This paper examines the justifications for using infinite systems to 'recover' thermodynamic properties, such as phase transitions (PT), critical phenomena (CP), and irreversibility, from the micro-structure of matter in bulk. Section 2 is a summary of such rigorous methods as in taking the thermodynamic limit (TL) to recover PT and in using renormalization (semi-) group approach (RG) to explain the universality of critical exponents. Section 3 examines various possible justifications for taking TL on physically finite systems. Section 4 discusses the (...) legitimacy of applying TL to the problem of irreversibility and assesses the repercussions for its legitimacy on its home turf. (shrink)

Two alternative accounts of quantum spontaneous symmetry breaking (SSB) are compared and one of them, the decompositional account in the algebraic approach, is argued to be superior for understanding quantum SSB. Two exactly solvable models are given as applications of our account -- the Weiss-Heisenberg model for ferromagnetism and the BCS model for superconductivity. Finally, the decompositional account is shown to be more conducive to the causal explanation of quantum SSB.

The renormalization method is specifically aimed at connecting theories describing physical processes at different length scales and thereby connecting different theories in the physical sciences.The renormalization method used today is the outgrowth of 150 years of scientific study of thermal physics and phase transitions. Different phases of matter show qualitatively different behaviors separated by abrupt phase transitions. These qualitative differences seem to be present in experimentally observed condensed-matter systems. However, the “extended singularity theorem” in statistical mechanics shows that sharp changes (...) can only occur in infinitely large systems. Abrupt changes from one phase to another are signaled by fluctuations that show correlation over infinitely long distances, and are measured by correlation functions that show algebraic decay as well as various kinds of singularities and infinities in thermodynamic derivatives and in measured system parameters.Renormalization methods were first developed in field theory to get around difficulties caused by apparent divergences at both small and large scales. However, no renormalization gives a fully satisfactory formulation of field theory.The renormalization group theory of phase transitions was put together by Kenneth G. Wilson in 1971 based upon ideas of scaling and universality developed earlier in the context of phase transitions and of couplings dependent upon spatial scale coming from field theory. Correlations among regions with fluctuations in their order underlie renormalization ideas. Wilson's theory is the first approach to phase transitions to agree with the extended singularity theorem.Some of the history of the study of these correlations and singularities is recounted, along with the history of renormalization and related concepts of scaling and universality. Applications, particularly to condensed-matter physics and particle physics, are summarized.This note is partially a summary of a talk given at the workshop “Part and Whole” in Leiden during the period March 22–26, 2010. (shrink)

This paper discusses the mistake of understanding the laws and concepts of thermodynamics too literally in the foundations of statistical mechanics. Arguing that this error is still made in subtle ways, the article explores its occurrence in three examples: the Second Law, the concept of equilibrium and the definition of phase transitions.

This is a companion to another paper. Together they rebut two widespread philosophical doctrines about emergence. The first, and main, doctrine is that emergence is incompatible with reduction. The second is that emergence is supervenience; or more exactly, supervenience without reduction.In the other paper, I develop these rebuttals in general terms, emphasising the second rebuttal. Here I discuss the situation in physics, emphasising the first rebuttal. I focus on limiting relations between theories and illustrate my claims with four examples, each (...) of them a model or a framework for modelling, from well-established mathematics or physics.I take emergence as behaviour that is novel and robust relative to some comparison class. I take reduction as, essentially, deduction. The main idea of my first rebuttal will be to perform the deduction after taking a limit of some parameter. Thus my first main claim will be that in my four examples (and many others), we can deduce a novel and robust behaviour, by taking the limit N→∞ of a parameter N.But on the other hand, this does not show that the N=∞ limit is “physically real”, as some authors have alleged. For my second main claim is that in these same examples, there is a weaker, yet still vivid, novel and robust behaviour that occurs before we get to the limit, i.e. for finite N. And it is this weaker behaviour which is physically real.My examples are: the method of arbitrary functions (in probability theory); fractals (in geometry); superselection for infinite systems (in quantum theory); and phase transitions for infinite systems (in statistical mechanics). (shrink)

This is one of two papers about emergence, reduction and supervenience. It expounds these notions and analyses the general relations between them. The companion paper analyses the situation in physics, especially limiting relations between physical theories. I shall take emergence as behaviour that is novel and robust relative to some comparison class. I shall take reduction as deduction using appropriate auxiliary definitions. And I shall take supervenience as a weakening of reduction, viz. to allow infinitely long definitions. The overall claim (...) of this paper will be that emergence is logically independent both of reduction and of supervenience. In particular, one can have emergence with reduction, as well as without it; and emergence without supervenience, as well as with it. Of the subsidiary claims, the four main ones are: : I defend the traditional Nagelian conception of reduction ; : I deny that the multiple realizability argument causes trouble for reductions, or ``reductionism'' ; : I stress the collapse of supervenience into deduction via Beth's theorem ; : I adapt some examples already in the literature to show supervenience without emergence and vice versa. (shrink)

Thermodynamics and Statistical Mechanics are related to one another through the so-called "thermodynamic limit'' in which, roughly speaking the number of particles becomes infinite. At critical points (places of physical discontinuity) this limit fails to be regular. As a result, the "reduction'' of Thermodynamics to Statistical Mechanics fails to hold at such critical phases. This fact is key to understanding an argument due to Craig Callender to the effect that the thermodynamic limit leads to mistakes in Statistical Mechanics. I discuss (...) this argument and argue that the conclusion is misguided. In addition, I discuss an analogous example where a genuine physical discontinuity---the breaking of drops---requires the use of infinite idealizations. (shrink)

According to standard (quantum) statistical mechanics, the phenomenon of a phase transition, as described in classical thermodynamics, cannot be derived unless one assumes that the system under study is infinite. This is naturally puzzling since real systems are composed of a finite number of particles; consequently, a well‐known reaction to this problem was to urge that the thermodynamic definition of phase transitions (in terms of singularities) should not be “taken seriously.” This article takes singularities seriously and analyzes their role by (...) using the well‐known distinction between data and phenomena , in an attempt to better understand the origin of the puzzle. *Received April 2009; revised July 2009. †To contact the author, please write to: University of Cambridge, Department of History and Philosophy of Science, Free School Lane, Cambridge CB2 3RH, United Kingdom; e‐mail: [email protected]. (shrink)

This thesis gives a philosophical assessment of a contemporary movement, influential amongst physicists, about the status of microscopic and macroscopic properties. The fountainhead for the movement was a short 1972 paper `More is Different', written by the condensed-matter physicist, Philip Anderson. Each of the chapters is concerned with themes mentioned in that paper, or subsequently expounded by Anderson and his followers. In Chapter 1, I aim to locate Anderson's existence claims for `emergent properties' within the metaphysical, epistemological and methodological doctrines (...) that identify themselves as `emergentist'. I argue, against the commentators' consensus, that the New Emergentists make claims about the metaphysical status of physical properties, and should not be read as concerned only with matters of research methodology for physics. In Chapter 2, I look at the physical examples that the New Emergentists appeal to, and propose a way of formulating their main claims within modern analytic metaphysics. I argue that it is possible to view their thesis as an updated version of `British Emergentism' a movement popular in the early years of the twentieth century. I support this contention by comparing examples of emergent properties put forward by the British and the New Emergentists. Chapter 3 is a discussion of the significance of renormalisation techniques. I attack a set of claims by Robert Batterman, who presents renormalisation as an explanatory strategy unrecognised by the philosophy of science. I separate several different methods of renormalisation analysis, and argue that he has conflated them. In Chapter 4, I discuss the theoretical representation of phase transitions in condensed matter physics; in particular, their appeal to the limit of an infinite system. I examine and refute various claims to the effect that the ineliminability of this limit in modelling phase transitions is of great metaphysical significance. I suggest a definition of phase transitions for finite systems that dissolves this illusion, and gives us reason to trust the results of the theories that only apply in the infinite limit. %I then comment on the significance of these results for a suggestion of Laura Ruetsche, that quantum statistical mechanics should be used as a guide to the interpretation of quantum field theory. Chapter 5 revisits the doctrines of the New Emergentists in order to place their views within some wider philosophical debates. I look at how their doctrines bear on issues in the interpretation of quantum mechanics, in the philosophy of mind and the philosophy of science. I close by returning to the context within physics, in which the New Emergentists originally made their presence felt: the controversy over whether elementary particle physics should enjoy greater status than other areas. (shrink)

This paper examines the apparent paradox in the fact that all successful theoretical treatments of phase transitions require an infinite system, yet they are clearly seen to occur in finite systems in the real world. A simple resolution is offered, and the paper ends with a consideration of analogies that can be taken in interpretations of quantum theory.