In this paper I present a historiography of the recent emergence of philosophy of chemistry. Special attention is given to the interest in this domain in Eastern Europe before the collapse of the USSR. It is shown that the initial neglect of the philosophy of chemistry is due to the unanimous view in philosophy and philosophy of science that only physics is a proper science (to put in Kant's words). More recently, due to the common though incorrect assumption that chemistry (...) can in principle be reduced to physics, the neglect continued, even when interest in sciences such as biology and psychology entered more strongly in philosophy of science. It is concluded that chemistry is an autonomous science and is perhaps a more typical science than physics. (shrink)

A superselection rule advanced in the course of a quantum-mechanical treatment of some phenomenon is an assertion to the effect that the superposition principle of quantum mechanics is to be restricted in the application at hand. Superselection accounts of measurement all have in common a decision to represent the indicator states of detectors by eigenspaces of superselection operators named in a superselection rule, on the grounds that the states in question are states of a so-called classical quantity and therefore not (...) subject to quantum interference effects. By this strategy superselectionists of measurement expect to dispense with use of projection postulates in treatments of measurement. I shall argue that superselection accounts of measurement are self-contradictory, and that treatments of infinite systems, if they can avoid the contradiction, are not true superselection accounts. (shrink)

Hermeneutics, or interpretation, is concerned with the generation, transmission, and acceptance of meaning within the lifeworld, and was the original method of the human sciences stemming, from F. Schleiermacher and W. Dilthey. The `hermeneutic philosophy' refers mostly to Heidegger. This paper addresses natural science from the perspective of Heidegger's analysis of meaning and interpretation. Its purpose is to incorporate into the philosophy of science those aspects of historicality, culture, and tradition that are absent from the traditional analysis of theory and (...) explanation, to re-orient the current discussion about scientific realism around the hermeneutics of meaning and truth in science, and to establish some relationship between the current philosophy of natural science and hermeneutical philosophy. The paper has particular relevance to the history and social studies of science and technology. (shrink)

A view of individuals as constituted of quantities of matter, both understood as continuants enduring over time, is elaborated in some detail. Constitution is a three-place relation which can't be collapsed to identity because of the place-holder for a time and because individuals and quantities of matter have such a radically different character. Individuals are transient entities with limited lifetimes, whereas quantities are permanent existents undergoing change in physical and chemical properties from time to time. Coincidence, considered as a matter (...) of occupying the same place, is developed, alongside sameness of constitutive matter, as a criterion of identity for individuals. Quantities satisfy the mereological criterion of identity, applicable to entities subject to mereological relations and operations such as regions of space and intervals of time. A time-dependent analogue of mereological parthood is defined for individuals, in terms of which analogues of the other mereological relations can be defined. But it is argued that there is no analogue of the mereological operation of summation for individuals. (shrink)

‘Water is H 2 O’ is naturally construed as an equivalence. What are the things to which the two predicates ‘is water’ and ‘is H 2 O’ apply? The equivalence presupposes that substance properties are distinguished from phase properties. A substance like water (H 2 O) exhibits various phases (solid, liquid, gas) under appropriate conditions, and a given (say liquid) phase may comprise several substances. What general features distinguish substance from phase properties? I tackle these questions on the basis of (...) an interpretation of a theorem of thermodynamics known as Gibbs' phase rule which systematically relates these two kinds of feature of matter. The interpretation develops the idea that the things substance and phase predicates apply to are quantities of matter which sustain mereological relations and operations and exploits these mereological features in distinguishing the two kinds of property. Gibbs' phase rule is a macroscopic principle applicable for macroscopic intervals of time. Bringing intervals of time into the picture calls for a more detailed consideration of the relation between macroscopic equilibria and the corresponding dynamic equilibria at the microlevel and throws into question the simple idea that quantities can always be regarded as collections of molecules. The account provides some insight into how the continuous, macroscopic conception of matter (‘gunk’) is reconciled with the discrete microscopic conception and illuminates the interpretation of substances present in mixtures. (shrink)

An exposition of Pierre Duhem’s formulation of the structure of chemical substances as expressed by their formulas is given, presenting it as a development of his essentially Aristotelian view of mixtures. Duhem’s masterly development of the subject displays an eye for logical clarity familiar from his work in thermodynamics but applied here to the extraction of what he regarded as true from the history of chemistry. Though no longer defensible, the account has a conceptual interest in its own right and (...) illuminates a less frequently discussed side of Duhem’s views. (shrink)

What are the criteria determining the individuation of chemical kinds? Recent philosophical discussion, which puts too much emphasis on microstructure, seems to presuppose a reductionist conception not motivated by the scientific facts. The present article traces the development of the traditional notion of a substance with the rise of modern chemistry from the end of the 18th century with a view to correcting this speculative distortion.

Bodies as conceived in macroscopic theories are loosely spoken of as participating in processes. But are there any systematic reasons for regarding processes as part of the ontology of macroscopic theory? The present paper suggests that suitable motivation can be found within a project of describing a phenomenological, macroscopic ontology for equilibrium thermodynamics, and outlines some aspects of the interrelation between continuant bodies and processes.

Duhem is often described as an anti-realist or instrumentalist. A contrary view has recently been expressed by Martin (1991) (Pierre Duhem: Philosophy and History in the Work of a Believing Physicist (La Salle, IL: Open Court)), who suggests that this interpretation makes it difficult to understand the vantage point from which Duhem argues in La science allemande (1915) that deduction, however impeccable, cannot establish truths unless it begins with truths. In the same spirit, the present paper seeks to establish that (...) Duhem is at any rate not the kind of anti-realist he is often presented as being, and that his views are like those Quine sees fit to call realist. An interpretation of Duhem's views on explanation and precision in science, and their bearing on the epistemological status of theory, is advanced which leads naturally into his critique of conventionalism. His attitude towards atomism, which should not be judged from a post-1925 perspective, is considered part of the unified view he strove after and appropriately called Duhem's physicalism, standing in contrast to the kind of reductionist conception usually associated with atomism. (shrink)

Why a hermeneutical philosophy of the natural sciences? It is necessary to address the philosophic crisis of realism vs relativism in the natural sciences. This crisis is seen as a part of the cultural crisis that Husserl and Heidegger identified and attributed to the hegemonic role of theoretical and calculative thought in Western societies. The role of theory is addressed using the hermeneutical circle to probe the origin of theoretic meaning in scientific cultural praxes. This is studied in Galileo's discovery (...) of the phases of Venus; the practice of measurement; the different theories and practices of space perception; the historicality and temporality of scientific research communities which ground paradigm change; and the process of discovery. The paper draws particularly from the work of Heidegger. Though envisaging all science and scholarship, the highlighted theme is research in the natural sciences. (shrink)

Hermeneutics, or interpretation, is concerned with the generation, transmission, and acceptance of meaning within the lifeworld, and was the original method of the human sciences stemming, from F. Schleiermacher and W. Dilthey. The `hermeneutic philosophy' refers mostly to Heidegger. This paper addresses natural science from the perspective of Heidegger's analysis of meaning and interpretation. Its purpose is to incorporate into the philosophy of science those aspects of historicality, culture, and tradition that are absent from the traditional analysis of theory and (...) explanation, to re-orient the current discussion about scientific realism around the hermeneutics of meaning and truth in science, and to establish some relationship between the current philosophy of natural science and hermeneutical philosophy. The paper has particular relevance to the history and social studies of science and technology. (shrink)