In October 1924, The Physical Review, a relatively minor journal at the time, published a remarkable two-part paper by John H. Van Vleck, working in virtual isolation at the University of Minnesota. Using Bohr’s correspondence principle and Einstein’s quantum theory of radiation along with advanced techniques from classical mechanics, Van Vleck showed that quantum formulae for emission, absorption, and dispersion of radiation merge with their classical counterparts in the limit of high quantum numbers. For modern readers Van Vleck’s paper is (...) much easier to follow than the famous paper by Kramers and Heisenberg on dispersion theory, which covers similar terrain and is widely credited to have led directly to Heisenberg’s Umdeutung paper. This makes Van Vleck’s paper extremely valuable for the reconstruction of the genesis of matrix mechanics. It also makes it tempting to ask why Van Vleck did not take the next step and develop matrix mechanics himself. (shrink)

In October 1924, The Physical Review, a relatively minor journal at the time, published a remarkable two-part paper by John H. Van Vleck, working in virtual isolation at the University of Minnesota. Van Vleck used Bohr's correspondence principle and Einstein's quantum theory of radiation to find quantum formulae for the emission, absorption, and dispersion of radiation. The paper is similar but in many ways superior to the well-known paper by Kramers and Heisenberg published the following year that is widely credited (...) to have led directly to Heisenberg's Umdeutung paper. As such, it clearly shows how strongly the discovery of matrix mechanics depended on earlier work on the application of the correspondence principle to the interaction of matter and radiation. (shrink)