Abstract

Throughout the history of philosophy, chemical concepts and theories have appeared in the work of philosophers, both as examples and as topics of discussion in their own right, and scientists themselves have often engaged with theoretical, conceptual, and methodological issues that fall within what one would now recognize as philosophy of chemistry. This chapter offers a summary of the history of philosophy of chemistry since Kant, alongside a critical examination of why chemistry has been relegated to the sidelines so frequently in recent philosophy of science. This history offers a unique vantage point from which to consider the interests and assumptions, often implicit, that underlie 20th-century philosophy's view of what science is or perhaps should be. These include the inheritance of logical positivism and empiricism, with its particular focus on theories expressed in the language of mathematics and understood as axiomatic systems, and the widespread acceptance of reductionist views of theoretical explanation. Against this background, much of chemistry disappears. Being perhaps too grounded in laboratory and experimental practice, and often practical in its aims and correspondingly pragmatic in its methods, chemical science seldom resembles an orderly top-down enterprise from fundamental theoretical principles. Many of its central "theories," like molecular structure, are expressed in systems of visual representation rather than mathematical equations. This chapter is further is devoted to brief discussions of historical individuals, both chemists and philosophers, whose work is relevant for contemporary philosophy of chemistry. © 2012 Elsevier B.V. All rights reserved.