Abstract

I describe two candidate representations of a mixture. The first, which I call the ‘standard representation’, is not a good representation of a mixture in spite of its widespread popularity. The second, which I call ‘Gibbs’ representation’, is less widely adopted but is, I argue, a much better representation. I show that, once we have a precise mathematical structure that can be used to represent thermodynamic systems, and once an adequate perspective on representation is adopted, Gibbs’ representation trumps the standard representation.