregeometric dynamical induction schemes for space-time structure.For special examples of generalized Dirac matrices (...) including perturbation terms with respect to the SRT Dirac matrices, we derive the energy level of the hydrogen atom and find a hyperfine splitting due to these perturbations. A comparison of this additional splitting with Lamb shift measurements gives us upper limits for possible perturbations, which turn out to be of measurable magnitude. Spin precession experiments give much more restrictive limits. So, it turns out that the hydrogen atom is not such a sensitive indicator for the Lorentz invariance as widely believed. (shrink)

Niels Bohr’s model of the hydrogen atom is widely cited as an example of an inconsistent scientific theory because of its reliance on classical electrodynamics together with assumptions about interactions between matter and electromagnetic radiation that could not be reconciled with CED. This view of Bohr’s model is controversial, but we believe a recently proposed approach to reasoning with inconsistent commitments offers a promising formal reading of how Bohr’s model worked. In this paper we present this new way (...) of reasoning with inconsistent commitments and compare it with other approaches before applying it to Bohr’s model and offering some suggestions for how it might be extended to account for subsequent developments in old quantum theory. (shrink)

The operator structures for the constants of the motion of the relativistic hydrogen atom are examined. ThoughJ 3 andJ · J are constants of the motion,J is not. Its replacement, $\tilde {\rm K}$ , is shown to emerge rather naturally in transforming the equation to spherical coordinates. The separation of variables is presented in hypercomplex number form. This leads to some interesting suggestions regarding the matter/antimatter operator for the Dirac equation.

The second-order radial differential equations for the relativistic Dirac hydrogen atom are derived from the Dirac equation treated as a system of partial differential equations. The quantum operators which arise in the development are defined and interpreted as they appear. The splitting in the energy levels is computed by applying the theory of singularities for second-order differential equations to the Klein-Gordon and Dirac relativistic equations. In the Dirac radial equation additional terms appear containing a constant, which is shown (...) to be the “radius of the electron.” It is concluded that the minute perturbation of the radial eigenfunction in the vicinity of the proton brought about by the extension of the elementary particles, which appears naturally out of the Dirac equations, results in the prediction of the observed splitting of the hydrogen atom energy levels by the Dirac theory. The extension of the particles arises even though the Dirac hydrogen atom is originally formulated for point charges. (shrink)

We review some of the progress made in the past 27 years in understanding the group theoretic and path integral aspects of the hydrogen atom. The group theoretic development was triggered by A. O. Barut who suggested to me the search for a dynamical group larger than SO(4). In this way he became indirectly responsible also for important recent path integral developments.

Asim Barut once,en passant, asked the question “For what transitions of the hydrogen atom do the spectral lines coincide”? It is a pleasure for us to give the answer in this paper.

It is usually claimed that the Laguerre polynomials were popularized by Schrödinger when creating wave mechanics; however, we show that he did not immediately identify them in studying the hydrogen atom. In the case of relativistic Dirac equations for an electron in a Coulomb field, Dirac gave only approximations, Gordon and Darwin gave exact solutions, and Pidduck first explicitly and elegantly introduced the Laguerre polynomials, an approach neglected by most modern treatises and articles. That Laguerre polynomials were not (...) very popular before their use in quantum mechanics, probably because they had been little used in classical mathematical physics, is confirmed by the fact that, as we show, they had been rediscovered independently several times during the nineteenth century, in published or unpublished studies of Abel, Murphy, Chebyshev, and Laguerre. (shrink)

We treat the classical dynamics of the hydrogen atom in perpendicular electric and magnetic fields as a celestial mechanics problem. By expressing the Hamiltonian in appropriate action–angle variables, we separate the different time scales of the motion. The method of averaging then allows us to reduce the system to two degrees of freedom, and to classify the most important periodic orbits.

Quantum mechanics teaches that before detection, knowledge of particle position is, at best, probabilistic, and classical trajectories are seen as a feature of the macroscopic world. These comments refer to detected particles, but we are still free to consider the motions generated by the wave equation. Within hydrogen, the Schrodinger equation allows calculation of kinetic energy at any location, and if this is identified as the energy of the wave, then radial momentum, allowing for spherical harmonics, becomes available. The (...) distance across the real zone of radial momentum is found to match semi-integer wavelengths of the adjusted matter wave, consistent with what is expected from a standing wave condition. The approach is extended to include orbital motions, where it is established that the underlying wave, which has direction and wavelength at each location, forms a series of connected trajectories, which are shown to be ellipses orientated at various angles to the equatorial plane. This suggests that wave trajectories, rather than particle trajectories, are still a feature of the hydrogen atom. The finding allows the reason for the coincidence between energy results derived by Sommerfeld’s classical trajectories and the Schrodinger wave equation to be appreciated. The result has implications when the relativistic situation is considered, as Sommerfeld’s correct deduction of the relativistic energy levels of hydrogen well before Dirac derived his wave equation has long been somewhat puzzling. (shrink)

The general expressions with retardation of the matrix elements for a central potential of the transitions S1/2−P1/2 and S1/2−P3/2 have been established previously for all the cases of degeneracies. Here, they are calculated, for any Z, as combinations of hypergeometric series, for the transitions between 1S1/2 and the continuum (photoeffect). A verification of the results is achieved for the approximation Z2α2≪κ2 by using the integral representation in the complex plane of the confluent hypergeometric functions and the residues theorem.

By using a geometrical form of the Darwin solutions of the Dirac equation, the general expressions with retardation of the matrix elements of the transitions S1/2-P1/2 and S1/2-P3/2 are established. The extension to the calculation with retardation of the sum rules relative to the intensities in the anomal Zeemann decomposition of the transitions between two levels is carried out.

Within the context of Born-Infeld (BI) nonlinear electrodynamics (NED) we revisit the non-relativistic, spinless H-atom. The pair potential computed from the Born-Infeld equations is approximated by the Morse type potential with remarkable fit over the critical region where the convergence of both the short and long distance expansions slows down dramatically. The Morse potential is employed to determine both the ground state energy of the electron and the BI parameter.

The Einstein-de Broglie soliton concept is applied to simulate stationary states of an electron in a hydrogen atom. According to this concept, the electron is described by the localized regular solutions to some nonlinear equations. It is shown that the electron-solilon center travels along some stationary orbit around the Coulomb center. The electromagnetic radiation is absent as the Poynting vector has non-wave asymptote O(r −3)after averaging over angles.

Freely falling point-like objects converge toward the center of the Earth. Hence the gravitational field of the Earth is inhomogeneous, and possesses a tidal component. The free fall of an extended quantum mechanical object such as a hydrogen atom prepared in a high principal-quantum-number state, i.e. a circular Rydberg atom, is predicted to fall more slowly than a classical point-like object, when both objects are dropped from the same height above the Earth’s surface. This indicates that, apart (...) from transitions between quantum states, the atom exhibits a kind of quantum mechanical incompressibility during free fall in inhomogeneous, tidal gravitational fields like those of the Earth.A superconducting ring-like system with a persistent current circulating around it behaves like the circular Rydberg atom during free fall. Like the electronic wavefunction of the freely falling atom, the Cooper-pair wavefunction is quantum mechanically incompressible. The ions in the lattice of the superconductor, however, are not incompressible, since they do not possess a globally coherent quantum phase. The resulting difference during free fall in the response of the nonlocalizable Cooper pairs of electrons and the localizable ions to inhomogeneous gravitational fields is predicted to lead to a charge separation effect, which in turn leads to a large Coulomb force that opposes the convergence caused by the tidal gravitational force on the superconducting system.A “Cavendish-like” experiment is proposed for observing the charge separation effect induced by inhomogeneous gravitational fields in a superconducting circuit. The charge separation effect is determined to be limited by a pair-breaking process that occurs when low frequency gravitational perturbations are present. (shrink)

Every so often an experiment trying to give reliable evidence for a metallic hydrogen solid is reported. Such evidence is, however, not too convincing. As Eric Scerri has recently reiterated, “the jury is still out on that issue” . This search stems from the common spectroscopy shared by the hydrogen atom and all the alkali metal atoms, and perhaps is guided by a desire to place hydrogen atop the alkali metals, in Mendeleiev’s Table, reinforced by the (...) fact pointed out by Scerri that there is no other obvious place for hydrogen in said Table. But H2 is a light gas at room temperature, while Li, Na, K and the other alkali elements form solid metal crystals. At very low temperatures, of course, hydrogen solidifies, but it is formed by H2 molecules . Our purpose here is to use a new argument to break this impasse: “should H be grouped with the alkali metals with which it shares a common spectroscopy, but which solidifies in a completely different fashion?” This argument has been proposed before in a couple of papers in this journal to establish a similar question for He and the alkaline earths , as is discussed in “Precedents” section. (shrink)

In the long history of science there is nothing quite like the famous dialogue which ensued between Albert Einstein and Neils Bohr about the validity and meaning of the new quantum theory. By 1927 when the first public debate took place, both men stood at the top of their profession. Einstein was the creator of the Special and General theories of relativity and also had made major contributions to atomic theory. Bohr had developed the successful model of the hydrogen (...) atom in 1913 and his two principles of correspondence and complementarity had established the relationship between classical physics and the new physics of the atom. MacKinnon treats this Bohr-Einstein dialogue as the centerpiece and climax of his book on the history of Atomism from a philosophical perspective. It is a carefully written and closely argued discussion of the contributions of significant scientists and philosophers of science to the perennial question about nature: is it made up of discrete nonreducible parts or is it continuous and infinitely divisible? (shrink)

Traditional nomological accounts of scientific explanation have assumed that a good scientific explanation consists in the derivation of the explanandum’s description from theory (plus antecedent conditions). But in more recent philosophy of science the adequacy of this approach has been challenged, because the relation between theory and phenomena in actual scientific practice turns out to be more intricate. This critique is here examined for an explanatory paradigm that was groundbreaking for 20th century physics and chemistry (and their interrelation): Bohr’s first (...) model of the atom and its explanatory relevance for the spectrum of hydrogen. First, the model itself is analysed with respect to the principles and assumptions that enter into its premises. Thereafter, the origin of the model’s explanandum is investigated. It can be shown that the explained “phenomenon” is itself the product of a host of modelling accomplishments that stem from an experimental tradition related to 19th century chemistry, viz. spectroscopy. The relation between theory and phenomenon is thus mediated in a twofold way: by (Bohr’s) theoretical model and a phenomenological model from spectroscopy. In the final section of the paper an account is outlined that nevertheless permits us to acknowledge this important physico-chemical achievement as a case of (nomological) explanation. (shrink)

Prout's hypothesis was influential in—if not necessary for—the establishment of the atomic weight of oxygen, a figure conclusively demonstrated in 1895. Ironically, the successful determination of oxygen's weight also led to a final refutation of the hypothesis . But more than this, the end of Prout's hypothesis via the determination of oxygen's atomic weight was due to three fundamental changes that characterized the way chemistry was practised and communicated in the late nineteenth century. First, encyclopaedia‐like presentations of past atomic‐weight investigations (...) became the focus in numerous and influential studies. Second, there was a dramatic change in the way professional publications presented investigations and experiments, characterized by experimental detail and apparatus design at the expense of theoretical discussion. Finally, the production of hydrogen became the focus of research, as it was one of the principal components of any investigation into atomic weights. Here I present Prout's hypothesis in its historical context by focusing on these three developments and their influence on the research of Edward Williams Morley. While doing so I also illustrate the way marginalized scientists were able to take advantage of their otherwise dubious position and participate in an active and important role in atomic‐weight investigations. (shrink)

The Periodic Table has the column of the noble gas atoms (He, Ne, Ar, Kr, Xe, Rn) as one of its main pillars. Indeed the inert chemical nature of their closed shell structure is so striking that it is sometimes extended to all such structures. Is it true however that any closed shell, say a closed d-subshell will denote a lack of chemical activity? Take the noble metals for instance, so renowned for their catalytic capacity. Platinum has 10 electrons in (...) its valence shell which makes one of its excited states to be a closed 5d10–6s0 state. Surely this state would not be expected to be crucial to the catalytic activity of platinum, or would it? Or take palladium whose ground state is precisely the 4d10–5s0 state, should we expect that an isolated Pd atom at near zero-point temperature would attack a closed-shell hydrogen molecule efficiently? We shall here show that this is precisely the case; the closed-shell excited states of nickel and platinum are indeed crucial, through symmetry avoided crossings, for their reactivity. Other valuable catalysts as ruthenium depend on their excited states with maximal d-shell occupancy for their activity. The most notable confirmation of this new finding; that closed d-shells are vital to the catalytic activity of noble metals however, is the case of palladium whose closed-shell ground state is indeed capable of attacking hydrogen and hydrocarbon molecules even at temperatures well below 10 K as was predicted theoretically and immediately confirmed experimentally. (shrink)

Symmetry is at the heart of our understanding of matter. This book tells the fascinating story of the constituents of matter from a common symmetry perspective. The standard model of elementary particles and the periodic table of chemical elements have the common goal to bring order in the bewildering chaos of the constituents of matter. Their success relies on the presence of fundamental symmetries in their core. -/- The purpose of Shattered Symmetry is to share the admiration for the power (...) and the beauty of these symmetries. The reader is taken on a journey from the basic geometric symmetry group of a circle to the sublime dynamic symmetries that govern the motions of the particles. Along the way the theory of symmetry groups is gradually introduced with special emphasis on its use as a classification tool and its graphical representations. This is applied to the unitary symmetry of the eightfold way of quarks, and to the four-dimensional symmetry of the hydrogen atom. The final challenge is to open up the structure of Mendeleev's table which goes beyond the symmetry of the hydrogen atom. Breaking this symmetry to accommodate the multi-electron atoms requires us to leave the common ground of linear algebras and explore the potential of non-linearity. (shrink)

The electronic and muonic hydrogen energy levels are calculated very accurately [1] in Quantum Electrodynamics (QED) by coupling the Dirac Equation four vector (c ,mc2) current covariantly with the external electromagnetic (EM) field four vector in QED’s Interactive Representation (IR). The c -Non Exclusion Principle(c -NEP) states that, if one accepts c as the electron/muon velocity operator because of the very accurate hydrogen energy levels calculated, the one must also accept the resulting electron/muon internal spatial and time coordinate (...) operators (ISaTCO) derived directly from c without any assumptions. This paper does not change any of the accurate QED calculations of hydrogen’s energy levels, given the simplistic model of the proton used in these calculations [1]. The Proton Radius Puzzle [2, 3] may indicate that new physics is necessary beyond the Standard Model (SM), and this paper describes the bizarre, and very different, situation when the electron and muon are located “inside” the spatially extended proton with their Centers of Charge (CoCs) orbiting the proton at the speed of light in S energy states. The electron/muon center of charge (CoC) is a structureless point that vibrates rapidly in its inseparable, non-random vacuum whose geometry and time structure are defined by the electron/muon ISaTCO discrete geometry. The electron/muon self mass becomes finite in a natural way due to the ISaTCOs cutting off high virtual photon energies in the photon propagator. The Dirac-Maxwell-Wilson (DMW) Equations are derived from the ISaTCO for the EM fields of an electron/muon, and the electron/muon “look” like point particles in far field scattering experiments in the same way the electric field from a sphere with evenly distributed charge “e” “looks” like a point with the same charge in the far field (Gauss Law). The electron’s/muon’s three fluctuating CoC internal spatial coordinate operators have eight possible eigenvalues [4, 5, 6] that fall on a spherical shell centered on the electron’s CoM with radius in the rest frame. The electron/muon internal time operator is discrete, describes the rapid virtual electron/positron pair production and annihilation. The ISaTCO together create a current that produce spin and magnetic moment operators, and the electron and muon no longer have “intrinsic” properties since the ISaTCO kinematics define spin and magnetic moment properties. (shrink)

1. Introduction : humanity's urge to understand -- 2. Elements of scientific thinking : skepticism, careful reasoning, and exhaustive evaluation are all vital. Science Is universal -- Maintaining a critical attitude. Reasonable skepticism -- Respect for the truth -- Reasoning. Deduction -- Induction -- Paradigm shifts -- Evaluating scientific hypotheses. Ockham's razor -- Quantitative evaluation -- Verification by others -- Statistics : correlation and causation -- Statistics : the indeterminacy of the small -- Careful definition -- Science at the frontier. (...) When good theories become ugly -- Stuff that just does not fit -- 3. Christopher Columbus and the discovery of the "Indies" : it can be disastrous to stubbornly refuse to recognize that you have falsified your own hypothesis -- 4. Antoine Lavoisier and Joseph Priestley both test the befuddling phlogiston theory : junking a confusing hypothesis may be necessary to clear the way for new and productive science -- 5. Michael Faraday discovers electromagnetic induction but fails to unify electromagnetism and gravitation : it is usually productive to simplify and consolidate your hypotheses -- 6. Wilhelm Röntgen intended to study cathode rays but ended up discovering X-rays : listen carefully when Mother Nature whispers in your ear : she may be leading you to a Nobel Prize -- 7. Max Planck, the first superhero of quantum theory, saves the universe from the ultraviolet catastrophe : assemble two flawed hypotheses about a key phenomenon into a model that fits experiment exactly and people will listen to you even if you must revolutionize physics -- 8. Albert Einstein attacks the problem "Are atoms real?" from every angle : solving a centuries-old riddle in seven different ways can finally resolve it -- 9. Niels Bohr models the hydrogen atom as a quantized system with compelling exactness, but his later career proves that collaboration and developing new talent can become more significant than the groundbreaking research of any individual -- 10. Conclusions, status of science, and lessons for our time. Conclusions from our biographies -- What thought processes lead to innovation? -- Is the scientist an outsider? -- The status of the modern scientific enterprise -- Lessons for our time -- Can the scientific method be applied to public policy? -- Why so little interest in science? -- Knowledge is never complete. (shrink)

Starting with Galileo's experiments with motion, this study of 25 crucial discoveries includes Newton's laws of motion, Chadwick's study of the neutron, Hertz on electromagnetic waves, and more. Includes Isaac Newton's "The Laws of Motion," Henry Cavendish's "The Law of Gravitation," Heinrich Hertz's "Electromagnetic Waves," Niels Bohr's "The Hydrogen Atom," and more.

Scientists often think of the world as a dynamical system, a stochastic process, or a generalization of such a system. Prominent examples of systems are the system of planets orbiting the sun or any other classical mechanical system, a hydrogen atom or any other quantum–mechanical system, and the earth’s atmosphere or any other statistical mechanical system. We introduce a general and unified framework for describing such systems and show how it can be used to examine some familiar philosophical (...) questions, including the following: how can we define nomological possibility, necessity, determinism, and indeterminism; what are symmetries and laws; what regularities must a system display to make scientific inference possible; how might principles of parsimony such as Occam’s Razor help when we make such inferences; what is the role of space and time in a system; and might they be emergent features? Our framework is intended to serve as a toolbox for the formal analysis of systems that is applicable in several areas of philosophy. (shrink)

There is a widespread assumption that the classical work in philosophical semantics of Saul Kripke (1980) and Hilary Putnam (1975) has taught us that the essences of natural kinds of substances, such as water and gold, are discoverable only a posteriori by scientific investigation. It is such investigation, thus, that has supposedly revealed to us that it is an essential property of water that it is composed of H2O molecules. This is the way in which Scott Soames, in a recent (...) paper, makes the point in the case of water and H2O: [Here is] how a Kripkean explanation of the necessary a posteriority of [‘Water = H2O’] would go – or at any rate my version of it. The account holds that ‘water’ is a non-descriptive, directly-referential term designating a substance – where substances are taken to be physically constitutive kinds (instances of which share the same basic physical constitution). It is further assumed that a kind of this sort may have different instances in different world-states, and that if a and b are kinds with the same instances in all possible world-states, then a is b. These are clearly metaphysical assumptions, to which we add the natural corollary that for any substance, s, if, in some possible world-state, instances of s have a certain molecular structure, then instances of s have that structure in every world-state. In other words, we assume that it is an essential property of a substance that instances of it have the molecular structure they do. From this it follows that [‘Water = H2O’] is necessary if true, and that ‘H2O’– which I take to be equivalent to ‘the substance instances of which have a molecular structure with two hydrogen atoms and one oxygen atom’– is a rigid designator. Being true, [‘Water = H2O’] is, therefore, necessary. Since knowing the proposition it expresses requires knowing of a certain substance that its instances have a particular chemical structure, [‘Water = H2O’] is knowable only a posteriori. (Soames 2007: 36). (shrink)

An introduction to temporal parts theory. Most of us believe in spatial parts: hands are spatial parts of people, an electron is a spatial part of a hydrogen atom, the earth is a spatial part of the solar system. Why are these parts "spatial" parts? Because they are spatially smaller: the hand is spatially smaller than the person, the electron is spatially smaller than the atom, the earth is spatially smaller than the solar system. Temporal parts, then, (...) are parts that are temporally smaller. My current temporal part, "me-today", we might call it, is temporally smaller than me, since it exists today and only today. Temporal parts theory says that objects are made up of temporal as well as spatial parts. (shrink)

This paper explores the mereology of structural universals, using the structural richness of a non-classical mereology without unique fusions. The paper focuses on a problem posed by David Lewis, who using the example of methane, and assuming classical mereology, argues against any purely mereological theory of structural universals. The problem is that being a methane molecule would have to contain being a hydrogen atom four times over, but mereology does not have the concept of the same part occurring (...) several times. This paper takes up the challenge by providing mereological analysis of three operations sufficient for a theory of structural universals: Reflexive binding, i.e. identifying two of the places of a universal; Existential binding, i.e. the language-independent correlate of an existential quantification; and Conjunction. (shrink)

According to ontological reductionism, molecular chemistry refers, at last, to the quantum ontology; therefore, the ontological commitments of chemistry turn out to be finally grounded on quantum mechanics. The main problem of this position is that nobody really knows what quantum ontology is. The purpose of this work is to argue that the confidence in the existence of the physical entities described by quantum mechanics does not take into account the interpretative problems of the theory: in the discussions about the (...) relationship between chemistry and physics, difficulties are seen only on the side of chemistry, whereas matters highly controversial on the side of physics are taken for granted. For instance, it is usually supposed that the infinite mass limit in the Born-Oppenheimer approximation leads by itself to the concept of molecular framework used in molecular chemistry. We will argue that this assumption is implicitly based on an interpretative postulate for quantum mechanics, which, in turn, runs into difficulties when applied to the explanation of the simplest model of the hydrogen atom. (shrink)

Since its inception in the late 1920s and 30s, the main problem of quantum electrodynamics had been that any interaction or scattering event involved processes of a higher order that arose from vacuum polarization, the creation and subsequent annihilation of particle-antiparticle pairs, and the mutual interactions of all those short-lived entities.1 These processes posed two kinds of conceptual problems. First, they were not detectable individually, but had a measurable effect on the energy of the overall process. Even in simple quantum (...) systems, such as the hydrogen atom, they showed up, for instance, in the form of a further splitting up of spectral lines, most prominently the Lamb shift and measurements of... (shrink)

We numerically solve the functional differential equations (FDEs) of 2-particle electrodynamics, using the full electrodynamic force obtained from the retarded Lienard–Wiechert potentials and the Lorentz force law. In contrast, the usual formulation uses only the Coulomb force (scalar potential), reducing the electrodynamic 2-body problem to a system of ordinary differential equations (ODEs). The ODE formulation is mathematically suspect since FDEs and ODEs are known to be incompatible; however, the Coulomb approximation to the full electrodynamic force has been believed to be (...) adequate for physics. We can now test this long-standing belief by comparing the FDE solution with the ODE solution, in the historically interesting case of the classical hydrogen atom. The solutions differ. A key qualitative difference is that the full force involves a ‘delay’ torque. Our existing code is inadequate to calculate the detailed interaction of the delay torque with radiative damping. However, a symbolic calculation provides conditions under which the delay torque approximately balances (3rd order) radiative damping. Thus, further investigations are required, and it was prematurely concluded that radiative damping makes the classical hydrogen atom unstable. Solutions of FDEs naturally exhibit an infinite spectrum of discrete frequencies. The conclusion is that (a) the Coulomb force is not a valid approximation to the full electrodynamic force, so that (b) the n-body interaction needs to be reformulated in various current contexts such as molecular dynamics. (shrink)

I present a novel objection to fine-tuning arguments for God's existence. On any values of the physical constants, the psychophysical laws could be set to permit intelligent and happy beings, so the specific values of the physical constants in our world provide little evidence for God's existence. For example, even if the physical constants didn't allow carbon or any atoms larger than hydrogen, the psychophysical laws could be set so that charge is sufficient to realize romantic desire. Then every (...) hydrogen atom would be a proton and electron in love. (shrink)

Quantum Mechanics, and apparently its successors, claim that there are minimum quantities by which objects can differ, at least in some situations: electrons can have various “energy levels” in an atom, but to move from one to another they must jump rather than move via continuous variation: and an electron in a hydrogen atom going from -13.6 eV of energy to -3.4 eV does not pass through states of -10eV or -5.1eV, let along -11.1111115637 eV or -4.89712384 (...) eV. (shrink)

Jaegwon Kim contends that global supervenience is consistent with non-materialistic cases. Paull and Sider, Horgan, as well as Kim, attempt to defend it from these charges. It is shown here that their defense is only partially successful. Their defense meets one challenge to global supervenience---the hydrogen-atom case---but fails to meet other, ‘local’, cases. It is suggested that the other challenges can be met if global supervenience is combined with weak supervenience. The combination of global and weak supervenience constitutes (...) a viable picture of psychophysical relations, and is especially attractive to nonreductive materialists who are also anti-individualists. (shrink)

Application of Einstein special theory of relativity in chemistry seems to be superfluous; energies are too low. The average velocity of electron in hydrogen atom is 1/135 c, making its actual mass only 26,6 ppm bigger than the rest mass. However, for heavier elements relativistic effects have to be taken into account and, more, many phenomena cannot be explained without ascribing new mass to electrons, in accordance with Einstein theory. In this paper such phenomena are described: color of (...) metallic gold and Bi and Pb compounds, contraction of Ln-X bond of lanthanide trihalides, voltage of lead-acid and Zn/HgO battery, and the shape of gold clusters. Besides, essentials of Einstein theory and quantum chemistry were problems concerning the validity of Lavoisier law. (shrink)

We describe the picture of physical processes suggested by Edward Nelson’s stochastic mechanics when generalized to quantum field theory regularized on a lattice, after an introductory review of his theory applied to the hydrogen atom. By performing numerical simulations of the relevant stochastic processes, we observe that Nelson’s theory provides a means of generating typical field configurations for any given quantum state. In particular, an intuitive picture is given of the field “beable”—to use a phrase of John Stewart (...) Bell—corresponding to the Fock vacuum, and an explanation is suggested for how particle-like features can be exhibited by excited states. We then argue that the picture looks qualitatively similar when generalized to interacting scalar field theory. Lastly, we compare the Nelsonian framework to various other proposed ontologies for QFT, and remark upon their relative merits in light of the effective field theory paradigm. Links to animations of the corresponding beables are provided throughout. (shrink)

Why is space 3-dimensional? The fi rst answer to this question, entirely based on Physics, was given by Ehrenfest, in 1917, who showed that the stability requirement for n-dimensional two-body planetary system very strongly constrains space dimensionality, favouring 3-d. This kind of approach will be generically called "stability postulate" throughout this paper and was shown by Tangherlini, in 1963, to be still valid in the framework of general relativity as well as for quantum mechanical hydrogen atom, giving the (...) same constraint for space{dimensionality. In the present work, before criticizing this methodology, a brief discussion has been introduced, aimed at stressing and clarifying some general physical aspects of the problem of how to determine the number of space dimensions. Then, the epistemological consequences of Ehrenfest's methodology are critically reviewed. An alternative procedure to get at the proper number of dimensions, in which the stability postulate - and the implicit singularities in three-dimensional physics - are not an essential part of the argument, is proposed. In this way, the main epistemological problems contained in Ehrenfest's original idea are avoided. The alternative methodology proposed in this paper is realized by obtaining and discussing the n-dimensional quantum theory as expressed in Planck's law, de Broglie relation and the Heisenberg uncertainty relation. As a consequence, it is possible to propose an experiment, based on thermal neutron di raction by crystals, to directly measure space dimensionality. Finally the distinguished role of Maxwell's electromagnetic theory in the determination of space dimensionality is stressed. (shrink)

A principle of continuity due to Leibniz has recently been revived by Graham Priest in arguing for an inconsistent account of motion. This paper argues that the Leibniz Continuity Condition has a reasonable interpretation in a different, though still inconsistent, class of dynamical systems. The account is then applied to the quantum mechanical description of the hydrogen atom.

Starting from the formal expressions of the hydrodynamical (or “local”) quantities employed in the applications of Clifford algebras to quantum mechanics, we introduce—in terms of the ordinary tensorial language—a new definition for the field of a generic quantity. By translating from Clifford into tensor algebra, we also propose a new (nonrelativistic) velocity operator for a spin- ${\frac{1}{2}}$ particle. This operator appears as the sum of the ordinary part p/m describing the mean motion (the motion of the center-of-mass), and of a (...) second part associated with the so-called Zitterbewegung, which is the spin “internal” motion observed in the center-of-mass frame (CMF). This spin component of the velocity operator is nonzero not only in the Pauli theoretical framework, i.e., in the presence of external electromagnetic fields with a nonconstant spin function, but also in the Schrödinger case, when the wavefunction is a spin eigenstate. Thus, one gets even in the latter case a decomposition of the velocity field for the Madelung fluid into two distinct parts, which constitutes the nonrelativistic analogue of the Gordon decomposition for the Dirac current. Explicit calculations are presented for the velocity field in the particular cases of the hydrogen atom, of a spherical well potential, and of an electron in a uniform magnetic field. We find, furthermore, that the Zitterbewegung motion involves a velocity field which is solenoidal, and that the local angular velocity is parallel to the spin vector. In the presence of a nonuniform spin vector (Pauli case) we have, besides the component of the local velocity normal to the spin (present even in the Schrödinger theory), also a component which is parallel to the curl of the spin vector. (shrink)

The exact agreement between the Sommerfeld and Dirac results for the energy levels of the relativistic hydrogen atom (the “Sommerfeld Puzzle”) is analyzed and explained.

This paper discusses some of the technical problems related to a Weylian geometrical interpretation of the Schrödinger and Klein-Gordon equations proposed by E. Santamato. Solutions to these technical problems are proposed. A general prescription for finding out the interdependence between a particle's effective mass and Weyl's scalar curvature is presented which leads to the fundamental equation of geometric quantum mechanics, $$m(R)\frac{{dm(R)}}{{dR}} = \frac{{\hbar ^2 }}{{c^2 }}$$ The Dirac equation is rigorously derived within this formulation, and further problems to be solved (...) are proposed in the conclusion. The main one is based on obtaining the relationship between Feynman's path integral quantization method, among others, and the methods of geometric quantum mechanics. The solution of this problem will be a crucial test for this theory that attempts to “geometrize” quantum mechanics rather than the conventional approach in the past of quantizing geometry. A numerical prediction of this theory yields a 3×10−35 eV correction to the ground-state energy of the hydrogen atom. (shrink)

One of the most influential physicists of the twentieth century, Niels Bohr was born in Copenhagen on 7 October 1885, and died there on 18 November 1962. He came of a well‐to‐do, cultivated family, his father being Professor of Physiology at Copenhagen University, where Bohr himself received his education in physics. After taking his doctorate in 1911, Bohr went to Cambridge University to continue his research on the theory of electrons under Sir J. J. Thomson. After several months in Cambridge, (...) he moved to Manchester to work under Ernest Rutherford, the world leader in the newly emerging field of atomic physics. It was in Rutherford's department that Bohr proposed his revolutionary quantum theory of the structure of the hydrogen atom in 1913. (shrink)

The state of science at any given time is characterized, in part at least, by the theories that are accepted at that time. Presently accepted theories include quantum theory, the general theory of relativity, and the modern synthesis of Darwin and Mendel, as well as lower‐level (but still clearly theoretical) assertions such as that DNA has a double‐helical structure, that the hydrogen atom contains a single electron, and so on. What precisely is involved in accepting a theory?

The state of science at any given time is characterized, in part at least, by the theories that are accepted at that time. Presently accepted theories include quantum theory, the general theory of relativity, and the modern synthesis of Darwin and Mendel, as well as lower‐level (but still clearly theoretical) assertions such as that DNA has a double‐helical structure, that the hydrogen atom contains a single electron, and so on. What precisely is involved in accepting a theory?

In the traditional frame of classical electrodynamics, a hydrogen atom would emit electromagnetic waves and thus constantly lose energy, resulting in the fall of the electron on the proton over a finite period of time. The corresponding results were derived under the assumption of the instantaneous interaction between the proton and the electron. In 2004, Raju published a paper where he removed the assumption of the instantaneous interaction and studied the role of a time delay in the classical (...) hydrogen atom. He introduced a model of this effect that can be solved analytically. He calculated the radius rsel of a selected orbit, for which this effect and the radiation reaction force would cancel each other with respect to the tangential acceleration. It turned out that rsel is by an order of magnitude smaller than the Bohr radius. In the present paper we use Raju’s model for the corresponding gravitational situation. In frames of Newton’s gravity, we calculate analytically the radius and the energy Esel of a selected orbit, for which the retardation effect and the radiation reaction force would cancel each other out with respect to the tangential acceleration. Then we compare our outcome with some results of Kaplan’s solution for the two-body gravitational problem based on the Schwarzschild’s field. We show that Esel is very close to the minimum energy of bound states obtained by Kaplan in Einstein’s gravity. We emphasize that the selected orbit from the present paper represents the second only physical situation where the radiation reaction force is zero, but the radiation-caused energy loss is not zero. (shrink)

It will be argued that Minkowski's implementation of distances is inconsistent. An alternative implementation will be proposed. In the new model the proper time of an object is taken as its fourth coordinate. Distances will be measured according to a four dimensional Euclidean metric. In the present approach mass is a constant of motion. A mass can therefore be ascribed to photons and neutrinos. Mechanics and dynamics will be reformulated in close correspondence with classical physics. Of particular interest is the (...) equation of motion for the proper time momentum. In the classical limit it reduces to the classical law of conservation of (kinetic+potential) energy. In the relativistic limit it is similar to the conservation of energy of the theory of relativity. The conservation of proper time momentum allows for an alternative explanation for Compton scattering and pair annihilation. On the basis of the proper time formulation of electrodynamics also an alternative explanation will be offered for the spectra of hydrogenic atoms. The proper time formulation of gravitational dynamics leads to the correct predictions of gravitational time dilation, the deflection of light and the precession of the perihelia of planets. For this no curvature will be needed. That is, spacetime is flat everywhere, even in the presence of sources of gravitation. Some cosmological consequences will be discussed. The present approach gives a new notion to energy, antiparticles and the structure of spacetime. The contents of the present paper will have important implications for the foundations of physics in general. (shrink)

In the de Broglie–Bohm formulation of quantum mechanics, the electron is stationary in the ground state of hydrogenic atoms, because the quantum force exactly cancels the Coulomb attraction of the electron to the nucleus. In this paper it is shown that classical electrodynamics similarly predicts the Coulomb force can be effectively canceled by part of the magnetic force that occurs between two similar particles each consisting of a point charge moving with circulatory motion at the speed of light. Supposition of (...) such motion is the basis of the Zitterbewegung interpretation of quantum mechanics. The magnetic force between two luminally-circulating charges for separation large compared to their circulatory motions contains a radial inverse square law part with magnitude equal to the Coulomb force, sinusoidally modulated by the phase difference between the circulatory motions. When the particles have equal mass and their circulatory motions are aligned but out of phase, part of the magnetic force is equal but opposite the Coulomb force. This raises a possibility that the quantum force of Bohmian mechanics may be attributable to the magnetic force of classical electrodynamics. It is further shown that relative motion between the particles leads to modulation of the magnetic force with spatial period equal to the de Broglie wavelength. (shrink)

The Bohr formulation—the original one—is now largely a matter of history. The usual career of a theory was its fate. It explained much, but it failed at the first signs of complication, even for the simplest molecules as hydrogen and helium. Some results were either only approximate in a loose or incomplete fashion, e.g. in the application of the correspondence principle to intensities, the only reliable predictions being only for an absence of certain lines, or they quite disagreed with (...) experiment, e.g. in the case of the hydrogen molecule and the hydrogen molecule ion, the normal and excited states of helium, the anomalous Zeeman effect, the Ramsauer effect, and in the treatment of problems where more than one electron was involved. In the last mentioned cases the perturbation method, so successful in solving “many-body” problems in celestial mechanics, failed completely because systems of several electrons, possessing frequencies of the order of light waves, cannot interact classically. A bit of much forced pragmatism was practiced in treating the many electron atom as a variation of the hydrogen atom. Besides, there were technical oddities, like ½ quantum numbers, and impenetrated anologies between visible and X-ray spectra. (shrink)