Chemical Atomism

Bohr’s atomic model is one of the better known examples of empirically successful, albeit inconsistent, theoretical schemes in the history of physics. For this reason, many philosophers use this model to illustrate their position for the occurrence and the function of inconsistency in science. In this paper, I proceed to a critical comparison of the structure and the aims of Bohr’s research program – the starting point of which was the formulation of his model – with some of its contemporary (...) philosophical readings. My study comes to conclude that the attempt of certain philosophers to accommodate Bohr’s model to a form of paraconsistent logic obliterates essential aspects of scientists' actual practice and reasoning. (shrink)

The heated debates and severe conflicts between the atomists and the anti-atomists of the latter half of the nineteenth century are well known to the historian of science. The position of Dmitrii Ivanovich Mendeleev towards these nineteenth century debates on atomism will be studied in this paper. A first attempt will thus be offered to reconcile Mendeleev’s seemingly contradictory comments and ambiguous standpoints into one coherent view.

The philosophical vision of the world and the consequent methodology behind the book are clarified. The perspective used is the systemic one, but since today this term has assumed a wide and diversified meaning in the literature, this introduction will clarify the specific meaning of our approach, starting from the meaning of the term "system". Our idea of system is based on three key assertions that may seem contradictory, but are necessary and complementary to its definition. In particular, we considered (...) the usual idea that the system is more and less than the sum of its juxtaposed parts, highlighting the role of emergencies and constraints. In our idea of a system, however, we must consider a third fundamental characteristic: its dynamism, the dual nature of the system as an entity and as a process, its role as a "dynamic entity". Afterwards, the holistic and reductionist approaches were analysed in detail, and both the specific merits and the fact that these two opposing worldviews, considered individually, cannot give a complete and balanced description of reality, were taken into account. For us, only the systemic approach provides a balanced description of both the parts and the whole and must, therefore, be preferred. Finally, the differences between our approach and the approaches mentioned above have been considered in detail in this introduction. (shrink)

Compared to its sister disciplines—philosophy of physics and philosophy of biology—philosophy of chemistry remains a relatively young field of philosophical endeavour. Having originated in the late...

I challenge Gareth Eaton’s recent claim that Theodore Richards should be counted among the discoverers of isotopes. In evaluating Eaton’s claim, I draw on two influential theories of scientific discovery, one developed by Thomas Kuhn, and one developed by Augustine Brannigan. I argue that though Richards’ experimental work contributed to the discovery, his work does not warrant attributing the discovery to him. Richards’ reluctance to acknowledge isotopes is well documented. Further, the fact that he made no claim to having made (...) the discovery also undermines Eaton’s argument. (shrink)

This book examines the way in which Robert Boyle seeks to accommodate his complex chemical philosophy within the framework of a mechanistic theory of matter. More specifically, the book proposes that Boyle regards chemical qualities as properties that emerged from the mechanistic structure of chymical atoms. Within Boyle’s chemical ontology, chymical atoms are structured concretions of particles that Boyle regards as chemically elementary entities, that is, as chemical wholes that resist experimental analysis. Although this interpretation of Boyle’s chemical philosophy has (...) already been suggested by other Boyle scholars, the present book provides a sustained philosophical argument to demonstrate that, for Boyle, chemical properties are dispositional, relational, emergent, and supervenient properties. This argument is strengthened by a detailed mereological analysis of Boylean chymical atoms that establishes the kind of theory of wholes and parts that is most consistent with an emergentist conception of chemical properties. The emergentist position that is being attributed to Boyle supports his view that chemical reactions resist direct explanation in terms of the mechanistic properties of fundamental particles, as well as his position regarding the scientific autonomy of chymistry from mechanics and physics. (shrink)

The French physicist Jean Baptiste Perrin is widely credited with providing the conclusive argument for atomism. The most well-known part of Perrin’s argument is his description of thirteen different procedures for determining Avogadro’s number (N)–the number of atoms, ions, and molecules contained in a gram-atom, gram-ion, and gram-mole of a substance, respectively. Because of its success in ending the atomism debates Perrin’s argument has been the focus of much philosophical interest. The various philosophers, however, have reached different conclusions, not only (...) about the argument’s general rationale but also the role that the multiple determination of N played in it. This paper emphasizes the historical development of Perrin’s experimental work in order to understand the role that the multiple determination of molecular magnitudes played in his argument for molecular reality. It claims that Perrin used the multiple determination strategy to put forward an exceptionally strong no-coincidence argument to argue for both the correctness of the values for the molecular magnitudes determined and the validity of the auxiliary assumptions upon which the different determinations were based. The historicist approach also allows the identification of the elements responsible for the epistemic strength of Perrin’s no-coincidence argument. (shrink)

It is commonly thought that Jean Perrin argued for the reality of atoms in the early twentieth century by using what Wesley Salmon calls a “common cause” argument, also known as robustness reasoning. After citing some concerns with this interpretation of Perrin, I offer a different interpretation of Perrin’s work that more closely depicts the details of Perrin’s reasoning in his relevant published writings. I then offer a historical argument that supports this interpretation and discuss the philosophical merits of Perrin’s (...) style of reasoning as I have presented it. I close by showing how my interpretation is distinct from previous interpretations of Perrin’s work. (shrink)

The original conception of atomism suggests “atoms”, which cannot be divided more into composing parts. However, the name “atom” in physics is reserved for entities, which can be divided into electrons, protons, neutrons and other “elementary particles”, some of which are in turn compounded by other, “more elementary” ones. Instead of this, quantum mechanics is grounded on the actually indivisible quanta of action limited by the fundamental Planck constant. It resolves the problem of how both discrete and continuous (even smooth) (...) to be described uniformly and invariantly in thus. Quantum mechanics can be interpreted in terms of quantum information. Qubit is the indivisible unit (“atom”) of quantum information. The imagery of atomism in modern physics moves from atoms of matter (or energy) via “atoms” (quanta) of action to “atoms” (qubits) of quantum information. This is a conceptual shift in the cognition of reality to terms of information, choice, and time. (shrink)

During the twentieth century, the mechanistic worldview came under attack mainly because of the rise of quantum mechanics but some of its basic characteristics survived and are still evident within current science in some form or other. Many scholars have produced interesting studies of such significant mechanistic trends within current physics and biology but very few have bothered to explore the effects of this worldview on current chemistry. This paper makes a contribution to fill this gap. It presents first a (...) brief historical overview of the mechanistic worldview and then examines the present situation within chemistry by referring to current studies in the philosophy of chemistry and determining which trends are still mechanistic in spirit and which are not. (shrink)

Quine, taking the molecular constitution of matter as a paradigmatic example, offers an account of the relation between theory confirmation and ontology. Elsewhere, he deploys a similar ontological methodology to argue for the existence of mathematical objects. Penelope Maddy considers the atomic/molecular theory in more historical detail. She argues that the actual ontological practices of science display a positivistic demand for “direct observation,” and that fulfillment of this demand allows us to distinguish molecules and other physical objects from mathematical abstracta. (...) However, the confirmation of the atomic/molecular theory and the development of scientists’ ontological attitudes towards atoms was more complicated and subtle than even Maddy supposes. The present paper argues that the history of the theory in fact supports neither Quine’s and Maddy’s accounts of scientific ontology. There was no general demand from scientists to “see” atoms before they were reckoned to be real; but neither did the indispensable appearance of atoms in the best theory of chemical combination suffice to convince scientists of their reality. (shrink)

In Seeing Things, Robert Hudson assesses a common way of arguing about observation reports called "robustness reasoning." Robustness reasoning claims that an observation report is more likely to be true if the report is produced by multiple, independent sources. Seeing Things argues that robustness reasoning lacks the special value it is often claimed to have. Hudson exposes key flaws in various popular philosophical defenses of robustness reasoning. This philosophical critique of robustness is extended by recounting five episodes in the history (...) of science (from experimental microbiology, atomic theory, astrophysics, and astronomy) where robustness reasoning is — or could be claimed to have been — used. Hudson goes on to show that none of these episodes do in fact exhibit robustness reasoning. In this way, the significance of robustness reasoning is rebutted on both philosophical and historical grounds. But the book does more than critique robustness reasoning. It also develops a better defense of the informative value of observation reports. The book concludes by relating insights into the failure of robustness reasoning to a popular approach to scientific realism called "(theoretical) preservationism." Hudson argues that those who defend this approach to realism commit similar errors to those who advocate robustness reasoning. In turn, a new form of realism is formulated and defended. Called "methodological preservationism," it recognizes the fundamental value of naked-eye observation to scientists — and the rest of us. (shrink)

David E. Fisher: Much Ado about (Practically) Nothing. A History of the Noble Gases Content Type Journal Article Pages 1-3 DOI 10.1007/s10698-011-9114-0 Authors Sandra D. Hojniak, Department of Chemistry, Laboratory of Coordination Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium Journal Foundations of Chemistry Online ISSN 1572-8463 Print ISSN 1386-4238.

Over the last two decades a new scholarship on alchemy has emerged, leading to a fundamental reformulation of knowledge about alchemists and their activities. We now know that medieval and early modern alchemists employed experiment in concert with theory to demonstrate the existence of stable “chymical atoms,” which were thought to combine with one another according to a hierarchical theory of matter. Employing laboratory-based analysis and synthesis, alchemists were among the first explicitly to enunciate the principle of mass balance and (...) to show that materials are compounded of the ingredients into which they can be physically decomposed. Perhaps even more surprisingly, these convictions and practices arose out of the interaction of alchemical practice with scholastic Aristotelianism, long viewed by historians of the Scientific Revolution as antithetical to experiment. Thus the new historiography challenges both a long-standing marginalization of alchemy itself and a commonplace view of Aristotelianism as inimical to the early modern growth of experimental science. -/- . (shrink)

This article documents the general tendency of seventeenth-century natural philosophers, irrespective of whether they were atomists or anti-atomists, to regard space, time and matter as magnitudes having the same internal composition. It examines the way in which authors such as Fromondus, Basson, Sennert, Arriaga, Galileo, Magnen, Descartes, Gassendi, Charleton as well as the young Newton motivated their belief in the isomorphism of space, time and matter, and how this belief reflected on their views concerning the relation between geometry and physics. (...) Special attention is paid to the fact that most of the authors mentioned above regarded rarefaction and condensation, on the one hand, and acceleration and deceleration, on the other hand, as analogous phenomena, which consequently had to be explained in similar terms. (shrink)

Paul Needham has claimed in several recent papers that Dalton’s chemical atomism was not explanatory. I respond to his criticism of Dalton by arguing that explanation admits of degrees and that under a view that allows for a spectrum of explanatory value, it is possible to see ample worth in Dalton’s atomistic explanations. Furthermore, I argue that even Duhem, who rejected atomism, acknowledged the explanatory worth of Dalton’s atomism.

Historical research on John Dalton has been dominated by an attempt to reconstruct the origins of his so-called "chemical atomic theory". I show that Dalton's theory is difficult to define in any concise manner, and that there has been no consensus as to its unique content among his contemporaries, later chemists, and modern historians. I propose an approach which, instead of attempting to work backward from Dalton's theory, works forward, by identifying the research questions that Dalton posed to himself and (...) attempting to understand how his hypotheses served as answers to these questions. I describe Dalton's scientific work as an evolving set of puzzles about natural phenomena. I show how an early interest in meteorology led Dalton to see the constitution of the atmosphere as a puzzle. In working on this great puzzle, he gradually turned his interest to specifically chemical questions. In the end, the web of puzzles that he worked on required him to create his own novel philosophy of chemistry for which he is known today. (shrink)

There have been occasions when the publication of a particular book has had a singular impact on the conceptual world of the chemist. Sometimes the publication occurs near the beginning of a major change in discourse, and sometimes more near the end. Jean Perrin published Les Atomes in 1913 as the culmination of a century-long controversy over the size and physical reality of atoms and molecules. After its publication almost all chemists and physicists agreed that atoms and molecules of the (...) size we currently understand to be appropriate are real physical objects. The story of the background, development, publication, content and response to Les Atomes forms the text of this paper. The content of Les Atomes is also the basis for extended reflection on the philosophical significance of the work of Jean Perrin. (shrink)

This paper aims to present concisely the Islamic kalām atomism as an alternative philosophy to Hellenizing falsafa. Kalām is a theological-philosophical discourse which, first ventured to rival the falsafa represented early by al-Kindī, then by al-Fārābī and Avicenna in the fourth/tenth and fifth/eleventh centuries, and which eventually appeared to be inclined to propose a mingling of the kalām discourse with falsafa in a series of varied "syntheses".—Focusing on the simple ontology of the basic kalām atomism, and noting the hybrid character (...) of kalām, the aim of this paper is to help to clarify the inevitable problematic consequences of those late ventures of Islamic intellectualism. (shrink)

Since Mendeleev’s discovery in 1869, the periodic table has figured as the ultimate paper tool in chemical research. It has proved to be a vital research instrument in the arsenal of the chemical community. No chemistry textbook, lecture theatre or scientific laboratory is complete without a copy of the periodic table of the elements. -/- This however, should not necessarily imply that the periodic table has never had to contend with problems. In this thesis, the history of the accommodation of (...) the rare-earth elements in the periodic table will be addressed. When Mendeleev published his periodic table in 1869, the rare earths already constituted a major obstacle. Mendeleev was able to include only four members of the rare earths and he experienced great difficulties in positioning these elements. Question marks and wrong atomic weights reigned in the last rows of Mendeleev’s system. -/- This problematic accommodation quickly grew into one of the most serious threats for the periodic law. For over fifty years, chemists continually struggled with the placement of these maddeningly similar elements. As a consequence, a lot of chemists started to question the validity of the periodic law, but others took it as a sign that the concept of a chemical element had to be reconsidered. As a result, this work intends to retrace the mutual influence of the philosophical ideas about the nature of chemical elements and the development of the periodic table from its inception in 1869 to the discovery of Moseley’s law in 1913 and Bohr’s publication of his landmark paper On the Constitution of Atoms and Molecules. -/- The aim of this thesis is to show how, on the one hand, the periodic table (as a research instrument) helped in reformulating the contemporary ideas about chemical elements, and how it aided in developing a new research program in order to resolve the rare earth crisis. On the other hand, the question will be taken up to what extent Crookes’ evolutionary ideas about meta elements helped in saving the periodic table from a severe downfall by solving the gnawing problem of the rare-earth elements. In particular, this work will also focus on the investigations of the Czech chemist, Bohuslav Brauner. It will be shown how Brauner, under the influence of Crookes’ ideas, was led to his formulation of the Asteroid Hypothesis, according to which all the rare-earth elements should be placed in a single case of the periodic table. (shrink)

The issue of shifting scales between the microscopic and the macroscopic dimensions is a recurrent one in the history of science, and in particular the history of microscopy. But it took on new dimensions in the context of early twentieth-century microscophysics, with the progressive realisation that the physical laws governing the macroscopic world were not always adequate for describing the sub-microscopic one. The paper focuses on the researches of Jean Perrin in the 1900s, in particular his use of Brownian motion (...) to produce evidence of the existence of atoms and in favour of the kinetic theory. His results were described by many contemporaries, and subsequently by historians, as the first direct proof of atomic and molecular reality. The paper examines the different strategies developed by Perrin for bridging the macro and sub-microphysical realms and making the latter accessible to the senses; even though neither atoms nor molecules were ever actually seen, and in fact very few visual representations were shown and published in connection with these experiments. This case provides a good example of how visualizing, representing and convincing could be interwoven in the production of evidence about the sub-microphysical realm circa 1900.Keywords: Jean Perrin; Brownian motion; Ultramicroscope; Evidence; Atom; Atomism. (shrink)

This paper suggests that the cases made for atoms and the aether in nineteenth-century physical science were analogous, with the implication that the case for the atom was less than compelling, since there is no aether. It is argued that atoms did not play a productive role in nineteenth-century chemistry any more than the aether did in physics. Atoms and molecules did eventually find an indispensable home in chemistry but by the time that they did so they were different kinds (...) of entities to those figuring in the speculations of those natural philosophers who were atomists. Advances in nineteenth-century chemistry were a precondition for rather than the result of the productive introduction of atoms into chemistry. (shrink)

Harvey and Highmore experimented together on chick fetuses at Oxford in the early 1640s, yet in 1651 published significantly different treatises on generation that emphasize their reliance on observations and dissections of fetal chicks at different stages of incubation. The key differences follow from their views on matter and souls. Harvey conceives of living bodies as governed by Aristotelian souls and faculties. Highmore views matter as made of corpuscles and describes organs as involved in chemical procedures. Highmore's treatise is a (...) response to Digby's claim that heat, moisture, and pressure could explain generation. Although Digby's treatment lacks Harvey's and Highmore's attention to detail, it offers a point of comparison that leads to a more nuanced understanding of their explanation. Moreover, Highmore's dedication of his work to Boyle provides a new perspective on both men's intellectual evolution from the latter part of the 1640s to 1651. (shrink)

Late nineteenth‐century opponents of atomism questioned whether the evidence required any notion of an atom. In this spirit, Duhem developed an account of the import of chemical formulas that is clearly neutral on the atomic question rather than antiatomistic. The argument is supplemented with specific inadequacies of atomic theories of chemical combination and considerably strengthened by the theory of chemical combination provided by thermodynamics. Despite possible counterevidence available at the time, which should have tempered some of Duhem's concluding remarks, there (...) was no atomic theory of chemical combination, which is wholly a product of the twentieth century. †To contact the author, please write to: Department of Philosophy, University of Stockholm, SE‐106 91 Stockholm, Sweden; e‐mail: [email protected]. (shrink)

This article examines the philosophical teaching of a colorful Oxford alumnus and Roman Catholic convert, Christopher Davenport, also known as Franciscus à Sancta Clara or Francis Coventry. At the peak of Puritan power during the English Interregnum and after five of his Franciscan confrères had perished for their missionary work, our author tried boldly to claim modern cosmology and atomism as the unrecognized fruits of medieval Scotism. His hope was to revive English pride in the golden age of medieval Oxford (...) and to defend English Franciscans as more legitimately patriotic and scientifically progressive than Puritan millenarians. (shrink)

Encyclopedia article briefly summarizing the history of atomism from antiquity to modernity.

The philosophical problem of the utility andmeaning of essences for chemistry cannot beresolved by Wittgenstein's principle thatessence cannot explain use, because use isdisplayed in a field of family resemblances.The transition of chemical taxonomy fromvernacular and mystical based terms to theorybased terms stabilized as a unified descriptivetaxonomy, removes chemical discourse from itsconnection with the vernacular. The transitioncan be tracked using the Lockean concepts ofreal and nominal essences, and the changingpriorities between them. Analyzing propertiesdispositionally, initiating a search forgroundings strengthens the case for (...) a logicalasymmetry between descriptive and explanatorydiscourses. Taxonomy is now driven byexplanatory concepts, but not including thosefrom quantum chemistry. (shrink)

During the 19th century atomism was a controversial issue in chemistry. It is an oversimplification to dismiss the critics' arguments as all falling under the general positivist view that what can't be seen can't be. The more interesting lines of argument either questioned whether any coherent notion of an atom had ever been formulated or questioned whether atoms were ever really given any explanatory role. At what point, and for what reasons, did atomistic hypotheses begin to explain anything in chemistry? (...) It is argued that 19th-century atomic accounts of constant proportions and isomerism had little to offer, whereas a non-atomic explanation of chemical combination was developed. Not until the turn of the century did atomism begin to do serious explanatory work in chemistry. (shrink)

الكيمياء علمٌ تجريبي بطبيعته، يشتغل معمليًا بالجواهر تحليلاً وتركيبًا، ويُقيم بناءاته النسقية استرشادًا بقواعد محددة تحكم إجراءات البحث التجريبي ونتائجه. وكشأن أي نشاط علمي آخر، تستلزم الممارسة الكيميائية لغة جزئية خاصة تصف بناءاتها التجريبية وتُنمّط أشكالها. وما دام التحليل والتركيب – كإجراءين تجريبيين – هما عمادا البحث الكيميائي وجوهره، فمن الضروري أن تحوي لغة الكيمياء تمثيلات صورية توصف بدورها بأنها صيغٌ أو عبارات تحليلية وتركيبية. يمكننا إذن الزعم بأن ثمة علاقة اعتماد متبادلة بين لغة الكيمياء وممارساتها المعملية؛ فاللغة تؤثر مباشرة (...) – وبأكثر من طريقة – على مجرى البحث الكيميائي وتطوره, ومن خلالها يمكن تحديد مدى قوته أو ضعفه ... تقدمه أو تخلفه ... شرعية تنبؤاته أو افتقادها لسمة الشرعية المنطقية؛ كما أن سُبل البحث المعملي للكيمياء تنعكس بالضرورة على قواعد الصياغة الصورية لهذه اللغة ومدى إمكانية تطويرها وتنقيتها من شوائب اللغة العادية التي اشتُقت منها. ويعني ذلك – بعبارة أخرى – أن اللغة والتجريب شقان مُكملان لبعضهما البعض؛ وجهان لعملة واحدة تحمل اسم الممارسة العلمية. فهل تختلف اللغة الكيميائية عن غيرها من لغات العلم الخاصة؟ وكيف يستخدم الكيميائيون لغتهم؟ ما هي القواعد الحاكمة لهذه اللغة؟, وما هي نتائج استخدامها بالنسبة للكيمياء ككل؟. (shrink)

In her recent case study, Elizabeth Potter attempts to show how Boyle's experimental method was biased by gender considerations. Part of her argument focuses on the combination of the “invisibility” of women in Boyle's published work together with his unpublished comments on female chastity, and part concerns Boyle's rejection of the animistic explanation of his air pump experiments by Francis Line. I argue that the historical and biographical elements of the case make Potter's arguments questionable. In addition, I address whether (...) and how such historical cases can shed light on current debates about gender issues and argue that Boyle's methodological writings could be used to better advantage in the feminist cause. (shrink)

Research into learners' ideas aboutscience suggests that school and collegestudents often hold alternative conceptionsabout `the atom'. This paper discusses whylearners acquire ideas about atoms which areincompatible with the modern scientificunderstanding. It is suggested that learners'alternative ideas derive – at least in part –from the way ideas about atoms are presented inthe school and college curriculum. Inparticular, it is argued that the atomicconcept met in science education is anincoherent hybrid of historical models, andthat this explains why learners commonlyattribute to atoms properties (...) (such as beingthe constituent particles of all substances, orof being indivisible and conserved inreactions) that more correctly belong to otherentities (such as molecules or sub-atomicparticles). Bachelard suggested that archaicscientific ideas act as `epistemologicalobstacles', and here it is argued thatanachronistic notions of the atom survive inthe chemistry curriculum. These conceptualfossils encourage learners to develop an`atomic ontology' (granting atoms `ontologicalpriority' in the molecular model of matter); tomake the `assumption of initial atomicity' whenconsidering chemical reactions; and to developan explanatory framework to rationalisechemical reactions which is based on thedesirability of full electron shells. Theseideas then act as impediments to thedevelopment of a modern chemical perspective onthe structure of matter, and an appreciation ofthe nature of chemical changes at the molecularlevel. (shrink)

The bulk of Duhem's writing which bears on the understanding of mixtures suggests he adopted an Aristotelian position which he opposed only to the atomic view. A third view from antiquity-that of the Stoics-seems not to be taken into account. But his lines of thought are not always as explicit as could be wished. The Stoic view is considered here from a perspective which Duhem might well have adopted. This provides a background against which his somewhat unorthodox Aristotelianism might be (...) understood. (shrink)