Two successes of old quantum theory are particularly notable: Bohr’s prediction of the spectral lines of ionised helium, and Sommerfeld’s prediction of the fine-structure of the hydrogen spectral lines. Many scientific realists would like to be able to explain these successes in terms of the truth or approximate truth of the assumptions which fuelled the relevant derivations. In this paper I argue that this will be difficult for the ionised helium success, and is almost certainly impossible for the fine-structure success. (...) Thus I submit that the case against the realist’s thesis that success is indicative of truth is marginally strengthened. (shrink)

Probably the most dramatic historical challenge to scientific realism concerns Arnold Sommerfeld’s derivation of the fine structure energy levels of hydrogen. Not only were his predictions good, he derived exactly the same formula that would later drop out of Dirac’s 1928 treatment. And yet the most central elements of Sommerfeld’s theory were not even approximately true: his derivation leans heavily on a classical approach to elliptical orbits, including the necessary adjustments to these orbits demanded by relativity. Even physicists call Sommerfeld’s (...) success a ‘miracle’, which rather makes a joke of the so-called ‘no miracles argument’. However, this can all be turned around. Here I argue that the realist has a story to tell vis-à-vis the discontinuities between the old and the new theory, leading to a realist defence based on sufficient continuity of relevant structure. 1Introduction2No Realist Commitment Required?3Enter the Physicists4A New Approach to the Non-relativistic Success5Relativity and Spin6Structure and Realist Commitment7Conclusion. (shrink)

Quantum mechanics teaches that before detection, knowledge of particle position is, at best, probabilistic, and classical trajectories are seen as a feature of the macroscopic world. These comments refer to detected particles, but we are still free to consider the motions generated by the wave equation. Within hydrogen, the Schrodinger equation allows calculation of kinetic energy at any location, and if this is identified as the energy of the wave, then radial momentum, allowing for spherical harmonics, becomes available. The distance (...) across the real zone of radial momentum is found to match semi-integer wavelengths of the adjusted matter wave, consistent with what is expected from a standing wave condition. The approach is extended to include orbital motions, where it is established that the underlying wave, which has direction and wavelength at each location, forms a series of connected trajectories, which are shown to be ellipses orientated at various angles to the equatorial plane. This suggests that wave trajectories, rather than particle trajectories, are still a feature of the hydrogen atom. The finding allows the reason for the coincidence between energy results derived by Sommerfeld’s classical trajectories and the Schrodinger wave equation to be appreciated. The result has implications when the relativistic situation is considered, as Sommerfeld’s correct deduction of the relativistic energy levels of hydrogen well before Dirac derived his wave equation has long been somewhat puzzling. (shrink)