The topic of the paper is the "realism-Instrumentalism" debate concerning the status of scientific theories. Popper's contributions to this debate are critically examined. In the first part his arguments against instrumentalism are considered; it is claimed that none strikes home against better versions of the doctrine (specifically those developed by duhem and poincare). In the second part, Various arguments against realism propounded by duhem and/or poincare (and much discussed by more recent philosophers) are evaluated. These are the arguments from the (...) use of idealisations in science, From the "underdetermination" of scientific theories, And (especially) from the existence of radical scientific revolutions. A maximally strong version of realism-After due allowance has been made to these arguments-Is stated and defended. This position is close to popper's own "conjectural realism" but involves dropping entirely the idea that science has developed "via" theories possessing increasing verisimilitude. (shrink)

The "Duhem-Quine thesis" says that isolated hypotheses are not singularly verifiable by experience, only the whole body of a theory being able to be subjected to the test of experience. I first examine the rather divergent meanings this thesis takes when it is replaced in the different contexts of Duhem's and Quine'sphilosophies. Secondly, questions are asked about the acceptability of the thesis, its logical strength and its historical soundness. Finally, the consequences of some doubts raised by this inquiry are examined (...) especially with respect to Quine's philosophy. (shrink)

An exposition of Pierre Duhem’s formulation of the structure of chemical substances as expressed by their formulas is given, presenting it as a development of his essentially Aristotelian view of mixtures. Duhem’s masterly development of the subject displays an eye for logical clarity familiar from his work in thermodynamics but applied here to the extraction of what he regarded as true from the history of chemistry. Though no longer defensible, the account has a conceptual interest in its own right and (...) illuminates a less frequently discussed side of Duhem’s views. (shrink)

Aristotelian ideas are presented in a favorable light in Duhem's historical works surveying the history of the notion of chemical combination (1902) and the development of mechanics (1903). The importance Duhem was later to ascribe to Aristotelian ideas as reflected in the weight he attached to medieval science is well known. But the Aristotelian influence on his own mature philosophical perspective, and more particularly on his concern for logical coherence and the development of his ontological views, is not generally acknowledged. (...) There are, however, clear pointers in this direction in these two earlier books on the history of science, which are unashamedly written in such a way as to project the author's own view of what is important in the relevant areas. Thermodynamics was the pinnacle of Duhemian science, and its interpretation requires the reinstatement, in Duhem's view, of Aristotelian conceptions which have been unfashionable since the rise of certain ideas with the scientific revolution of the seventeenth century. The present paper is not primarily an exposition of these Aristotelian views of Duhem's, but an attempt to pursue the interpretation of a macroscopic, thermodynamical perspective on chemical substances from an elementary viewpoint in the spirit of Duhem (1902), sometimes being more definite than Duhem seems to be, and occasionally taking issue with him on certain points. Some of his leading ideas will determine the general approach, but views and problems will also be taken from modern textbooks in an attempt to lay down the general lines along which an explicit ontology--in Quine's sense--of macroscopic theory might be developed. (shrink)

Summary Robert Boyle did not subordinate chemistry to mechanical philosophy. He was in fact reluctant to explain chemical phenomena by having recourse to the mechanical properties of particles. For him chemistry provided a primary way of penetrating into nature. In his chemical works he employed corpuscles endowed with chemical properties as his explanans. Boyle's chemistry was corpuscular, rather than mechanical. As Boyle's views of seminal principles show, his corpuscular philosophy cannot be described as a purely mechanical theory of matter. Boyle's (...) classification of corpuscles allowed him to connect his corpuscular views of matter with chemistry. Boyle did not rule out the possibility of a classification of chemical substances based on their properties: his aim was to reform the received classification. (shrink)

Jean Perrin’s argument for the existence of molecules from his 1908 experimental determination of Avogadro’s number raises two questions considered in this article. One is historical: Why as late as 1908 should Perrin have thought it necessary to argue that molecules exist? The other, which takes up the bulk of this article, is philosophical: In view of the fact that his argument appears to assume the existence of molecules as a premise, how, if at all, can a charge of circularity (...) be avoided? I criticize attempted reconstructions of his argument by Salmon, Glymour, and hypothetico-deductivists. And I propose a probabilistic solution that avoids circularity. Finally, I consider whether Perrin’s reasoning, so construed, is an empirical argument for scientific realism. (shrink)