Valencies of the lanthanides

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Foundations of Chemistry 20 (1):15-27 (2017)
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Abstract

The valencies of the lanthanides vary more than was once thought. In addition to valencies associated with a half-full shell, there are valencies associated with a quarter- and three-quarter-full shell. This can be explained on the basis of Slater’s theory of many-electron atoms. The same theory explains the variation in complexing constants in the trivalent state. Valency in metallic and organometallic compounds is also discussed.

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2018

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10.1007/s10698-017-9291-6

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David Anton Johnson
Brown University

Citations of this work

Editorial 63.Eric Scerri - 2019 - Foundations of Chemistry 21 (3):253-254.
What is chemistry that I may teach it?Peter G. Nelson - 2018 - Foundations of Chemistry 21 (2):179-191.
Editorial 63.Eric Scerri - 2019 - Foundations of Chemistry 21 (3):253-254.

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