The distribution function associated with a classical gas at equilibrium is considered. We prove that apart from a factorisable multiplier, the distribution function is fully determined by the correlations among local momenta fluctuations. Using this result we discuss the conditions which enable idealised local observers, who are immersed in the gas and form a part of it, to determine the distribution 'from within'. This analysis sheds light on two views on thermodynamic equilibrium, the 'ergodic' and the 'thermodynamic limit' schools, and (...) the relations between them. It also provides an outline for a new definition of equilibrium that is weaker than full ergodicity. Finally, we briefly discuss the possibility that the distribution can be determined by external observers. (shrink)

We discuss a recent proposal by Albert (1994a; 1994b; 2000, ch. 7) to recover thermodynamics on a purely dynamical basis, using the quantum theory of the collapse of the wave function by Ghirardi, Rimini, and Weber (1986). We propose an alternative way to explain thermodynamics within no-collapse interpretations of quantum mechanics. Our approach relies on the standard quantum mechanical models of environmental decoherence of open systems (e.g., Joos and Zeh 1985; Zurek and Paz 1994). This paper presents the two approaches (...) and discusses their advantages. The problems faced by both approaches will be discussed in a sequel (Hemmo and Shenker 2003). (shrink)

Huw Price (1996, 2002, 2003) argues that causal-dynamical theories that aim to explain thermodynamic asymmetry in time are misguided. He points out that in seeking a dynamical factor responsible for the general tendency of entropy to increase, these approaches fail to appreciate the true nature of the problem in the foundations of statistical mechanics (SM). I argue that it is Price who is guilty of misapprehension of the issue at stake. When properly understood, causal-dynamical approaches in the foundations of SM (...) offer a solution for a different problem; a problem that unfortunately receives no attention in Price’s celebrated work. (shrink)

It has become something of a dogma in the philosophy of science that modern cosmology has completed Boltzmann's program for explaining the statistical validity of the Second Law of thermodynamics by providing the low entropy initial state needed to ground the asymmetry in entropic behavior that underwrites our inference about the past. This dogma is challenged on several grounds. In particular, it is argued that it is likely that the Boltzmann entropy of the initial state of the universe is an (...) ill-defined or severely hobbled concept. It is also argued that even if the entropy of the initial state of the universe had a well-defined, low value, this would not suffice to explain why thermodynamics works as well as it does for the kinds of systems we care about. Because the role of Boltzmann entropy in our inferences to the past has been vastly overrated, the failure of the Boltzmann program does not pose a serious problem for our knowledge of the past. But it does call a different explanation of why thermodynamics works as well as it does. A suggestion is offered for a different approach. (shrink)

Using the 'Aharonov approach', Linden and colleagues purportedly prove that reaching equilibrium is a universal property of quantum systems. Such a proof would constitute a very significant result in the foundations of statistical mechanics. I argue that, as it stands, this proof is not sound. However, based on the their theorems, I construct an argument for the conclusion that an arbitrary small subsystem of a large quantum system typically tends toward and remains in, or close to, equilibrium. This is the (...) central result of the article. In the final part of the article, I defend the Aharonov approach against anti-interventionist criticisms. (shrink)

Philosophers of physics have long debated whether the Past State of low entropy of our universe calls for explanation. What is meant by “calls for explanation”? In this article we analyze this notion, distinguishing between several possible meanings that may be attached to it. Taking the debate around the Past State as a case study, we show how our analysis of what “calling for explanation” might mean can contribute to clarifying the debate and perhaps to settling it, thus demonstrating the (...) fruitfulness of this analysis. Applying our analysis, we show that two main opponents in this debate, Huw Price and Craig Callender, are, for the most part, talking past each other rather than disagreeing, as they employ different notions of “calling for explanation”. We then proceed to show how answering the different questions that arise out of the different meanings of “calling for explanation” can result in clarifying the problems at hand and thus, hopefully, to solving them. (shrink)

Interference phenomena are a well-known and crucial feature of quantum mechanics, the two-slit experiment providing a standard example. There are situations, however, in which interference effects are (artificially or spontaneously) suppressed. We shall need to make precise what this means, but the theory of decoherence is the study of (spontaneous) interactions between a system and its environment that lead to such suppression of interference. This study includes detailed modelling of system-environment interactions, derivation of equations (‘master equations’) for the (reduced) state (...) of the system, discussion of time-scales etc. A discussion of the concept of suppression of interference and a simplified survey of the theory is given in Section 2, emphasising features that will be relevant to the following discussion (and restricted to standard non-relativistic particle quantum mechanics.[1] A partially overlapping field is that of decoherent histories, which proceeds from an abstract definition of loss of interference, but which we shall not be considering in any detail. (shrink)

Or better: time asymmetry in thermodynamics. Better still: time asymmetry in thermodynamic phenomena. “Time in thermodynamics” misleadingly suggests that thermodynamics will tell us about the fundamental nature of time. But we don’t think that thermodynamics is a fundamental theory. It is a theory of macroscopic behavior, often called a “phenomenological science.” And to the extent that physics can tell us about the fundamental features of the world, including such things as the nature of time, we generally think that only fundamental (...) physics can. On its own, a science like thermodynamics won’t be able to tell us about time per se. But the theory will have much to say about everyday processes that occur in time; and in particular, the apparent asymmetry of those processes. The pressing question of time in the context of thermodynamics is about the asymmetry of things in time, not the asymmetry of time, to paraphrase Price ( , ). I use the title anyway, to underscore what is, to my mind, the centrality of thermodynamics to any discussion of the nature of time and our experience in it. The two issues—the temporal features of processes in time, and the intrinsic structure of time itself—are related. Indeed, it is in part this relation that makes the question of time asymmetry in thermodynamics so interesting. This, plus the fact that thermodynamics describes a surprisingly wide range of our ordinary experience. We’ll return to this. First, we need to get the question of time asymmetry in thermodynamics out on the table. (shrink)

This is an extensive review of recent work on the foundations of statistical mechanics.

The thesis proposes, defends, and applies a new model of inter-theoretic reduction, called "Neo-Nagelian" reduction. There are numerous accounts of inter-theoretic reduction in the philosophy of science literature but the most well-known and widely-discussed is the Nagelian one. In the thesis I identify various kinds of problems which the Nagelian model faces. Whilst some of these can be resolved, pressing ones remain. In lieu of the Nagelian model, other models of inter-theoretic reduction have been proposed, chief amongst which are so-called (...) "New Wave" models. I show these to be no more adequate than the original Nagelian model. I propose a new model of inter-theoretic reduction, Neo-Nagelian reduction. This model is structurally similar to the Nagelian one, but differs in substantive ways. In particular I argue that it avoids the problems pertaining to both the Nagelian and New Wave models. Multiple realizability looms large in discussions about reduction: it is claimed that multiply realizable properties frustrate the reduction of one theory to another in various ways. I consider these arguments and show that they do not undermine the Neo-Nagelian of reduction of one theory to another. Finally, I apply the model to statistical mechanics. Statistical mechanics is taken to be a reductionist enterprise: one of the aims of statistical mechanics is to reduce thermodynamics. Without an adequate model of inter-theoretic reduction one cannot assess whether it succeeds; I use the Neo-Nagelian model to critically discuss whether it does. Specifically, I consider two very recent derivations of the Second Law of thermodynamics, one from Boltzmannian classical statistical mechanics and another from quantum statistical mechanics. I argue that they are partially successful, and that each makes for a promising line of future research. (shrink)

One of the recurrent problems in the foundations of physics is to explain why we rarely observe certain phenomena that are allowed by our theories and laws. In thermodynamics, for example, the spontaneous approach towards equilibrium is ubiquitous yet the time-reversal-invariant laws that presumably govern thermal behaviour in the microscopic level equally allow spontaneous departure from equilibrium to occur. Why are the former processes frequently observed while the latter are almost never reported? Another example comes from quantum mechanics where the (...) formalism, if considered complete and universally applicable, predicts the existence of macroscopic superpositions—monstrous Schr¨odinger cats—and these are never observed: while electrons and atoms enjoy the cloudiness of waves, macroscopic objects are always localized to definite positions. (shrink)