In the problem of the relationship between chemistry and physics, many authors take for granted the ontological reduction of the chemical world to the world of physics. The autonomy of chemistry is usually defended on the basis of the failure of epistemological reduction: not all chemical concepts and laws can be derived from the theoretical framework of physics. The main aim of this paper is to argue that this line of argumentation is not strong enough for eliminate the idea of (...) a hierarchical dependence of chemistry with respect to physics. The rejection of the secondary position of chemistry and the defense of the legitimacy of the philosophy of chemistry require a radically different philosophical perspective that denies not only epistemological reduction but also ontological reduction. Only on the basis of a philosophically grounded ontological pluralism it is possible to accept the ontological autonomy of the chemical world and, with this, to reverse the traditional idea of the ‘superiority’ of physics in the context of natural sciences. (shrink)

Kellert (In the Wake of Chars, University of Chicago press, Chicago, 1993) has argued that Laplacean determinism in classical physics is actually a layered concept, where various properties or layers composing this form of determinism can be peeled away. Here, I argue that a layered conception of determinism is inappropriate and that we should think in terms of different deterministic models applicable to different kinds of systems. The upshot of this analysis is that the notion of state is more closely (...) tied to the kind of system being investigated than is usually considered in discussions of determinism. So when investigating determinism corresponding changes to the appropriate notion of state – and, perhaps, the state space itself – also need to be considered. (shrink)

We have two main aims: to construct mathematical models for analysing determinism, causality and supervenience; and then to use these to demonstrate the possibility of constructing an ontic construal of the operation of free will - one requiring both the presentation of genuine alternatives to an agent and their selecting between them in a manner that permits the attribution of responsibility. Determinism is modelled using trans-temporal ontic links between discrete juxtaposed universe states and shown to be distinct from predictability. Causality (...) is defined on a temporal sequence of δ-algebras and quantified using a measure. The measure leads to definitions of causal overdetermination and epiphenomena. Proofs are constructed to demonstrate deterministic universes must carry their properties essentially but not necessarily locally. We argue determinism and causality are separate doctrines. These models and results are marshalled to put the case that a counterfactual construal of ontic choice cannot work. In response we propose ‘immanence’ - a modified form of indeterminism whereby a universe can present choices to its denizens. We prove that beings subsumed within a universe cannot pilot their own actions. We then argue these beings can exercise free will only when selecting between choices inhering within immanent relata. A being is responsible for its selections if and only if it is constituted of a temporally evolving deterministic substructure. Our proposal is novel: it avoids injecting indeterminism into the decision process. Topological models for property supervenience are developed and used to reconstruct standard definitions from the literature. These are then used to demonstrate considerations of supervenience do not affect our arguments. We have demonstrated that a model of the exercise of free will involving both genuine choices and responsibility is possible but can only operate within a non-deterministic universe possessing specific traits. (shrink)