I argue that molecules may not have structure in isolation. I support this by investigating how quantum models identify structure for isolated molecules. Specifically, I distinguish between two sets of models: those that identify structure in isolation and those that do not. The former identify structure because they presuppose structural information about the target system via the Born- Oppenheimer approximation. However, it is an idealisation to assume structure in isolation because there is no empirical evidence of this. In fact, whenever (...) structure is empirically examined it is always partially determined by factors that are absent in isolation. Together with the growing empirical evidence that isolated molecules behave in non-classical ways, this shows that the quantum models that do not identify structure are more faithful representations of isolated molecules. (shrink)

The aim of this paper is to consider in what sense the modal-Hamiltonian interpretation of quantum mechanics satisfies the physical constraints imposed by the Galilean group. In particular, we show that the only apparent conflict, which follows from boost-transformations, can be overcome when the definition of quantum systems and subsystems is taken into account. On this basis, we apply the interpretation to different well-known models, in order to obtain concrete examples of the previous conceptual conclusions. Finally, we consider the role (...) played by the Casimir operators of the Galilean group in the interpretation. (shrink)

We introduce a realist, unextravagant interpretation of quantum theory that builds on the existing physical structure of the theory and allows experiments to have definite outcomes but leaves the theory’s basic dynamical content essentially intact. Much as classical systems have specific states that evolve along definite trajectories through configuration spaces, the traditional formulation of quantum theory permits assuming that closed quantum systems have specific states that evolve unitarily along definite trajectories through Hilbert spaces, and our interpretation extends this intuitive picture (...) of states and Hilbert-space trajectories to the more realistic case of open quantum systems despite the generic development of entanglement. We provide independent justification for the partial-trace operation for density matrices, reformulate wave-function collapse in terms of an underlying interpolating dynamics, derive the Born rule from deeper principles, resolve several open questions regarding ontological stability and dynamics, address a number of familiar no-go theorems, and argue that our interpretation is ultimately compatible with Lorentz invariance. Along the way, we also investigate a number of unexplored features of quantum theory, including an interesting geometrical structure—which we call subsystem space—that we believe merits further study. We conclude with a summary, a list of criteria for future work on quantum foundations, and further research directions. We include an appendix that briefly reviews the traditional Copenhagen interpretation and the measurement problem of quantum theory, as well as the instrumentalist approach and a collection of foundational theorems not otherwise discussed in the main text. (shrink)

Quantum mechanics studies physical phenomena on a microscopic scale. These phenomena are far beyond the reach of our observation, and the connection between QM's mathematical formalism and the experimental results is very indirect. Furthermore, quantum indeterminism defies common sense. Microphysical experiments have shown that, according to the empirical context, electrons and quanta of light behave as waves and other times as particles, even though it is impossible to design an experiment that manifests both behaviors at the same time. Unlike Newtonian (...) physics, the properties of quantum systems are not all well-defined simultaneously. Moreover, quantum systems are not characterized by their properties, but by a wave function. Although one of the principles of the theory is the uncertainty principle, the trajectory of the wave function is controlled by the deterministic Schrödinger equations. But what is the wave function? Like other theories of the physical sciences, quantum theory assigns states to systems. The wave function is a particular mathematical representation of the quantum state of a physical system, which contains information about the possible states of the system and the respective probabilities of each state. (shrink)

In the last years, the surprising bosonic behavior that a many-fermion system may acquire has raised interest because of theoretical and practical reasons. This trans-statistical behavior is usually considered to be the result of approximation modeling methods generally employed by physicists when faced with complexity. In this paper, we take a tensor product structure and an ontology of properties approach and provide two versions of a toy model in order to argue that trans-statistical behavior allows for a realistic interpretation.

Some authors, inspired by the theoretical requirements for the formulation of a quantum theory of gravity, proposed a relational reconstruction of the quantum parameter-time—the time of the unitary evolution, which would make quantum mechanics compatible with relativity. The aim of the present work is to follow the lead of those relational programs by proposing a relational reconstruction of the event-time—which orders the detection of the definite values of the system’s observables. Such a reconstruction will be based on the modal-Hamiltonian interpretation (...) of quantum mechanics, which provides a clear criterion to select which observables acquire a definite value and to specify in what situation they do so. (shrink)

Harrigan and Spekkens provided a categorization of quantum ontological models classifying them as \-ontic or \-epistemic if the quantum state \ describes respectively either a physical reality or mere observers’ knowledge. Moreover, they claimed that Einstein—who was a supporter of the statistical interpretation of quantum mechanics—endorsed an epistemic view of \ In this essay we critically assess such a classification and some of its consequences by proposing a twofold argumentation. Firstly, we show that Harrigan and Spekkens’ categorization implicitly assumes that (...) a complete description of a quantum system ) only concerns single, individual systems instantiating absolute, intrinsic properties. Secondly, we argue that such assumptions conflict with some current interpretations of quantum mechanics, which employ different ontic states as a complete description of quantum systems. In particular, we will show that, since in the statistical interpretation ontic states describe ensembles rather than individuals, such a view cannot be considered \-epistemic. As a consequence, the authors misinterpreted Einstein’s view concerning the nature of the quantum state. Next, we will focus on relational quantum mechanics and perspectival quantum mechanics, which in virtue of their relational and perspectival metaphysics employ ontic states \ dealing with relational properties. We conclude that Harrigan and Spekkens’ categorization is too narrow and entails an inadequate classification of the mentioned interpretations of quantum theory. Hence, any satisfactory classification of quantum ontological models ought to take into account the variations of \ across different interpretations of quantum mechanics. (shrink)

When young Kant meditated upon the distinction between his right and left hands, he could not foresee that the problem of incongruent counterparts would revive in the twentieth century under a new form. In the early days of quantum chemistry, Friedrich Hund developed the so-called Hund paradox that arises from the supposed inability of quantum mechanics to account for the difference between enantiomers. In this paper, the paradox is expressed as a case of quantum measurement, stressing that decoherence does not (...) offer a way out of the problem. The main purpose is to argue for the need to adopt a clear interpretation of quantum mechanics in order to solve the paradox. In particular, I claim that the Modal-Hamiltonian Interpretation, which conceives measurement as a breaking-symmetry process, supplies the tools required to explain the dextro-rotation or levo-rotation properties of optical isomers. (shrink)

In the present paper we address the problem of optical isomerism embodied in the socalled “Hund’s paradox”, which points to the difficulty to account for chirality by means of quantum mechanics. In particular, we explain the answer to the problem proposed by the theory of decoherence. The purpose of this article is to challenge this answer on the basis of a conceptual analysis of the phenomenon of decoherence, that reveals the limitations of the theory of decoherence to solve the difficulties (...) posed by optical isomerism and, in general, by quantum measurement. (shrink)

Los criterios de identidad propuestos por la metafísica tradicional debieron ser sometidos a una profunda revisión cuando entró en escena la mecánica cuántica con sus característicos sistemas indistinguibles. En este trabajo aplicamos el modelo de espacios controversiales de Oscar Nudler para analizar la controversia sobre la identidad en el ámbito de la mecánica cuántica y proponer la introducción en el debate de una ontología cuántica de propiedades sin objetos.

The many-faced relationship between chemistry and physics is one of the most discussed topics in the philosophy of chemistry. In his recent book Reducing Chemistry to Physics. Limits, Models, Consequences, Hinne Hettema conceives this relationship as a reduction link, and devotes his work to defend this position on the basis of a “naturalized” concept of reduction. In the present paper I critically review three kinds of issues stemming from Hettema’s argumentation: philosophical, scientific and methodological.

In the literature on the interpretation of quantum mechanics, not many works attempt to adopt a proactive perspective aimed at seeing how different interpretations can enrich each other through a productive dialogue. In particular, few proposals have been devised to show that different approaches can be clarified by comparing them, and can even complement each other, improving or leading to a more fertile overall approach. The purpose of this paper is framed within this perspective of complementation and mutual enrichment. In (...) particular, the Relational Quantum Mechanics and the Modal-Hamiltonian Interpretation are compared, highlighting their differences and points of contact. The final purpose is to show that, in spite of their disagreements, they are not contradictory but, on the contrary, they can be made compatible from an overarching perspective and can even complement each other in a fruitful way. (shrink)

El propósito del presente trabajo consiste en abordar la pregunta por la ontología de la química cuántica. Para ello nos concentraremos en el concepto de enlace químico desde la perspectiva de los dos enfoques a través de los cuales la ecuación de Schrödinger se aplica a los sistemas químicos moleculares: la teoría del enlace de valencia (EV) y la teoría del orbital molecular (OM). Sobre la base de la presentación de ambos enfoques y su comparación, señalaremos que, a pesar de (...) su denominación tradicional, no pueden considerarse estrictamente como teorías científicas, sino que se ajustan mejor a la noción de modelo; en particular, son modelos que incorporan conceptos y leyes tanto del ámbito de la mecánica cuántica como del de la química estructural. Estas consideraciones nos permitirán argumentar que la química cuántica no posee un referente ontológico autónomo, sino que se trata de un ámbito científico cuya vigencia descansa sobre su éxito práctico en el cálculo y la predicción. Finalmente, indicaremos de qué modo los enfoques EV y OM del enlace químico abren una nueva perspectiva respecto de la noción misma de modelo en ciencias empíricas. (shrink)

Given the impressive success of environment-induced decoherence, nowadays no interpretation of quantum mechanics can ignore its results. The modal-Hamiltonian interpretation has proved to be effective for solving several interpretative problems, but since its actualization rule applies to closed systems, it seems to stand at odds with EID. The purpose of this article is to show that this is not the case: the states einselected by the interaction with the environment according to EID are the eigenvectors of an actual-valued observable belonging (...) to the preferred context selected by the MHI. (shrink)

Este trabajo presenta algunas discusiones preliminares a una reconstrucción de la mecánicacuántica desde una perspectiva estructuralista. Intento responder a la pregunta por lostérminos MQ- no teóricos, es decir, qué magnitudes pueden ser medidas con independenciade la ecuación de Schrödinger y de la regla de Born. Uno de los aspectos relevantes que puedeser analizado una vez que se ha respondido a esta pregunta es el problema de la medición.Dado que el problema de la medición está directamente relacionado con el carácter linealde (...) la evolución temporal del estado dada por la ecuación de Schrödinger, la medición delos valores de aquellos conceptos que no presupongan esta ley no se verá afectada por esteproblema. Si bien esto no responde a todas las preguntas sobre la medición cuántica, indicaun primer paso a dar en la dirección hacia una comprensión más acabada de este problema. (shrink)

In previous works, an ontology of properties for quantum mechanics has been proposed, according to which quantum systems are bundles of properties with no principle of individuality. The aim of the present article is to show that, since quasi-set theory is particularly suited for dealing with aggregates of items that do not belong to the traditional category of individual, it supplies an adequate meta-language to speak of the proposed ontology of properties and its structure.

We argue that it is fundamentally impossible to recover information about quantum superpositions when a quantum system has interacted with a sufficiently large number of degrees of freedom of the environment. This is due to the fact that gravity imposes fundamental limitations on how accurate measurements can be. This leads to the notion of undecidability: there is no way to tell, due to fundamental limitations, if a quantum system evolved unitarily or suffered wavefunction collapse. This in turn provides a solution (...) to the problem of outcomes in quantum measurement by providing a sharp criterion for defining when an event has taken place. We analyze in detail in examples two situations in which in principle one could recover information about quantum coherence: (a) “revivals” of coherence in the interaction of a system with the measurement apparatus and the environment and (b) the measurement of global observables of the system plus apparatus plus environment. We show in the examples that the fundamental limitations due to gravity and quantum mechanics in measurement prevent both revivals from occurring and the measurement of global observables. It can therefore be argued that the emerging picture provides a complete resolution to the measurement problem in quantum mechanics. (shrink)

The interpretation of the concept of reduced state is a subtle issue that has relevant consequences when the task is the interpretation of quantum mechanics itself. The aim of this paper is to argue that reduced states are not the quantum states of subsystems in the same sense as quantum states are states of the whole composite system. After clearly stating the problem, our argument is developed in three stages. First, we consider the phenomenon of environment-induced decoherence as an example (...) of the case in which the subsystems interact with each other; we show that decoherence does not solve the measurement problem precisely because the reduced state of the measuring apparatus is not its quantum state. Second, the non-interacting case is illustrated in the context of no-collapse interpretations, in which we show that certain well-known experimental results cannot be accounted for due to the fact that the reduced states of the measured system and the measuring apparatus are conceived as their quantum states. Finally, we prove that reduced states are a kind of coarse-grained states, and for this reason they cancel the correlations of the subsystem with other subsystems with which it interacts or is entangled. (shrink)

In a recent article entitled “The problem of molecular structure just is the measurement problem”, Alexander Franklin and Vanessa Seifert argue that insofar as the quantum measurement problem is solved, the problems of molecular structure are resolved as well. The purpose of the present article is to show that such a claim is too optimistic. Although the solution of the quantum measurement problem is relevant to how the problem of molecular structure is faced, such a solution is not sufficient to (...) account for the structure of molecules as understood in the field of chemistry. (shrink)

In the present paper we address the problem of optical isomerism embodied in the socalled “Hund’s paradox”, which points to the difficulty to account for chirality by means of quantum mechanics. In particular, we explain the answer to the problem proposed by the theory of decoherence. The purpose of this article is to challenge this answer on the basis of a conceptual analysis of the phenomenon of decoherence, that reveals the limitations of the theory of decoherence to solve the difficulties (...) posed by optical isomerism and, in general, by quantum measurement. (shrink)

The modal-Hamiltonian interpretation belongs to the modal family of interpretations of quantum mechanics. By endowing the Hamiltonian with the role of selecting the subset of the definite-valued observables of the system, it accounts for ideal and non-ideal measurements, and also supplies a criterion to distinguish between reliable and non-reliable measurements in the non-ideal case. It can be reformulated in an explicitly invariant form, in terms of the Casimir operators of the Galilean group, and the compatibility of the MHI with the (...) theory of decoherence has been proved. Nevertheless, perhaps its main advantage in the eyes of a scientist is given by its several applications to well-known physical situations, leading to results compatible with experimental evidence. The purpose of this paper is to add a new application to the list: the case of optical isomerism, which is a central issue for the philosophy of physics and of chemistry since it points to the core of the problem of the relationship between physics and chemistry. Here it will be shown that the MHI supplies a direct and physically natural solution to the problem, a solution that does not require putting classical assumptions in “by hand.”. (shrink)

Se cuestiona que la restitución de hijos/as de desaparecidos/as durante la última dictadura argentina exalta una concepción biológica, conservadora de la identidad personal. Argumentaré que el problema de esta noción no radica en la apelación a lo biológico, sino en la adopción de dos supuestos metafísicos: una ontología de individuos sustanciales y un esencialismo actualista. Propondré una concepción de la identidad relacional y como potencia o locus de poder, que permitirá re-significar lo biológico de la identidad y apoyar el fenómeno (...) de la restitución. (shrink)

The purpose of the present paper is to consider the traditional interpretive problems of quantum mechanics from the viewpoint of a modal ontology of properties. In particular, we will try to delineate a quantum ontology that (i) is modal, because describes the structure of the realm of possibility, and (ii) lacks the ontological category of individual. The final goal is to supply an adequate account of quantum non-individuality on the basis of this ontology.

According to ontological reductionism, molecular chemistry refers, at last, to the quantum ontology; therefore, the ontological commitments of chemistry turn out to be finally grounded on quantum mechanics. The main problem of this position is that nobody really knows what quantum ontology is. The purpose of this work is to argue that the confidence in the existence of the physical entities described by quantum mechanics does not take into account the interpretative problems of the theory: in the discussions about the (...) relationship between chemistry and physics, difficulties are seen only on the side of chemistry, whereas matters highly controversial on the side of physics are taken for granted. For instance, it is usually supposed that the infinite mass limit in the Born-Oppenheimer approximation leads by itself to the concept of molecular framework used in molecular chemistry. We will argue that this assumption is implicitly based on an interpretative postulate for quantum mechanics, which, in turn, runs into difficulties when applied to the explanation of the simplest model of the hydrogen atom. (shrink)

The difficult issues related to the interpretation of quantum mechanics and, in particular, the “measurement problem” are revisited using as motivation the process of generation of structure from quantum fluctuations in inflationary cosmology. The unessential mathematical complexity of the particular problem is bypassed, facilitating the discussion of the conceptual issues, by considering, within the paradigm set up by the cosmological problem, another problem where symmetry serves as a focal point: a simplified version of Mott’s problem.

This article presents a reconstruction of the so-called classical, formal or Mendelian genetics, which is intended to be more complete and adequate than existing reconstructions. This reconstruction has been carried out with the instruments, duly modified and extended with respect to the case under consideration, of the structuralist conception of theories. The so-called Mendel’s Laws, as well as linkage genetics and gene mapping are formulated in a precise manner while the global structure of genetics is represented as a theory-net. These (...) results are of methodological, philosophical and didactical relevance. (shrink)

We introduce an ontology of objects and events that is particularly well suited for several interpretations of quantum mechanics. It leads to an important revision of the notion of matter and its implications. Within this context one can show that systems in entangled states present emergent new properties and downward causation where certain behavior of parts of the system are only determined by the state of the whole. Interpretations of quantum mechanics that admit such an event ontology solve the problem (...) of emergence. (shrink)

This work is a critique of the program of "environment-induced decoherence" as advocated by Zurek, Zeh and Joos, among others. In particular, the alleged relevance of decoherence for a solution of the "measurement problem" is subjected to a detailed philosophical analysis. In the first chapter, an attempt is made to unravel what exactly this "measurement problem" amounts to for the decoherence theorists. The second chapter reviews the standard decoherence literature. The third chapter starts with a brief discussion of the philosophical (...) implications of the decoherence program, followed by a non-standard reconstruction of the decoherence argument that aims to uncover some (mostly hidden) assumptions underlying the approach. It is argued that different subsets of these assumptions result in different versions of the decoherence argument. Next, these assumptions are investigated in more detail, and a number of open problems for the decoherence approach is formulated, in addition to the well-known "problem of outcomes". These problems concern the interpretational relevance of the preferred basis, the role and status of the ignorance interpretation of mixed states, imperfect decoherence and the role of the environment and the definition of subsystems. The fourth chapter addresses the question to what extent the embedding of decoherence in an Everett-like interpretational framework, such as Zurek's "existentional interpretation" and Wallace's structural-realistic version of the many-worlds interpretation, helps to resolve these problems. The main conclusions are formulated in the fifth chapter. Namely: 1) decoherence cannot address the "preferred-basis problem" without adding new interpretational axioms to the standard formalism, 2) the the locality principle (that says that the environment is the "irrelevant" part and should therefore be ignored) is not only problematic but also interpretationally superfluous, 3) the decoherence approach, when formulated in terms of the standard interpretation of quantum mechanics, is predicated on a solution of the "problem of outcomes" and thus cannot claim to account (even partially) for the latter, and 4) that the results of the decoherence program do not increase the plausibility of a realist interpretation of the quantum state. (shrink)

In this paper it will be argued that any realist interpretation of quantum mechanics intending to preserve the objectivity of the set of the definite-valued observables should require such a set to be invariant under the symmetry group of the theory. In particular, it will be shown that the natural way to reach this goal is to appeal to the Casimir operators of the Galilean group. Additionally, this idea will be generalized in two ways: by selecting the definite-valued observables of (...) a system in quantum field theory as those represented by the Casimir operators of the Poincaré group, and by extending the strategy to gauge symmetries. (shrink)

The more common scheme to explain the classical limit of quantum mechanics includes decoherence, which removes from the state the interference terms classically inadmissible since embodying non-Booleanity. In this work we consider the classical limit from a logical viewpoint, as a quantum-to-Boolean transition. The aim is to open the door to a new study based on dynamical logics, that is, logics that change over time. In particular, we appeal to the notion of hybrid logics to describe semiclassical systems. Moreover, we (...) consider systems with many characteristic decoherence times, whose sublattices of properties become distributive at different times. (shrink)

In April 2016, Daniela Frauchiger and Renato Renner published an article online in which they introduce a Gedankenexperiment that led them to conclude that single-world interpretations of quantum theory cannot be self-consistent. In a new version of the paper, published in September 2018, the authors moderate their original claim by concluding that quantum theory cannot be extrapolated to complex systems, at least not in a straightforward manner. The purpose of this short article is to clarify the core of the F-R (...) argument, in order to show how the contradiction is obtained. On the basis of this clarification, we argue that the result of the F-R argument has been overestimated and should be reconsidered from a more cautious perspective. (shrink)

Experimental evidence of the last decades has made the status of ``collapses of the wave function'' even more shaky than it already was on conceptual grounds: interference effects turn out to be detectable even when collapses are typically expected to occur. Non-collapse interpretations should consequently be taken seriously. In this paper we argue that such interpretations suggest a perspectivalism according to which quantum objects are not characterized by monadic properties, but by relations to other systems. Accordingly, physical systems may possess (...) different properties with respect to different ``reference systems''. We discuss some of the relevant arguments, and argue that perspectivalism both evades recent arguments that single-world interpretations are inconsistent and eliminates the need for a privileged rest frame in the relativistic case. (shrink)