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Emergence vs. Reduction in Chemistry

In Cynthia Macdonald & Graham Macdonald (eds.), Emergence in Mind. Oxford University Press (2010)

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  1. Do molecules have structure in isolation? How models can provide the answer.Vanessa Seifert - 2022 - In Olimpia Lombardi, Juan Camilo Martínez & Sebastian Fortin (eds.), Philosophical Perspectives on Quantum Chemistry. Springer Cham. pp. 125–143.
    I argue that molecules may not have structure in isolation. I support this by investigating how quantum models identify structure for isolated molecules. Specifically, I distinguish between two sets of models: those that identify structure in isolation and those that do not. The former identify structure because they presuppose structural information about the target system via the Born- Oppenheimer approximation. However, it is an idealisation to assume structure in isolation because there is no empirical evidence of this. In fact, whenever (...)
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  • Emergence, Reduction and the Identity and Individuation of Powers.Alexander Daniel Carruth - 2020 - Topoi 39 (5):1021-1030.
    One recently popular way to characterise strong emergence is to say that emergent entities possess novel causal powers. However, there is little agreement concerning the nature of powers. One controversy involves whether powers are single- or multi-track; that is, whether each power has only one manifestation type, or whether a single power can be directed towards a number of distinct manifestations. Another concerns how powers operate: whether a lone power manifests when triggered by the presence of a suitable stimulus, or (...)
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  • Emergence in Mind (Mind Association Occasional Series) . Edited by Cynthia and Macdonald. New York: Oxford University Press, 2010. 288 pages ISBN 13: 978-0-19-958362-1. [REVIEW]Elly Vintiadis - 2012 - Philosophy 87 (4):603-610.
  • Are Acids Natural Kinds?Pieter Thyssen - forthcoming - Foundations of Chemistry:1-29.
    Are acids natural kinds? Or are they merely relevant kinds? Although acidity has been one of the oldest and most important concepts in chemistry, surprisingly little ink has been spilled on the natural kind question. I approach the question from the perspective of microstructural essentialism. After explaining why both Brønsted acids and Lewis acids are considered functional kinds, I address the challenges of multiple realization and multiple determination. Contra Manafu and Hendry, I argue that the stereotypical properties of acids are (...)
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  • The strong emergence of molecular structure.Vanessa A. Seifert - 2020 - European Journal for Philosophy of Science 10 (3):1-25.
    One of the most plausible and widely discussed examples of strong emergence is molecular structure. The only detailed account of it, which has been very influential, is due to Robin Hendry and is formulated in terms of downward causation. This paper explains Hendry’s account of the strong emergence of molecular structure and argues that it is coherent only if one assumes a diachronic reflexive notion of downward causation. However, in the context of this notion of downward causation, the strong emergence (...)
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  • How to minimize ontological commitments: a grounding-reductive approach.Reuben Sass - 2022 - Synthese 200 (4):1-22.
    Some revisionary ontologies are highly parsimonious: they posit far fewer entities than what we quantify over in ordinary discourse. The most radical examples are minimal ontologies, on which physical simples are the only things that exist. Highly parsimonious ontologies, and especially minimal ones, face the challenge of either accounting for the truth of our ordinary quantificational discourse, or paraphrasing such discourse away. Common strategies for addressing this challenge include classical reduction, paraphrase nihilism, and a distinction between ontological and existence commitments. (...)
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  • No microphysical causation? No problem: selective causal skepticism and the structure of completeness-based arguments for physicalism.Matthew C. Haug - 2019 - Synthese 196 (3):1187-1208.
    A number of philosophers have argued that causation is not an objective feature of the microphysical world but rather is a perspectival phenomenon that holds only between “coarse-grained” entities such as those that figure in the special sciences. This view seems to pose a problem for arguments for physicalism that rely on the alleged causal completeness of physics. In this paper, I address this problem by arguing that the completeness of physics has two components, only one of which is causal. (...)
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  • Structure, shape, topology: entangled concepts in molecular chemistry.Elena Ghibaudi, Luigi Cerruti & Giovanni Villani - 2019 - Foundations of Chemistry 22 (2):279-307.
    The concepts of molecular structure and molecular shape are ubiquitous in the chemical literature, where they are often taken as synonyms, with unavoidable drawbacks in chemistry teaching. A third concept, molecular topology, is less frequent but it is a reference term in molecular research domains such as Quantitative Structure–Activity Relationships. The present paper proposes an epistemological analysis of these three notions, aimed at clarifying the nature of their relationship, as well as the contiguities and differences between them. At first, we (...)
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  • The Problem of Molecular Structure Just Is The Measurement Problem.Alexander Franklin & Vanessa Angela Seifert - forthcoming - The British Journal for the Philosophy of Science.
    Whether or not quantum physics can account for molecular structure is a matter of considerable controversy. Three of the problems raised in this regard are the problems of molecular structure. We argue that these problems are just special cases of the measurement problem of quantum mechanics: insofar as the measurement problem is solved, the problems of molecular structure are resolved as well. In addition, we explore one consequence of our argument: that claims about the reduction or emergence of molecular structure (...)
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  • Finding Time for Wheeler-DeWitt Cosmology.Nick Huggett & Karim Thebault - manuscript
    We conduct a case study analysis of a proposal for the emergence of time based upon the approximate derivation of three grades of temporal structure within an explicit quantum cosmological model which obeys a Wheeler-DeWitt type equation without an extrinsic time parameter. Our main focus will be issues regarding the consistency of the approximations and derivations in question. Our conclusion is that the model provides a self-consistent account of the emergence of chronordinal, chronometric and chronodirected structure. Residual concerns relate to (...)
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  • Emerging into the Rainforest: Emergence and Special Science Ontology.Alexander Franklin & Katie Robertson - manuscript
    Many philosophers of science are ontologically committed to a lush rainforest of special science entities ), but are often reticent about the criteria that determine which entities count as real. On the other hand, the metaphysics literature is much more forthcoming about such criteria, but often links ontological commitment to irreducibility. We argue that the irreducibility criteria are in tension with scientific realism: for example, they would exclude viruses, which are plausibly theoretically reducible and yet play a sufficiently important role (...)
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  • God et al—World-Making as Collaborative Improvisation: New Metaphors for Open Theists.Mark Steen - 2021 - In Jeffrey Koperski & Kelly James Clark (eds.), Abrahamic Reflections on Randomness and Providence. Cham, Switzerland: pp. 311-338.
    The Abrahamic traditions regard God as the world’s author. But what kind of author? A novelist? A playwright? Perhaps a composer of classical music? I will argue that it is best to regard God as like an improvisational play director or the leader of a jazz ensemble. Each determines the broad melodic contours or coarse-grained plot beforehand, while allowing their musicians or actors, and chance, to fill in the more fine-grained details. This analogy allows us to regard God as the (...)
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