A popular view in contemporary Boltzmannian statistical mechanics is to interpret the measures as typicality measures. In measure-theoretic dynamical systems theory measures can similarly be interpreted as typicality measures. However, a justification why these measures are a good choice of typicality measures is missing, and the paper attempts to fill this gap. The paper first argues that Pitowsky's (2012) justification of typicality measures does not fit the bill. Then a first proposal of how to justify typicality measures is presented. The (...) main premises are that typicality measures are invariant and are related to the initial probability distribution of interest (which are translation-continuous or translation-close). The conclusions are two theorems which show that the standard measures of statistical mechanics and dynamical systems are typicality measures. There may be other typicality measures, but they agree about judgements of typicality. Finally, it is proven that if systems are ergodic or epsilon-ergodic, there are uniqueness results about typicality measures. (shrink)

Why does classical equilibrium statistical mechanics work? Malament and Zabell (1980) noticed that, for ergodic dynamical systems, the unique absolutely continuous invariant probability measure is the microcanonical. Earman and Rédei (1996) replied that systems of interest are very probably not ergodic, so that absolutely continuous invariant probability measures very distant from the microcanonical exist. In response I define the generalized properties of epsilon-ergodicity and epsilon-continuity, I review computational evidence indicating that systems of interest are epsilon-ergodic, I adapt Malament and Zabell’s (...) defense of absolute continuity to support epsilon-continuity, and I prove that, for epsilon-ergodic systems, every epsilon-continuous invariant probability measure is very close to the microcanonical. (shrink)

Emphasis in historiography of science is naturally placed on the discoveries and inventions which scientists make and generally less on new methods of doing science, but sometimes the latter can he an important clue to help us understand the former. For example, while we all acknowledge how great the contributions of Maxwell, Boltzmann, Planck, and Einstein were to physics from roughly 1870 to 1920, we often overlook the significance of a methodological phrase which was popular during that same period, namely, (...) what in German was called “Bildtheorie” or in English “picture theory”. But even before we can properly study its significance we have to know what the theory was, but even this presents problems, since the meaning changed. In fact, this paper is an attempt not only to describe the history of that change from Maxwell to Wittgenstein but to study in particular how Boltzmann’s conception of Bildtheorie seems to have been at least partly incorporated into the approach of Ludwig Wittgenstein. (shrink)

The traditional use of ergodic theory in the foundations of equilibrium statistical mechanics is that it provides a link between thermodynamic observables and microcanonical probabilities. First of all, the ergodic theorem demonstrates the equality of microcanonical phase averages and infinite time averages (albeit for a special class of systems, and up to a measure zero set of exceptions). Secondly, one argues that actual measurements of thermodynamic quantities yield time averaged quantities, since measurements take a long time. The combination of these (...) two points is held to be an explanation why calculating microcanonical phase averages is a successful algorithm for predicting the values of thermodynamic observables. It is also well-known that this account is problematic.

This survey intends to show that ergodic theory nevertheless may have important roles to play, and it explores three other uses of ergodic theory. Particular attention is paid, firstly, to the relevance of specific interpretations of probability, and secondly, to the way in which the concern with systems in thermal equilibrium is translated into probabilistic language. With respect to the latter point, it is argued that equilibrium should not be represented as a stationary probability distribution as is standardly done; instead, a weaker definition is presented. (shrink)

This paper develops a philosophical investigation of the merits and faults of a theorem by Lanford , Lanford , Lanford for the problem of the approach towards equilibrium in statistical mechanics. Lanford’s result shows that, under precise initial conditions, the Boltzmann equation can be rigorously derived from the Hamiltonian equations of motion for a hard spheres gas in the Boltzmann-Grad limit, thereby proving the existence of a unique solution of the Boltzmann equation, at least for a very short amount of (...) time. We argue that, by establishing a statistical H-theorem, it offers a prospect to complete Boltzmann’s combinatorial argument, without running against the objections which plug other typicality-based approaches. However, we submit that, while recovering the irreversible approach towards equilibrium for positive times, it fails to predict a monotonic increase of entropy for negative times, and hence it yields the wrong retrodictions about the past evolution of a gas. (shrink)

It has been a longstanding problem to show how the irreversible behaviour of macroscopic systems can be reconciled with the time-reversal invariance of these same systems when considered from a microscopic point of view. A result by Lanford shows that, under certain conditions, the famous Boltzmann equation, describing the irreversible behaviour of a dilute gas, can be obtained from the time-reversal invariant Hamiltonian equations of motion for the hard spheres model. Here, we examine how and in what sense Lanford’s theorem (...) succeeds in deriving this remarkable result. Many authors have expressed different views on the question which of the ingredients in Lanford’s theorem is responsible for the emergence of irreversibility. We claim that these interpretations miss the target. In fact, we argue that there is no time-asymmetric ingredient at all. (shrink)

The aim of this article is to analyse the relation between the second law of thermodynamics and the so-called arrow of time. For this purpose, a number of different aspects in this arrow of time are distinguished, in particular those of time-reversal (non-)invariance and of (ir)reversibility. Next I review versions of the second law in the work of Carnot, Clausius, Kelvin, Planck, Gibbs, Caratheodory and Lieb and Yngvason, and investigate their connection with these aspects of the arrow of time. It (...) is shown that this connection varies a great deal along with these formulations of the second law. According to the famous formulation by Planck, the second law expresses the irreversibility of natural processes. But in many other formulations irreversibility or even time-reversal non-invariance plays no role. I therefore argue for the view that the second law has nothing to do with the arrow of time. (shrink)

In this paper I first argue that the objection which is most commonly levelled against the coarse-graining approach-viz. that it introduces an element of subjectivity into what ought to be a purely objective formalism-is ultimately unfounded. I then proceed to argue that two different objections to the coarse-graining approach indicate that it is an inadequate approach to statistical mechanics. The first objection is based on the fact that the appeal to appearances by the coarse-graining approach fails to justify the coarse-graining (...) strategy of ignoring the physical differences between so-called quasi-equilibrium distributions and equilibrium distributions. The second objection is centred on the notion of a coarse-grained entropy. I will argue that the required increase in the coarse-grained entropy is obtained by disregarding the dynamical constraints on the system. This undermines the very task statistical mechanics has set out to accomplish, viz. to provide a microdynamical underpinning of thermodynamics. (shrink)

We propose an "explanation scheme" for why the Gibbs phase average technique in classical equilibrium statistical mechanics works. Our account emphasizes the importance of the Khinchin-Lanford dispersion theorems. We suggest that ergodicity does play a role, but not the one usually assigned to it.

We discuss Boltzmann’s probabilistic explanation of the second law of thermodynamics providing a comprehensive presentation of what is called today the typicality account. Countering its misconception as an alternative explanation, we examine the relation between Boltzmann’s H-theorem and the general typicality argument demonstrating the conceptual continuity between the two. We then discuss the philosophical dimensions of the concept of typicality and its relevance for scientific reasoning in general, in particular for understanding the reduction of macroscopic laws to microscopic laws. Finally, (...) we reply to various common criticisms of the typicality account. (shrink)

The Boltzmann and Gibbs approaches to statistical mechanics have very different definitions of equilibrium and entropy. The problems associated with this are discussed and it is suggested that they can be resolved, to produce a version of statistical mechanics incorporating both approaches, by redefining equilibrium not as a binary property but as a continuous property measured by the Boltzmann entropy and by introducing the idea of thermodynamic-like behaviour for the Boltzmann entropy. The Kac ring model is used as an example (...) to test the proposals. (shrink)

This paper presents a new foundation of equilibrium thermodynamics based on certain ideas of T. Ehrenfest. The main result is the proof for the existence of entropy as a consequence of the conservation of energy for conservative thermal systems.

A new axiomatic treatment of equilibrium thermodynamics—thermostatics—is presented. The equilibrium states of a thermal system are assumed to be represented by a differentiable manifold of dimensionn + 1 (n finite). The empirical temperature is defined by the notion of thermal equilibrium. Empirical entropy is shown to exist for all systems with the property that the total work delivered along closed adiabats is zero. Absolute entropy and temperature follow from the additivity of heat and energy for two separate systems in thermal (...) equilibrium considered as a whole. The absolute temperature is defined up to a multiplicative constant. The exterior differentiable calculus of Cartan is introduced and in a subsequent paper its use for the derivation of standard results in thermostatics will be explained. (shrink)

An important contemporary version of Boltzmannian statistical mechanics explains the approach to equilibrium in terms of typicality. The problem with this approach is that it comes in different versions, which are, however, not recognized as such and not clearly distinguished. This article identifies three different versions of typicality‐based explanations of thermodynamic‐like behavior and evaluates their respective successes. The conclusion is that the first two are unsuccessful because they fail to take the system's dynamics into account. The third, however, is promising. (...) I give a precise formulation of the proposal and present an argument in support of its central contention. †To contact the author, please write to: Department of Philosophy, Logic, and Scientific Method, London School of Economics, Houghton Street, London WC2A 2AE, England; e‐mail: [email protected]. (shrink)

Consider a gas that is adiabatically isolated from its environment and confined to the left half of a container. Then remove the wall separating the two parts. The gas will immediately start spreading and soon be evenly distributed over the entire available space. The gas has approached equilibrium. Thermodynamics (TD) characterizes this process in terms of an increase of thermodynamic entropy, which attains its maximum value at equilibrium. The second law of thermodynamics captures the irreversibility of this process by positing (...) that in an isolated system such as the gas entropy cannot decrease. The aim of statistical mechanics (SM) is to explain the behavior of the gas and, in particular, its conformity with the second law in terms of the dynamical laws governing the individual molecules of which the gas is made up. In what follows these laws are assumed to be the ones of Hamiltonian classical mechanics. We should not, however, ask for an explanation of the second law literally construed. This law is a universal law and as such cannot be explained by a statistical theory. But this is not a problem because we.. (shrink)

Gases reach equilibrium when left to themselves. Why do they behave in this way? The canonical answer to this question, originally proffered by Boltzmann, is that the systems have to be ergodic. This answer has been criticised on different grounds and is now widely regarded as flawed. In this paper we argue that some of the main arguments against Boltzmann's answer, in particular, arguments based on the KAM-theorem and the Markus-Meyer theorem, are beside the point. We then argue that something (...) close to Boltzmann's original proposal is true for gases: gases behave thermodynamic-like if they are epsilon-ergodic, i.e., ergodic on the entire accessible phase space except for a small region of measure epsilon. This answer is promising because there are good reasons to believe that relevant systems in statistical mechanics are epsilon-ergodic. (shrink)

A gas prepared in a non-equilibrium state will approach equilibrium and stay there. An influential contemporary approach to Statistical Mechanics explains this behaviour in terms of typicality. However, this explanation has been criticised as mysterious as long as no connection with the dynamics of the system is established. We take this criticism as our point of departure. Our central claim is that Hamiltonians of gases which are epsilon-ergodic are typical with respect to the Whitney topology. Because equilibrium states are typical, (...) we argue that there follows the desired conclusion that typical initial conditions approach equilibrium and stay there. (shrink)

We argue that, contrary to some analyses in the philosophy of science literature, ergodic theory falls short in explaining the success of classical equilibrium statistical mechanics. Our claim is based on the observations that dynamical systems for which statistical mechanics works are most likely not ergodic, and that ergodicity is both too strong and too weak a condition for the required explanation: one needs only ergodic-like behaviour for the finite set of observables that matter, but the behaviour must ensure that (...) the approach to equilibrium for these observables is on the appropriate time-scale. (shrink)

This article examines the role of philosophy in the development of the kinetic theory of gases. Two opposing accounts of this role, by Peter Clark and John Nyhof, are discussed and criticized. Contrary to both accounts, it is argued that philosophical views of scientists can fundamentally influence the results of their scientific work. This claim is supported by a detailed analysis of the philosophical views of Maxwell and Boltzmann, and of their work on the kinetic theory, especially concerning the so-called (...) specific heat anomaly. It leads to the conclusion that the scientific development of the kinetic theory cannot be understood without taking into account the role of philosophy. (shrink)

This paper discusses the mistake of understanding the laws and concepts of thermodynamics too literally in the foundations of statistical mechanics. Arguing that this error is still made in subtle ways, the article explores its occurrence in three examples: the Second Law, the concept of equilibrium and the definition of phase transitions.

The Past Hypothesis is the claim that the Boltzmann entropy of the universe was extremely low when the universe began. Can we make sense of this claim when *classical* gravitation is included in the system? I first show that the standard rationale for not worrying about gravity is too quick. If the paper does nothing else, my hope is that it gets the problems induced by gravity the attention they deserve in the foundations of physics. I then try to make (...) plausible a very weak claim: that there is a well-defined Boltzmann entropy that *can* increase in *some* interesting self-gravitating systems. More work is needed before we can say whether this claim answers the threat to the standard explanation of entropy increase. (shrink)

This article argues that most of the approaches to the foundations of statistical mechanics have severed their link with the original foundational project, the project of demonstrating how real mechanical systems can behave thermodynamically.

This paper investigates what the source of time-asymmetry is in thermodynamics, and comments on the question whether a time-symmetric formulation of the Second Law is possible.

This paper is an attempt to clarify why Ludwig Boltzmann from about 1895 to 1905 seemed to adopt a series of extreme epistemological positions, ranging from phenomenalism to pragmatism, while emphatically rejecting what he called ‘metaphysics’ (by which he meant all traditional philosophy). He concluded that all philosophical differences were merely linguistic and most were ultimately meaningless. But at about the time that young Ludwig Wittgenstein began absorbing these desperate ideas (1905), Boltzmann himself under the influence of Franz Brentano seemed (...) to assume a type of representationalism about the external physical world, while in his own mind adopting it for pragmatic reasons. Why? Because “it worked”. He seems to have defended his non-representationalist Bildtheorie on similar grounds, but his suicide followed shortly (1906). (shrink)

Various processes are often classified as both deterministic and random or chaotic. The main difficulty in analysing the randomness of such processes is the apparent tension between the notions of randomness and determinism: what type of randomness could exist in a deterministic process? Ergodic theory seems to offer a particularly promising theoretical tool for tackling this problem by positing a hierarchy, the so-called ‘ergodic hierarchy’, which is commonly assumed to provide a hierarchy of increasing degrees of randomness. However, that notion (...) of randomness requires clarification. The mathematical definition of EH does not make explicit appeal to randomness; nor does the usual way of presenting EH involve a specification of the notion of randomness that is supposed to underlie the hierarchy. In this paper we argue that EH is best understood as a hierarchy of random behaviour if randomness is explicated in terms of unpredictability. We then show that, contrary to common wisdom, EH is useful in characterising the behaviour of Hamiltonian dynamical systems. (shrink)

This book is an attempt to get to the bottom of an acute and perennial tension between our best scientific pictures of the fundamental physical structure of the ...

This book presents the life and personality, the scientific and philosophical work of Ludwig Boltzmann, one of the great scientists who marked the passage from 19th- to 20th-Century physics. His rich and tragic life, ending by suicide at the age of 62, is described in detail. A substantial part of the book is devoted to discussing his scientific and philosophical ideas and placing them in the context of the second half of the 19th century. The fact that Boltzmann was the (...) man who did most to establish that there is a microscopic, atomic structure underlying macroscopic bodies is documented, as is Boltzmann's influence on modern physics, especially through the work of Planck on light quanta and of Einstein on Brownian motion. Boltzmann was the centre of a scientific upheaval, and he has been proved right on many crucial issues. He anticipated Kuhn's theory of scientific revolutions and proposed a theory of knowledge based on Darwin. His basic results, when properly understood, can also be stated as mathematical theorems. Some of these have been proved: others are still at the level of likely but unproven conjectures. The main text of this biography is written almost entirely without equations. Mathematical appendices deepen knowledge of some technical aspects of the subject. (shrink)

The book presents the life and personality, the scientific and philosophical work of Ludwig Boltzmann, one of the great scientists who marked the passage from 19th to 20th century physics. His rich and tragic life, ending by suicide at the age of 62, is described in detail. A substantial part of the book is devoted to discussing his scientific and philosophical ideas and placing them in the context of the second half of the 19th century. The fact that Boltzmann was (...) the man who did most to establish that there is a microscopic, atomic structure underlying macroscopic bodies is documented, as is Boltzmann's influence on modern physics, especially through the work of Planck on light quanta and of Einstein on Brownian motion. Boltzmann was the centre of a scientific revolution, and he has been proved right on many crucial issues. He anticipated Kuhn's theory of scientific revolutions and proposed a theory of knowledge based on Darwin. His basic results, when properly understood, can also be stated as mathematical theorems. Some of these have been proved; others are still at the level of likely but unproven conjectures. The main text of this biography is written almost entirely without equations. Mathematical appendices deepen knowledge of some technical aspects of the subject. (shrink)

Statistical mechanics is one of the crucial fundamental theories of physics, and in his new book Lawrence Sklar, one of the pre-eminent philosophers of physics, offers a comprehensive, non-technical introduction to that theory and to attempts to understand its foundational elements. Among the topics treated in detail are: probability and statistical explanation, the basic issues in both equilibrium and non-equilibrium statistical mechanics, the role of cosmology, the reduction of thermodynamics to statistical mechanics, and the alleged foundation of the very notion (...) of time asymmetry in the entropic asymmetry of systems in time. The book emphasises the interaction of scientific and philosophical modes of reasoning, and in this way will interest all philosophers of science as well as those in physics and chemistry concerned with philosophical questions. The book could also be read by an informed general reader interested in the foundations of modern science. (shrink)

Winner of the Wolf Prize for his contribution to our understanding of the universe, Penrose takes on the question of whether artificial intelligence will ever ...

The so-called ergodic hierarchy (EH) is a central part of ergodic theory. It is a hierarchy of properties that dynamical systems can possess. Its five levels are egrodicity, weak mixing, strong mixing, Kolomogorov, and Bernoulli. Although EH is a mathematical theory, its concepts have been widely used in the foundations of statistical physics, accounts of randomness, and discussions about the nature of chaos. We introduce EH and discuss how its applications in these fields.

Statistical mechanics is one of the crucial fundamental theories of physics, and in his new book Lawrence Sklar, one of the pre-eminent philosophers of physics, offers a comprehensive, non-technical introduction to that theory and to attempts to understand its foundational elements. Among the topics treated in detail are: probability and statistical explanation, the basic issues in both equilibrium and non-equilibrium statistical mechanics, the role of cosmology, the reduction of thermodynamics to statistical mechanics, and the alleged foundation of the very notion (...) of time asymmetry in the entropic asymmetry of systems in time. The book emphasises the interaction of scientific and philosophical modes of reasoning, and in this way will interest all philosophers of science as well as those in physics and chemistry concerned with philosophical questions. The book could also be read by an informed general reader interested in the foundations of modern science. (shrink)

In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann’s analysis, the essence of which I shall review here, is basically correct. The most famous criticisms of Boltzmann’s later work on the subject have little merit. Most twentieth century innovations – such as the identification of the state of a physical system with a probability distribution on its phase space, (...) of its thermodynamic entropy with the Gibbs entropy of , and the invocation of the notions of ergodicity and mixing for the justification of the foundations of statistical mechanics – are thoroughly misguided. (shrink)

I give a brief account of the way in which thermodynamics and statistical mechanics actually work as contemporary scientific theories, and in particular of what statistical mechanics contributes to thermodynamics over and above any supposed underpinning of the latter's general principles. In doing so, I attempt to illustrate that statistical mechanics should not be thought of wholly or even primarily as itself a foundational project for thermodynamics, and that conceiving of it this way potentially distorts the foundational study of statistical (...) mechanics itself. (shrink)

This is an extensive review of recent work on the foundations of statistical mechanics.

Consider a gas confined to the left half of a container. Then remove the wall separating the two parts. The gas will start spreading and soon be evenly distributed over the entire available space. The gas has approached equilibrium. Why does the gas behave in this way? The canonical answer to this question, originally proffered by Boltzmann, is that the system has to be ergodic for the approach to equilibrium to take place. This answer has been criticised on different grounds (...) and is now widely regarded as flawed. In this paper we argue that these criticisms have dismissed Boltzmann’s answer too quickly and that something almost like Boltzmann’s answer is true: the approach to equilibrium takes place if the system is epsilon-ergodic, i.e. ergodic on the entire accessible phase space except for a small region of measure epsilon. We introduce epsilon-ergodicity and argue that relevant systems in statistical mechanics are indeed espsilon-ergodic. (shrink)

Why do systems prepared in a non-equilibrium state approach, and eventually reach, equilibrium? An important contemporary version of the Boltzmannian approach to statistical mechanics answers this question by an appeal to the notion of typicality. The problem with this approach is that it comes in different versions, which are, however, not recognised as such, much less clearly distinguished, and we often find different arguments pursued side by side. The aim of this paper is to disentangle different versions of typicality-based explanations (...) of thermodynamic behaviour and evaluate their respective success. My conclusion will be that the boldest version fails for technical reasons, while more prudent versions leave unanswered essential questions. (shrink)